Lithium ion (1+)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Reactions 51 to 100

(Lithium ion (1+) • 2Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) • 3Carbon monoxide)

By formula: (Li+ • 2CO) + CO = (Li+ • 3CO)

Quantity Value Units Method Reference Comment
ΔrH°8.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°8.4 ± 1.0kcal/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) • Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) • 2Carbon monoxide)

By formula: (Li+ • CO) + CO = (Li+ • 2CO)

Quantity Value Units Method Reference Comment
ΔrH°8.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°8.6 ± 1.0kcal/molCIDTWalter, Sievers, et al., 1998RCD

Lithium ion (1+) + Carbon monoxide = (Lithium ion (1+) • Carbon monoxide)

By formula: Li+ + CO = (Li+ • CO)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°13.1 ± 2.9kcal/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) • Nitrogen) + Nitrogen = (Lithium ion (1+) • 2Nitrogen)

By formula: (Li+ • N2) + N2 = (Li+ • 2N2)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.4318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) • Nitrogen)

By formula: Li+ + N2 = (Li+ • N2)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.6318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

Lithium ion (1+) + Oxygen = (Lithium ion (1+) • Oxygen)

By formula: Li+ + O2 = (Li+ • O2)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.2319.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

(Lithium ion (1+) • Toluene) + Toluene = (Lithium ion (1+) • 2Toluene)

By formula: (Li+ • C7H8) + C7H8 = (Li+ • 2C7H8)

Quantity Value Units Method Reference Comment
ΔrH°27.8 ± 0.7kcal/molCIDTAmunugama and Rodgers, 2002RCD

(Lithium ion (1+) • Phenol) + Phenol = (Lithium ion (1+) • 2Phenol)

By formula: (Li+ • C6H6O) + C6H6O = (Li+ • 2C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°27.4 ± 0.8kcal/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Lithium ion (1+) • Benzene, fluoro-) + Benzene, fluoro- = (Lithium ion (1+) • 2Benzene, fluoro-)

By formula: (Li+ • C6H5F) + C6H5F = (Li+ • 2C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°22.7 ± 0.7kcal/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Lithium ion (1+) • Anisole) + Anisole = (Lithium ion (1+) • 2Anisole)

By formula: (Li+ • C7H8O) + C7H8O = (Li+ • 2C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°29.0 ± 0.9kcal/molCIDTAmunugama and Rodgers, 2003RCD

(Lithium ion (1+) • Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) • 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ • C4H10O2) + C4H10O2 = (Li+ • 2C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°33.2 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

(Lithium ion (1+) • Benzene) + Benzene = (Lithium ion (1+) • 2Benzene)

By formula: (Li+ • C6H6) + C6H6 = (Li+ • 2C6H6)

Quantity Value Units Method Reference Comment
ΔrH°24.9 ± 1.7kcal/molCIDTAmicangelo and Armentrout, 2000RCD

Lithium ion (1+) + 2H-Tetrazole = (Lithium ion (1+) • 2H-Tetrazole)

By formula: Li+ + CH2N4 = (Li+ • CH2N4)

Quantity Value Units Method Reference Comment
ΔrH°36.1 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Hydrogen = (Lithium ion (1+) • Hydrogen)

By formula: Li+ + H2 = (Li+ • H2)

Quantity Value Units Method Reference Comment
ΔrH°6.5 ± 4.6kcal/molEIWu, 1979gas phase; M

Lithium ion (1+) + Acetamide, N-methyl- = (Lithium ion (1+) • Acetamide, N-methyl-)

By formula: Li+ + C3H7NO = (Li+ • C3H7NO)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
41.4373.CIDT,ICRHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Toluene = (Lithium ion (1+) • Toluene)

By formula: Li+ + C7H8 = (Li+ • C7H8)

Quantity Value Units Method Reference Comment
ΔrH°43.7 ± 4.0kcal/molCIDTAmunugama and Rodgers, 2002RCD

Lithium ion (1+) + Phenol = (Lithium ion (1+) • Phenol)

By formula: Li+ + C6H6O = (Li+ • C6H6O)

Quantity Value Units Method Reference Comment
ΔrH°42.6 ± 4.0kcal/molCIDTAmunugama and Rodgers, 2002, 2RCD

Lithium ion (1+) + Pyrrole = (Lithium ion (1+) • Pyrrole)

By formula: Li+ + C4H5N = (Li+ • C4H5N)

Quantity Value Units Method Reference Comment
ΔrH°42.3 ± 4.0kcal/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Formamide, N-methyl- = (Lithium ion (1+) • Formamide, N-methyl-)

By formula: Li+ + C2H5NO = (Li+ • C2H5NO)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
39.6373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + 1H-Pyrazole = (Lithium ion (1+) • 1H-Pyrazole)

By formula: Li+ + C3H4N2 = (Li+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°44.7 ± 4.0kcal/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole = (Lithium ion (1+) • 1H-Imidazole)

By formula: Li+ + C3H4N2 = (Li+ • C3H4N2)

Quantity Value Units Method Reference Comment
ΔrH°50.4 ± 2.3kcal/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Benzene, fluoro- = (Lithium ion (1+) • Benzene, fluoro-)

By formula: Li+ + C6H5F = (Li+ • C6H5F)

Quantity Value Units Method Reference Comment
ΔrH°35.1 ± 5.0kcal/molCIDTAmunugama and Rodgers, 2002, 3RCD

Lithium ion (1+) + 1H-Imidazole, 1-methyl- = (Lithium ion (1+) • 1H-Imidazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°57.9 ± 5.0kcal/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Pyrazole, 1-methyl- = (Lithium ion (1+) • 1H-Pyrazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ • C4H6N2)

Quantity Value Units Method Reference Comment
ΔrH°49.5 ± 4.5kcal/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Anisole = (Lithium ion (1+) • Anisole)

By formula: Li+ + C7H8O = (Li+ • C7H8O)

Quantity Value Units Method Reference Comment
ΔrH°44.1 ± 4.5kcal/molCIDTAmunugama and Rodgers, 2003RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) • Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ • C4H10O2)

Quantity Value Units Method Reference Comment
ΔrH°37.8 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + C2H3N3 = (Lithium ion (1+) • C2H3N3)

By formula: Li+ + C2H3N3 = (Li+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°32.5 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1H-1,2,4-Triazole = (Lithium ion (1+) • 1H-1,2,4-Triazole)

By formula: Li+ + C2H3N3 = (Li+ • C2H3N3)

Quantity Value Units Method Reference Comment
ΔrH°45.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Pyrazine = (Lithium ion (1+) • Pyrazine)

By formula: Li+ + C4H4N2 = (Li+ • C4H4N2)

Quantity Value Units Method Reference Comment
ΔrH°35.6 ± 3.3kcal/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + 1,3,5-Triazine = (Lithium ion (1+) • 1,3,5-Triazine)

By formula: Li+ + C3H3N3 = (Li+ • C3H3N3)

Quantity Value Units Method Reference Comment
ΔrH°30.4 ± 3.0kcal/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + 12-Crown-4 = (Lithium ion (1+) • 12-Crown-4)

By formula: Li+ + C8H16O4 = (Li+ • C8H16O4)

Quantity Value Units Method Reference Comment
ΔrH°60.2 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Formamide = (Lithium ion (1+) • Formamide)

By formula: Li+ + CH3NO = (Li+ • CH3NO)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
37.5373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + 1H-Pyrrole, 1-methyl- = (Lithium ion (1+) • 1H-Pyrrole, 1-methyl-)

By formula: Li+ + C5H7N = (Li+ • C5H7N)

Quantity Value Units Method Reference Comment
ΔrH°44.5 ± 4.0kcal/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + C7H8O3S = (Lithium ion (1+) • C7H8O3S)

By formula: Li+ + C7H8O3S = (Li+ • C7H8O3S)

Quantity Value Units Method Reference Comment
ΔrH°49.2kcal/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Ethanol = (Lithium ion (1+) • Ethanol)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Isopropyl Alcohol = (Lithium ion (1+) • Isopropyl Alcohol)

By formula: Li+ + C3H8O = (Li+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°41.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol = (Lithium ion (1+) • 1-Propanol)

By formula: Li+ + C3H8O = (Li+ • C3H8O)

Quantity Value Units Method Reference Comment
ΔrH°40.9 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Butanol = (Lithium ion (1+) • 1-Butanol)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°42.5 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Propanol, 2-methyl- = (Lithium ion (1+) • 2-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°42.5 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol, 2-methyl- = (Lithium ion (1+) • 1-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°40.4 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Butanol = (Lithium ion (1+) • 2-Butanol)

By formula: Li+ + C4H10O = (Li+ • C4H10O)

Quantity Value Units Method Reference Comment
ΔrH°41.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine, 4-methyl- = (Lithium ion (1+) • Pyridine, 4-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°46.9 ± 3.3kcal/molCIDTRodgers, 2001RCD

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) • Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°47.0 ± 3.5kcal/molCIDTRodgers, 2001RCD

Lithium ion (1+) + Pyridine, 2-methyl- = (Lithium ion (1+) • Pyridine, 2-methyl-)

By formula: Li+ + C6H7N = (Li+ • C6H7N)

Quantity Value Units Method Reference Comment
ΔrH°46.4 ± 1.6kcal/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 3-Aminopyridine = (Lithium ion (1+) • 3-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°48.2 ± 2.5kcal/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + 4-Aminopyridine = (Lithium ion (1+) • 4-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°51.8 ± 5.0kcal/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + 2-Aminopyridine = (Lithium ion (1+) • 2-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ • C5H6N2)

Quantity Value Units Method Reference Comment
ΔrH°56.8 ± 5.0kcal/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Benzene, (methylsulfinyl)- = (Lithium ion (1+) • Benzene, (methylsulfinyl)-)

By formula: Li+ + C7H8OS = (Li+ • C7H8OS)

Quantity Value Units Method Reference Comment
ΔrH°54.9kcal/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Methyl 4-nitrophenyl sulfone = (Lithium ion (1+) • Methyl 4-nitrophenyl sulfone)

By formula: Li+ + C7H8NO4S = (Li+ • C7H8NO4S)

Quantity Value Units Method Reference Comment
ΔrH°47.4kcal/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Sulfone, methyl phenyl = (Lithium ion (1+) • Sulfone, methyl phenyl)

By formula: Li+ + C7H8O2S = (Li+ • C7H8O2S)

Quantity Value Units Method Reference Comment
ΔrH°50.8kcal/molCIDCBuncel, Decouzon, et al., 1997RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Walter, Sievers, et al., 1998
Walter, D.; Sievers, M.R.; Armentrout, P.B., Alkali Ion Carbonyls: Sequential Bond Energies of Li+(CO)x (x=1-3), Na+(CO)x (x=1, 2), and K+(CO), Int. J. Mass Spectrom., 1998, 175, 1-2, 93, https://doi.org/10.1016/S0168-1176(98)00109-8 . [all data]

Gatland, Colonna-Romano, et al., 1975
Gatland, I.R.; Colonna-Romano, L.M.; Keller, G.E., Single and Double Clustering of Nitrogen to Li+, Phys. Rev. A, 1975, 12, 5, 1885, https://doi.org/10.1103/PhysRevA.12.1885 . [all data]

Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E., The Clustering of O2 and He to Li+, J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522 . [all data]

Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b . [all data]

Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T., The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584 . [all data]

Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a . [all data]

Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Wu, 1979
Wu, C.H., Binding Energies of LiH2 and LiH2+ and the Ionization Potential of LiH2, J. Chem. Phys., 1979, 71, 2, 783, https://doi.org/10.1063/1.438367 . [all data]

Herreros, Gal, et al., 1999
Herreros, M.; Gal, J.-F.; Maria, P.-C.; Decouzon, M., Gas-Phase Basicity of Simple Amides Toward Proton and Lithium Cation: An Experimental and Theoretical Study, Eur. J. Mass Spectrom., 1999, 5, 1, 259, https://doi.org/10.1255/ejms.282 . [all data]

Huang and Rodgers, 2002
Huang, H.; Rodgers, M.T., Sigma versus Pi interactions in alkali metal ion binding to azoles: Threshold collision-induced dissociation and ab initio theory studies, J. Phys. Chem. A, 2002, 106, 16, 4277, https://doi.org/10.1021/jp013630b . [all data]

Amunugama and Rodgers, 2000
Amunugama, R.; Rodgers, M.T., Absolute Alkali Metal Ion Binding Affinities of Several Azines Determined by Threshold Collision-Induced Dissociation and Ab Initio Theory, Int. J. Mass Spectrom., 2000, 195/196, 439, https://doi.org/10.1016/S1387-3806(99)00145-1 . [all data]

Buncel, Decouzon, et al., 1997
Buncel, E.; Decouzon, M.; Formento, A.; Gal, J.-F.; Herreros, M.; Li, L.; Maria, P.-C., Lithium-Cation and Proton Affinities of Sulfoxides and Sulfones: A Fourier Transform Ion Cyclotron Resonance Study, J. Am. Soc. Mass Spectrom., 1997, 8, 3, 262, https://doi.org/10.1016/S1044-0305(96)00255-3 . [all data]

Rodgers, 2001
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Methylpyridines, J. Phys. Chem. A, 2001, 105, 11, 2374, https://doi.org/10.1021/jp004055z . [all data]

Rodgers, 2001, 2
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Aminopyridines, J. Phys. Chem. A, 2001, 105, 35, 8145, https://doi.org/10.1021/jp011555z . [all data]

Notes

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