Sodium ion (1+)
- Formula: Na+
- Molecular weight: 22.98922070
- IUPAC Standard InChIKey: FKNQFGJONOIPTF-UHFFFAOYSA-N
- CAS Registry Number: 17341-25-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Sodium cation
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 201 to 248
- Ion clustering data
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 151 to 200
By formula: (Na+ • 34Na) + Na = (Na+ • 35Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.6 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 35Na) + Na = (Na+ • 36Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.8 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: Na+ + C2H6S = (Na+ • C2H6S)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
14.2 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H9N = (Na+ • C3H9N)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
19.0 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: Na+ + C3H6O2 = (Na+ • C3H6O2)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
23.3 | 298. | IMRE | McMahon and Ohanessian, 2000 | Anchor alanine=39.89; RCD |
By formula: (Na+ • 9Na) + Na = (Na+ • 10Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.0 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 2Na) + Na = (Na+ • 3Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.4 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 3Na) + Na = (Na+ • 4Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.1 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 4Na) + Na = (Na+ • 5Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.8 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 5Na) + Na = (Na+ • 6Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 26.3 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 6Na) + Na = (Na+ • 7Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.5 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 7Na) + Na = (Na+ • 8Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30.2 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: Na+ + F3Sc = (Na+ • F3Sc)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 33. | kcal/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
By formula: Na+ + FNa = (Na+ • FNa)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 62.7 | kcal/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
By formula: Na+ + O2 = (Na+ • O2)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
0.2 | 310. | DT | Keller and Beyer, 1971 | gas phase; low E/N; M |
By formula: (Na+ • Na) + Na = (Na+ • 2Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 31.8 | kcal/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: Na+ + C6H14N2O2 = (Na+ • C6H14N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >50.9 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H14N4O2 = (Na+ • C6H14N4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | >53.7 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.8 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H13NO2 = (Na+ • C6H13NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.0 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C9H11NO3 = (Na+ • C9H11NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.0 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H7NO4 = (Na+ • C4H7NO4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.5 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.7 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 50.6 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H8N2O3 = (Na+ • C4H8N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 49.2 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C6H9N3O2 = (Na+ • C6H9N3O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 52.3 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: Na+ + C4H9NO3 = (Na+ • C4H9NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 47.1 | kcal/mol | CIDC | Kish, Ohanessian, et al., 2003 | Anchor alanine=39.89; RCD |
By formula: (Na+ • C7H8) + C7H8 = (Na+ • 2C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.7 ± 0.5 | kcal/mol | CIDT | Amunugama and Rodgers, 2002 | RCD |
By formula: (Na+ • C6H6O) + C6H6O = (Na+ • 2C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.5 ± 0.8 | kcal/mol | CIDT | Amunugama and Rodgers, 2002, 2 | RCD |
By formula: (Na+ • C6H5F) + C6H5F = (Na+ • 2C6H5F)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.7 ± 0.9 | kcal/mol | CIDT | Amunugama and Rodgers, 2002, 3 | RCD |
By formula: (Na+ • C7H8O) + C7H8O = (Na+ • 2C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.4 ± 0.6 | kcal/mol | CIDT | Amunugama and Rodgers, 2003 | RCD |
By formula: Na+ + O3 = (Na+ • O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.5 | kcal/mol | FA | Rowe, Viggiano, et al., 1982 | gas phase; M |
By formula: Na+ + CH2N4 = (Na+ • CH2N4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 27.5 ± 1.0 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 | RCD |
By formula: Na+ + C6H10N2O2 = (Na+ • C6H10N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 36.1 ± 1.7 | kcal/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C5H8N2O2 = (Na+ • C5H8N2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 35.6 ± 1.7 | kcal/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C5H9NO4 = (Na+ • C5H9NO4)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
33.9 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
+ C5H10N2O3S = (
• C5H10N2O3S)
By formula: Na+ + C5H10N2O3S = (Na+ • C5H10N2O3S)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
34.3 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42.5 ± 1.7 | kcal/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C6H12N2O3 = (Na+ • C6H12N2O3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 43.0 ± 1.7 | kcal/mol | CIDC | Cerda, Hoyau, et al., 1998 | RCD |
By formula: Na+ + C3H9N = (Na+ • C3H9N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 28.9 ± 1.4 | kcal/mol | CIDT | Moision and Armentrout, 2002 | RCD |
By formula: Na+ + C8H15NO3 = (Na+ • C8H15NO3)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
33.9 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C7H11NO5 = (Na+ • C7H11NO5)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
37.0 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C13H14NO3 = (Na+ • C13H14NO3)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
37.4 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C2H7NO = (Na+ • C2H7NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 41.8 ± 1.7 | kcal/mol | CIDT | Moision and Armentrout, 2002 | RCD |
By formula: Na+ + C7H14N2O3 = (Na+ • C7H14N2O3)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
36.7 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C11H13NO3 = (Na+ • C11H13NO3)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
34.8 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C13H15N2O3 = (Na+ • C13H15N2O3)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
41.2 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C11H14N2O3 = (Na+ • C11H14N2O3)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
38.1 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C5H10N2O3 = (Na+ • C5H10N2O3)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
35.5 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
By formula: Na+ + C6H10N2O5 = (Na+ • C6H10N2O5)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
38.5 | 0. | CIDC | Feng, Gronert, et al., 1999 | RCD |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brechignac, Cahuzac, et al., 1989
Brechignac, C.; Cahuzac, P.; Leygnier, J.; Weiner, J.,
Dynamics of Unimolecular Dissociation of Sodium Cluster Ions,
J. Chem. Phys., 1989, 90, 3, 1492, https://doi.org/10.1063/1.456675
. [all data]
McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G.,
An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions,
Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7
. [all data]
Tsirlina, Gusarov, et al., 1986
Tsirlina, E.A.; Gusarov, A.V.; Gorokhov, L.N.,
High Temp., 1986, 14, 1064. [all data]
Keller and Beyer, 1971
Keller, G.E.; Beyer, R.A.,
CO2 and O2 Clustering to Sodium Ions,
J. Geophys. Res., 1971, 74, 1, 289, https://doi.org/10.1029/JA076i001p00289
. [all data]
Kish, Ohanessian, et al., 2003
Kish, M.M.; Ohanessian, G.; Wesdemiotis, C.,
The Na+ affinities of a-amino acids: side-chain substituent effects,
Int. J. Mass Spectrom., 2003, 227, 3, 509, https://doi.org/10.1016/S1387-3806(03)00082-4
. [all data]
Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T.,
Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies,
J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b
. [all data]
Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T.,
The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies,
J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584
. [all data]
Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T.,
Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies,
J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a
. [all data]
Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T.,
Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies,
Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4
. [all data]
Rowe, Viggiano, et al., 1982
Rowe, B.R.; Viggiano, A.A.; Fehsenfeld, F.C.; Fahey, D.W.; Ferguson, E.E.,
Reactions between Neutrals Clustered on Ions,
J. Chem. Phys., 1982, 76, 1, 742, https://doi.org/10.1063/1.442684
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Cerda, Hoyau, et al., 1998
Cerda, B.A.; Hoyau, S.; Ohanessian, G.; Wesdemiotis, C.,
PAs of Peptides,
J. Am. Chem. Soc., 1998, 120, 2437. [all data]
Feng, Gronert, et al., 1999
Feng, W.Y.; Gronert, S.; Lebrilla, C.B.,
Lithium and sodium ion binding energies of N-acetyl and N-glycyl amino acids,
J. Am. Chem. Soc., 1999, 121, 6, 1365, https://doi.org/10.1021/ja983116s
. [all data]
Moision and Armentrout, 2002
Moision, R.M.; Armentrout, P.B.,
Experimental and Theoretical Dissection of Sodium Cation/Glycine Interactions,
J. Phys. Chem A, 2002, 106, 43, 10350, https://doi.org/10.1021/jp0216373
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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