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Decaborane(14)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.88 ± 0.03PELloyd, Lynaugh, et al., 1975LLK
10.3 ± 0.5EIKaufman, Koski, et al., 1962RDSH
11.0 ± 0.5EIMargrave, 1960RDSH
10.15PERoberts, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Bl0H7+12.5 ± 0.53H2+HEIKaufman, Koski, et al., 1962RDSH
B10H6+13.1 ± 0.34H2EIKaufman, Koski, et al., 1962RDSH
B10H8+12.7 ± 0.33H2EIKaufman, Koski, et al., 1962RDSH
B10H10+11.6 ± 0.22H2EIKaufman, Koski, et al., 1962RDSH
B10H11+10.8 ± 0.5H2+HEIKaufman, Koski, et al., 1962RDSH
B10H12+10.9 ± 0.2H2EIKaufman, Koski, et al., 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lloyd, Lynaugh, et al., 1975
Lloyd, D.R.; Lynaugh, N.; Roberts, P.J.; Guest, M.F., Photoelectron studies of boron and compounds, Part 5. -Higher boron hydrides B4H10, B5H9, B10H14, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1382. [all data]

Kaufman, Koski, et al., 1962
Kaufman, J.J.; Koski, W.S.; Kuhns, L.J.; Law, R.W., Appearance and ionization potentials of selected fragments from decaborane, 11B10H14, J. Am. Chem. Soc., 1962, 84, 4198. [all data]

Margrave, 1960
Margrave, J.L., Ionization potentials of B5H9, B5H8I, B10H14, and B10H13C2H5 from electron impact studies, J. Chem. Phys., 1960, 32, 1889. [all data]

Roberts, 1974
Roberts, P., Title unavailable, Thesis, University of Birmingham, 1974. [all data]


Notes

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