cis-2,2,4,6-Tetramethyl-1,3-dioxane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-128.92 ± 0.82kcal/molCcbPihlaja and Luoma, 1968see Pihlaja and Heikkila, 1967, and Pihlaja, 1968
Quantity Value Units Method Reference Comment
Δcliquid-1170.02 ± 0.82kcal/molCcbPihlaja and Luoma, 1968see Pihlaja and Heikkila, 1967, and Pihlaja, 1968; Corresponding Δfliquid = -128.91 kcal/mol (simple calculation by NIST; no Washburn corrections)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pihlaja and Luoma, 1968
Pihlaja, K.; Luoma, S., Heats of formation and conformational energies of 1,3-dioxane and its methyl homologues, Acta Chem. Scand., 1968, 22, 2401-2414. [all data]

Pihlaja and Heikkila, 1967
Pihlaja, K.; Heikkila, J., The configurations of isomeric 2,2,4,6-tetramethyl-1,3-dioxanes, Acta Chem. Scand., 1967, 21, 2430-2434. [all data]

Pihlaja, 1968
Pihlaja, K., The energy difference between the chair and skew-boat forms of the 1,3-dioxane ring, Acta Chem. Scand., 1968, 22, 716-718. [all data]


Notes

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