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Chlorine anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion = C4HClF9-

By formula: Cl- = C4HClF9-

Quantity Value Units Method Reference Comment
Deltar15.50 ± 0.30kcal/molIMREGuerrero, Herrero, et al., 2009gas phase; B

Chlorine anion = C5H10Cl-

By formula: Cl- = C5H10Cl-

Quantity Value Units Method Reference Comment
Deltar8.51kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.61kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C5H12Cl-

By formula: Cl- = C5H12Cl-

Quantity Value Units Method Reference Comment
Deltar8.96kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.61kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C6H12Cl-

By formula: Cl- = C6H12Cl-

Quantity Value Units Method Reference Comment
Deltar9.56kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar3.00kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C6H14Cl-

By formula: Cl- = C6H14Cl-

Quantity Value Units Method Reference Comment
Deltar10.18kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar3.20kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H14Cl-

By formula: Cl- = C7H14Cl-

Quantity Value Units Method Reference Comment
Deltar10.52kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar3.54kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H16Cl-

By formula: Cl- = C7H16Cl-

Quantity Value Units Method Reference Comment
Deltar10.52kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar3.60kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Deltar20.1 ± 1.6kcal/molCIDTHammad and Wenthold, 2000gas phase; B

Chlorine anion = C8H16Cl-

By formula: Cl- = C8H16Cl-

Quantity Value Units Method Reference Comment
Deltar10.52kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar3.25kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H18Cl-

By formula: Cl- = C8H18Cl-

Quantity Value Units Method Reference Comment
Deltar11.74kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar4.47kcal/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = ClN2O-

By formula: Cl- = ClN2O-

Quantity Value Units Method Reference Comment
Deltar4.50 ± 0.10kcal/molN/ABoesl, Distelrath, et al., 2008gas phase; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion bullet Aluminum chloride fluoride)

By formula: Cl- + AlClF2 = (Cl- bullet AlClF2)

Quantity Value Units Method Reference Comment
Deltar74.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100K. See also AlCl2F..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion bullet Aluminum chloride fluoride)

By formula: Cl- + AlCl2F = (Cl- bullet AlCl2F)

Quantity Value Units Method Reference Comment
Deltar75.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiemnts at 800-1100K. See also AlCl3..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + AlCl3 = (Chlorine anion bullet AlCl3)

By formula: Cl- + AlCl3 = (Cl- bullet AlCl3)

Quantity Value Units Method Reference Comment
Deltar76.7 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Aluminum fluoride = (Chlorine anion bullet Aluminum fluoride)

By formula: Cl- + AlF3 = (Cl- bullet AlF3)

Quantity Value Units Method Reference Comment
Deltar74.3 ± 2.9kcal/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiment at 800-1100 K. See also AlClF2..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Deltar27.5 ± 1.7kcal/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + trifluoroarsine = (Chlorine anion bullet trifluoroarsine)

By formula: Cl- + AsF3 = (Cl- bullet AsF3)

Quantity Value Units Method Reference Comment
Deltar25.8 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar18.6 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Boron trichloride = (Chlorine anion bullet Boron trichloride)

By formula: Cl- + BCl3 = (Cl- bullet BCl3)

Quantity Value Units Method Reference Comment
Deltar69.0 ± 2.0kcal/molTherKrivtsov, Titova, et al., 1977gas phase; Halide affinities from this reference are too high. G3MP2B3 calculations indicate an dHaff ca. 46 kcal/mol; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Boron trifluoride = (Chlorine anion bullet Boron trifluoride)

By formula: Cl- + BF3 = (Cl- bullet BF3)

Quantity Value Units Method Reference Comment
Deltar26.0 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar19.3 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Deltar36.6 ± 3.6kcal/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Bromotrifluoromethane = CBrClF3-

By formula: Cl- + CBrF3 = CBrClF3-

Quantity Value Units Method Reference Comment
Deltar16.50 ± 0.20kcal/molTDAsBogdanov and McMahon, 2006gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.20kcal/molTDAsBogdanov and McMahon, 2006gas phase; B

Chlorine anion + Phosgene = (Chlorine anion bullet Phosgene)

By formula: Cl- + CCl2O = (Cl- bullet CCl2O)

Quantity Value Units Method Reference Comment
Deltar12.5 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.5 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Carbon Tetrachloride = (Chlorine anion bullet Carbon Tetrachloride)

By formula: Cl- + CCl4 = (Cl- bullet CCl4)

Quantity Value Units Method Reference Comment
Deltar13.4 ± 2.0kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar14.20 ± 0.70kcal/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.8cal/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.05kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar5.90 ± 0.90kcal/molTDAsDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Carbonic difluoride = (Chlorine anion bullet Carbonic difluoride)

By formula: Cl- + CF2O = (Cl- bullet CF2O)

Quantity Value Units Method Reference Comment
Deltar12.5 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.6 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Methane, trifluoroiodo- = CClF3I-

By formula: Cl- + CF3I = CClF3I-

Quantity Value Units Method Reference Comment
Deltar23.60 ± 0.20kcal/molTDAsBogdanov and McMahon, 2006gas phase; B

Chlorine anion + Difluorochloromethane = (Chlorine anion bullet Difluorochloromethane)

By formula: Cl- + CHClF2 = (Cl- bullet CHClF2)

Quantity Value Units Method Reference Comment
Deltar17.2 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar10.3 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Fluorodichloromethane = (Chlorine anion bullet Fluorodichloromethane)

By formula: Cl- + CHCl2F = (Cl- bullet CHCl2F)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar10.7 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Trichloromethane = (Chlorine anion bullet Trichloromethane)

By formula: Cl- + CHCl3 = (Cl- bullet CHCl3)

Quantity Value Units Method Reference Comment
Deltar15.2 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Deltar19.5 ± 2.0kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar18.10kcal/molMoblGiles and Grimsrud, 1993gas phase; B
Deltar18.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar19.10 ± 0.70kcal/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KN/ALarson and McMahon, 1984gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Deltar24.5cal/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Deltar14.8cal/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar11. ± 1.kcal/molAVGN/AAverage of 6 values; Individual data points

Chlorine anion + Fluoroform = (Chlorine anion bullet Fluoroform)

By formula: Cl- + CHF3 = (Cl- bullet CHF3)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 2.4kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar9.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Hydrogen cyanide = (Chlorine anion bullet Hydrogen cyanide)

By formula: Cl- + CHN = (Cl- bullet CHN)

Quantity Value Units Method Reference Comment
Deltar21.8 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B,B,M
Deltar21.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.9cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Deltar23.7cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar16.2 ± 1.6kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B
Deltar16.1 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Deltar13.9 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion bullet Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 2Hydrogen cyanide)

By formula: (Cl- bullet CHN) + CHN = (Cl- bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar17.9 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.7cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar11.10kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 2Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 3Hydrogen cyanide)

By formula: (Cl- bullet 2CHN) + CHN = (Cl- bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 3Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 4Hydrogen cyanide)

By formula: (Cl- bullet 3CHN) + CHN = (Cl- bullet 4CHN)

Quantity Value Units Method Reference Comment
Deltar11.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.20kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 4Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 5Hydrogen cyanide)

By formula: (Cl- bullet 4CHN) + CHN = (Cl- bullet 5CHN)

Quantity Value Units Method Reference Comment
Deltar8.8 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 5Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 6Hydrogen cyanide)

By formula: (Cl- bullet 5CHN) + CHN = (Cl- bullet 6CHN)

Quantity Value Units Method Reference Comment
Deltar8.7 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.3cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.50kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 6Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 7Hydrogen cyanide)

By formula: (Cl- bullet 6CHN) + CHN = (Cl- bullet 7CHN)

Quantity Value Units Method Reference Comment
Deltar7.9 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.1cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.00kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 7Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 8Hydrogen cyanide)

By formula: (Cl- bullet 7CHN) + CHN = (Cl- bullet 8CHN)

Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar27.4cal/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.0 ± 2.2kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 8Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 9Hydrogen cyanide)

By formula: (Cl- bullet 8CHN) + CHN = (Cl- bullet 9CHN)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 1.0kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar0.10kcal/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.2171.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

Chlorine anion + Methylene chloride = (Chlorine anion bullet Methylene chloride)

By formula: Cl- + CH2Cl2 = (Cl- bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar15.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar14.8 ± 2.0kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar15.50 ± 0.30kcal/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.1cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M
Deltar22.0cal/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar8.84kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar8.90 ± 0.60kcal/molTDEqDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Formic acid = (Chlorine anion bullet Formic acid)

By formula: Cl- + CH2O2 = (Cl- bullet CH2O2)

Quantity Value Units Method Reference Comment
Deltar27.4 ± 2.0kcal/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Deltar27.7 ± 2.1kcal/molCIDTWalker and Sunderlin, 1999gas phase; B
Deltar25.6 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar37.2 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B,M
Quantity Value Units Method Reference Comment
Deltar24.5cal/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Deltar24.1cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar39.6cal/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.1 ± 2.0kcal/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Deltar18.4 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar25.4 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B

(Chlorine anion bullet Formic acid) + Formic acid = (Chlorine anion bullet 2Formic acid)

By formula: (Cl- bullet CH2O2) + CH2O2 = (Cl- bullet 2CH2O2)

Quantity Value Units Method Reference Comment
Deltar11.2 ± 2.1kcal/molCIDTWalker and Sunderlin, 1999gas phase; B
Deltar34.1 ± 3.1kcal/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar55.cal/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

(Chlorine anion bullet 2Formic acid) + Formic acid = (Chlorine anion bullet 3Formic acid)

By formula: (Cl- bullet 2CH2O2) + CH2O2 = (Cl- bullet 3CH2O2)

Quantity Value Units Method Reference Comment
Deltar22.2 ± 2.7kcal/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar35.cal/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

(Chlorine anion bullet 3Formic acid) + Formic acid = (Chlorine anion bullet 4Formic acid)

By formula: (Cl- bullet 3CH2O2) + CH2O2 = (Cl- bullet 4CH2O2)

Quantity Value Units Method Reference Comment
Deltar14.1 ± 2.2kcal/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; M

(Chlorine anion bullet 4Formic acid) + Formic acid = (Chlorine anion bullet 5Formic acid)

By formula: (Cl- bullet 4CH2O2) + CH2O2 = (Cl- bullet 5CH2O2)

Quantity Value Units Method Reference Comment
Deltar10.1 ± 2.0kcal/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Deltar11.5cal/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

Chlorine anion + Methane, bromo- = (Chlorine anion bullet Methane, bromo-)

By formula: Cl- + CH3Br = (Cl- bullet CH3Br)

Quantity Value Units Method Reference Comment
Deltar12.5 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar10.90 ± 0.50kcal/molTDAsDougherty and Roberts, 1974gas phase; B,M
Deltar12.2 ± 3.0kcal/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Deltar12.8cal/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar6.80 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar7.1 ± 1.2kcal/molTDAsDougherty and Roberts, 1974gas phase; B

Chlorine anion + Chloromethane = (Chlorine anion bullet Chloromethane)

By formula: Cl- + CH3Cl = (Cl- bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar11.7 ± 2.0kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar12.2 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar8.60 ± 0.20kcal/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Deltar15.2 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B
Quantity Value Units Method Reference Comment
Deltar20.5cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar15.3cal/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar5.80 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar4.84kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Deltar6.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar4.10 ± 0.50kcal/molTDAsDougherty, Dalton, et al., 1974gas phase; B
Deltar10.8 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B

Chlorine anion + Methyl fluoride = (Chlorine anion bullet Methyl fluoride)

By formula: Cl- + CH3F = (Cl- bullet CH3F)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.3cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar5.4kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Silane, trifluoromethyl- = (Chlorine anion bullet Silane, trifluoromethyl-)

By formula: Cl- + CH3F3Si = (Cl- bullet CH3F3Si)

Quantity Value Units Method Reference Comment
Deltar16.1 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar9.5 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Methane, iodo- = (Chlorine anion bullet Methane, iodo-)

By formula: Cl- + CH3I = (Cl- bullet CH3I)

Quantity Value Units Method Reference Comment
Deltar9.80 ± 0.20kcal/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar7.3cal/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar7.0 ± 1.3kcal/molTDAsDougherty and Roberts, 1974gas phase; B

Chlorine anion + Methane, nitro- = (Chlorine anion bullet Methane, nitro-)

By formula: Cl- + CH3NO2 = (Cl- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar15.60 ± 0.60kcal/molTDAsWincel, 2003gas phase; B
Deltar16.70 ± 0.10kcal/molTDAsSieck, 1985gas phase; B,M
Deltar16.3 ± 3.0kcal/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Deltar17.1cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.20kcal/molTDAsWincel, 2003gas phase; B
Deltar11.60 ± 0.10kcal/molTDAsSieck, 1985gas phase; B

(Chlorine anion bullet Methane, nitro-) + Methane, nitro- = (Chlorine anion bullet 2Methane, nitro-)

By formula: (Cl- bullet CH3NO2) + CH3NO2 = (Cl- bullet 2CH3NO2)

Quantity Value Units Method Reference Comment
Deltar13.00 ± 0.50kcal/molTDAsWincel, 2003gas phase; B
Deltar13.10 ± 0.10kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.3cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.70kcal/molTDAsWincel, 2003gas phase; B
Deltar7.60 ± 0.30kcal/molTDAsSieck, 1985gas phase; B

Chlorine anion + Methyl Alcohol = (Chlorine anion bullet Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar17. ± 3.kcal/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar24.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.0cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar22.9cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar14.8cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar10.1 ± 0.8kcal/molAVGN/AAverage of 10 values; Individual data points

(Chlorine anion bullet Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol)

By formula: (Cl- bullet CH4O) + CH4O = (Cl- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar14.10 ± 0.40kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13.70 ± 0.20kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar14.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar13.00 ± 0.70kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.0cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar19.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar7.10kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar6.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar7.20 ± 0.40kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 3Methyl Alcohol)

By formula: (Cl- bullet 2CH4O) + CH4O = (Cl- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar11.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.80 ± 0.30kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
Deltar11.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar12.30 ± 0.60kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar22.7cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
Deltar23.6cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.00kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar4.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar5.20 ± 0.30kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 4Methyl Alcohol)

By formula: (Cl- bullet 3CH4O) + CH4O = (Cl- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar10.50kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar11.20 ± 0.60kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar26.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar3.70kcal/molTDAsEvans and Keesee, 1991gas phase; B
Deltar3.30 ± 0.20kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 5Methyl Alcohol)

By formula: (Cl- bullet 4CH4O) + CH4O = (Cl- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar10.50 ± 0.50kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar25.5cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar2.90 ± 0.10kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 6Methyl Alcohol)

By formula: (Cl- bullet 5CH4O) + CH4O = (Cl- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar8.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 7Methyl Alcohol)

By formula: (Cl- bullet 6CH4O) + CH4O = (Cl- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar8.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 8Methyl Alcohol)

By formula: (Cl- bullet 7CH4O) + CH4O = (Cl- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar7.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 9Methyl Alcohol)

By formula: (Cl- bullet 8CH4O) + CH4O = (Cl- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar7.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.6cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 10Methyl Alcohol)

By formula: (Cl- bullet 9CH4O) + CH4O = (Cl- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 10Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 11Methyl Alcohol)

By formula: (Cl- bullet 10CH4O) + CH4O = (Cl- bullet 11CH4O)

Quantity Value Units Method Reference Comment
Deltar7.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion bullet Methyl Alcohol) + Water = (Chlorine anion bullet Water bullet Methyl Alcohol)

By formula: (Cl- bullet CH4O) + H2O = (Cl- bullet H2O bullet CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.9kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar16.9cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet 2Methyl Alcohol) + Water = (Chlorine anion bullet Water bullet 2Methyl Alcohol)

By formula: (Cl- bullet 2CH4O) + H2O = (Cl- bullet H2O bullet 2CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar7.7kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar11.cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet Methyl Alcohol bullet Water) + Methyl Alcohol = (Chlorine anion bullet 2Methyl Alcohol bullet Water)

By formula: (Cl- bullet CH4O bullet H2O) + CH4O = (Cl- bullet 2CH4O bullet H2O)

Quantity Value Units Method Reference Comment
Deltar10.8kcal/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.cal/mol*KHPMSEvans and Keesee, 1991gas phase; M

Chlorine anion + Methanethiol = (Chlorine anion bullet Methanethiol)

By formula: Cl- + CH4S = (Cl- bullet CH4S)

Quantity Value Units Method Reference Comment
Deltar15.5 ± 3.0kcal/molIMRBStaneke, Groothuis, et al., 1995gas phase; Chloride affinity comparable to that of CHCl3; B
Quantity Value Units Method Reference Comment
Deltar10.8 ± 3.0kcal/molIMRBStaneke, Groothuis, et al., 1995gas phase; Chloride affinity comparable to that of CHCl3; B

Chlorine anion + Methane = CH4Cl-

By formula: Cl- + CH4 = CH4Cl-

Quantity Value Units Method Reference Comment
Deltar3.80kcal/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar-2.16kcal/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

Chlorine anion + Carbon dioxide = (Chlorine anion bullet Carbon dioxide)

By formula: Cl- + CO2 = (Cl- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar6.80 ± 0.50kcal/molPDisArnold, Bradforth, et al., 1995gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Deltar7.60kcal/molTDEqHiraoka, Shoda, et al., 1986gas phase; B,M
Deltar8.00 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Deltar19.6cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.10kcal/molTDEqHiraoka, Shoda, et al., 1986gas phase; B
Deltar2.10 ± 0.10kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Chlorine anion bullet Carbon dioxide) + Carbon dioxide = (Chlorine anion bullet 2Carbon dioxide)

By formula: (Cl- bullet CO2) + CO2 = (Cl- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar7.2 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar7.20kcal/molTDAsHiraoka, Shoda, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.8cal/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar-1.4 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar1.00kcal/molTDAsHiraoka, Shoda, et al., 1986gas phase; B

(Chlorine anion bullet 2Carbon dioxide) + Carbon dioxide = (Chlorine anion bullet 3Carbon dioxide)

By formula: (Cl- bullet 2CO2) + CO2 = (Cl- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar6.8 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar6.80kcal/molTDAsHiraoka, Shoda, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.4cal/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Deltar0.10kcal/molTDAsHiraoka, Shoda, et al., 1986gas phase; B

(Chlorine anion bullet 3Carbon dioxide) + Carbon dioxide = (Chlorine anion bullet 4Carbon dioxide)

By formula: (Cl- bullet 3CO2) + CO2 = (Cl- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar6.40kcal/molTDAsHiraoka, Shoda, et al., 1986gas phase; entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar-0.80kcal/molTDAsHiraoka, Shoda, et al., 1986gas phase; entropy estimated.; B

Chlorine anion + Carbon disulfide = (Chlorine anion bullet Carbon disulfide)

By formula: Cl- + CS2 = (Cl- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar8.80 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar11.7 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar13.9cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Deltar20.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.6 ± 2.2kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar5.7 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

(Chlorine anion bullet Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 2Carbon disulfide)

By formula: (Cl- bullet CS2) + CS2 = (Cl- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar7.70 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar15.8cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.0 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 3Carbon disulfide)

By formula: (Cl- bullet 2CS2) + CS2 = (Cl- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar7.20 ± 0.20kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.3cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 3Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 4Carbon disulfide)

By formula: (Cl- bullet 3CS2) + CS2 = (Cl- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar6.8 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B
Quantity Value Units Method Reference Comment
Deltar-0.1 ± 1.0kcal/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + C2ClF3O = (Chlorine anion bullet C2ClF3O)

By formula: Cl- + C2ClF3O = (Cl- bullet C2ClF3O)

Quantity Value Units Method Reference Comment
Deltar17.8 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.2 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + C2F4O = (Chlorine anion bullet C2F4O)

By formula: Cl- + C2F4O = (Cl- bullet C2F4O)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.1 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Ethene, tetrafluoro- = C2ClF4-

By formula: Cl- + C2F4 = C2ClF4-

Quantity Value Units Method Reference Comment
Deltar>10.00kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B
Quantity Value Units Method Reference Comment
Deltar2.55kcal/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B

Chlorine anion + Pentafluorodimethyl ether = (Chlorine anion bullet Pentafluorodimethyl ether)

By formula: Cl- + C2HF5O = (Cl- bullet C2HF5O)

Quantity Value Units Method Reference Comment
Deltar17.50 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.3 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Deltar12.1 ± 2.0kcal/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + Ethane, pentafluoro- = (Chlorine anion bullet Ethane, pentafluoro-)

By formula: Cl- + C2HF5 = (Cl- bullet C2HF5)

Quantity Value Units Method Reference Comment
Deltar18.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.3cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar11.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 1,1,1',1'-Tetrafluorodimethyl ether = (Chlorine anion bullet 1,1,1',1'-Tetrafluorodimethyl ether)

By formula: Cl- + C2H2F4O = (Cl- bullet C2H2F4O)

Quantity Value Units Method Reference Comment
Deltar28.20 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.8 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Deltar17.0 ± 2.0kcal/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + Acetic acid, chloro- = (Chlorine anion bullet Acetic acid, chloro-)

By formula: Cl- + C2H3ClO2 = (Cl- bullet C2H3ClO2)

Quantity Value Units Method Reference Comment
Deltar14.1 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.8 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B

Chlorine anion + C2H3ClO2 = (Chlorine anion bullet C2H3ClO2)

By formula: Cl- + C2H3ClO2 = (Cl- bullet C2H3ClO2)

Quantity Value Units Method Reference Comment
Deltar14.1kcal/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar7.8kcal/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Ethanol, 2,2,2-trifluoro- = (Chlorine anion bullet Ethanol, 2,2,2-trifluoro-)

By formula: Cl- + C2H3F3O = (Cl- bullet C2H3F3O)

Quantity Value Units Method Reference Comment
Deltar24.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar16.5 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 1,1,2-Trifluoroethane = (Chlorine anion bullet 1,1,2-Trifluoroethane)

By formula: Cl- + C2H3F3 = (Cl- bullet C2H3F3)

Quantity Value Units Method Reference Comment
Deltar18.9kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar11.4kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Acetonitrile = (Chlorine anion bullet Acetonitrile)

By formula: Cl- + C2H3N = (Cl- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar15. ± 2.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar15.7cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar15.7cal/mol*KPHPMSYamabe, Furumiya, et al., 1986gas phase; M
Deltar14.3cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar14.3cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Deltar21.4cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar10.20 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar9.2 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar8.9 ± 2.6kcal/molTDAsYamabe, Furumiya, et al., 1986gas phase; B
Deltar10.10 ± 0.20kcal/molTDAsSieck, 1985gas phase; B
Deltar9.2 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet Acetonitrile) + Acetonitrile = (Chlorine anion bullet 2Acetonitrile)

By formula: (Cl- bullet C2H3N) + C2H3N = (Cl- bullet 2C2H3N)

Quantity Value Units Method Reference Comment
Deltar12.50 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.00 ± 0.70kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar12.20kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar16.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar18.9cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.6 ± 1.2kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar6.60kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet 2Acetonitrile) + Acetonitrile = (Chlorine anion bullet 3Acetonitrile)

By formula: (Cl- bullet 2C2H3N) + C2H3N = (Cl- bullet 3C2H3N)

Quantity Value Units Method Reference Comment
Deltar11.20 ± 0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar12.00 ± 0.70kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar10.60kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar20.1cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.3 ± 1.3kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar4.60kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet 3Acetonitrile) + Acetonitrile = (Chlorine anion bullet 4Acetonitrile)

By formula: (Cl- bullet 3C2H3N) + C2H3N = (Cl- bullet 4C2H3N)

Quantity Value Units Method Reference Comment
Deltar10.90 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar9.00 ± 0.80kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Deltar6.20kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar10.8cal/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar2.9 ± 1.2kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar3.00kcal/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion bullet 4Acetonitrile) + Acetonitrile = (Chlorine anion bullet 5Acetonitrile)

By formula: (Cl- bullet 4C2H3N) + C2H3N = (Cl- bullet 5C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.80 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar5.80 ± 0.90kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar27.1cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.70 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion bullet 5Acetonitrile) + Acetonitrile = (Chlorine anion bullet 6Acetonitrile)

By formula: (Cl- bullet 5C2H3N) + C2H3N = (Cl- bullet 6C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.50 ± 0.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar5.8 ± 1.0kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar29.1cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.80 ± 0.80kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion bullet 6Acetonitrile) + Acetonitrile = (Chlorine anion bullet 7Acetonitrile)

By formula: (Cl- bullet 6C2H3N) + C2H3N = (Cl- bullet 7C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.40 ± 0.30kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar3.9 ± 1.1kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar30.7cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.2 ± 1.4kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion bullet 7Acetonitrile) + Acetonitrile = (Chlorine anion bullet 8Acetonitrile)

By formula: (Cl- bullet 7C2H3N) + C2H3N = (Cl- bullet 8C2H3N)

Quantity Value Units Method Reference Comment
Deltar9.20kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Deltar2.8 ± 1.2kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar32.cal/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar-0.40kcal/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Chlorine anion bullet 8Acetonitrile) + Acetonitrile = (Chlorine anion bullet 9Acetonitrile)

By formula: (Cl- bullet 8C2H3N) + C2H3N = (Cl- bullet 9C2H3N)

Quantity Value Units Method Reference Comment
Deltar4.4 ± 1.4kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 9Acetonitrile) + Acetonitrile = (Chlorine anion bullet 10Acetonitrile)

By formula: (Cl- bullet 9C2H3N) + C2H3N = (Cl- bullet 10C2H3N)

Quantity Value Units Method Reference Comment
Deltar2.1 ± 1.5kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 10Acetonitrile) + Acetonitrile = (Chlorine anion bullet 11Acetonitrile)

By formula: (Cl- bullet 10C2H3N) + C2H3N = (Cl- bullet 11C2H3N)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 1.6kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 11Acetonitrile) + Acetonitrile = (Chlorine anion bullet 12Acetonitrile)

By formula: (Cl- bullet 11C2H3N) + C2H3N = (Cl- bullet 12C2H3N)

Quantity Value Units Method Reference Comment
Deltar-0.5 ± 1.7kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 12Acetonitrile) + Acetonitrile = (Chlorine anion bullet 13Acetonitrile)

By formula: (Cl- bullet 12C2H3N) + C2H3N = (Cl- bullet 13C2H3N)

Quantity Value Units Method Reference Comment
Deltar0.9 ± 1.8kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 13Acetonitrile) + Acetonitrile = (Chlorine anion bullet 14Acetonitrile)

By formula: (Cl- bullet 13C2H3N) + C2H3N = (Cl- bullet 14C2H3N)

Quantity Value Units Method Reference Comment
Deltar-0.5 ± 1.9kcal/molN/AMarkovich, Perera, et al., 1996gas phase; B

Chlorine anion + Ethane, 1,1-difluoro- = (Chlorine anion bullet Ethane, 1,1-difluoro-)

By formula: Cl- + C2H4F2 = (Cl- bullet C2H4F2)

Quantity Value Units Method Reference Comment
Deltar14.9 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.7cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar8.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2,2,2-Trifluoroethylamine = (Chlorine anion bullet 2,2,2-Trifluoroethylamine)

By formula: Cl- + C2H4F3N = (Cl- bullet C2H4F3N)

Quantity Value Units Method Reference Comment
Deltar18.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar10.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Acetaldehyde = (Chlorine anion bullet Acetaldehyde)

By formula: Cl- + C2H4O = (Cl- bullet C2H4O)

Quantity Value Units Method Reference Comment
Deltar14.4 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar7.9 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Acetic acid = (Chlorine anion bullet Acetic acid)

By formula: Cl- + C2H4O2 = (Cl- bullet C2H4O2)

Quantity Value Units Method Reference Comment
Deltar24.40 ± 0.20kcal/molTDAsSieck, 1985gas phase; B,M
Deltar21.6 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Deltar23.9 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar24.0cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar19.3cal/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.60 ± 0.30kcal/molTDAsSieck, 1985gas phase; B
Deltar15.8 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B
Deltar16.7 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl bromide = (Chlorine anion bullet Ethyl bromide)

By formula: Cl- + C2H5Br = (Cl- bullet C2H5Br)

Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.92 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + 2-Chloroethanol = (Chlorine anion bullet 2-Chloroethanol)

By formula: Cl- + C2H5ClO = (Cl- bullet C2H5ClO)

Quantity Value Units Method Reference Comment
Deltar21.5 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)FCH2CH2OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar14.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl Chloride = (Chlorine anion bullet Ethyl Chloride)

By formula: Cl- + C2H5Cl = (Cl- bullet C2H5Cl)

Quantity Value Units Method Reference Comment
Deltar12.4 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar14.5 ± 4.5kcal/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Deltar6.80 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Ethanol, 2-fluoro- = (Chlorine anion bullet Ethanol, 2-fluoro-)

By formula: Cl- + C2H5FO = (Cl- bullet C2H5FO)

Quantity Value Units Method Reference Comment
Deltar20.5 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Dimethyl Sulfoxide = (Chlorine anion bullet Dimethyl Sulfoxide)

By formula: Cl- + C2H6OS = (Cl- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar18.60kcal/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.50kcal/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

(Chlorine anion bullet Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 2Dimethyl Sulfoxide)

By formula: (Cl- bullet C2H6OS) + C2H6OS = (Cl- bullet 2C2H6OS)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.8cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 2Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 3Dimethyl Sulfoxide)

By formula: (Cl- bullet 2C2H6OS) + C2H6OS = (Cl- bullet 3C2H6OS)

Quantity Value Units Method Reference Comment
Deltar14.9kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.8cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 3Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 4Dimethyl Sulfoxide)

By formula: (Cl- bullet 3C2H6OS) + C2H6OS = (Cl- bullet 4C2H6OS)

Quantity Value Units Method Reference Comment
Deltar14.6kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar37.2cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 4Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 5Dimethyl Sulfoxide)

By formula: (Cl- bullet 4C2H6OS) + C2H6OS = (Cl- bullet 5C2H6OS)

Quantity Value Units Method Reference Comment
Deltar13.8kcal/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar40.2cal/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

Chlorine anion + Ethanol = (Chlorine anion bullet Ethanol)

By formula: Cl- + C2H6O = (Cl- bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar17.90 ± 0.40kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar17.60 ± 0.50kcal/molTDAsHiraoka, 1987gas phase; B,B,M
Deltar17.3 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar23.1cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar10.65kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.5 ± 2.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar10.5 ± 2.0kcal/molTDAsHiraoka, 1987gas phase; B
Deltar10.4 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.0295.ICRRiveros, 1974gas phase; switching reaction(Cl-)CH3OH; Riveros, Breda, et al., 1973; M

(Chlorine anion bullet Ethanol) + Ethanol = (Chlorine anion bullet 2Ethanol)

By formula: (Cl- bullet C2H6O) + C2H6O = (Cl- bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar15.30 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar16.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.34kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 2Ethanol) + Ethanol = (Chlorine anion bullet 3Ethanol)

By formula: (Cl- bullet 2C2H6O) + C2H6O = (Cl- bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar13.90 ± 0.70kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.8cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.16kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar5.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 3Ethanol) + Ethanol = (Chlorine anion bullet 4Ethanol)

By formula: (Cl- bullet 3C2H6O) + C2H6O = (Cl- bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar12.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar29.5cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 4Ethanol) + Ethanol = (Chlorine anion bullet 5Ethanol)

By formula: (Cl- bullet 4C2H6O) + C2H6O = (Cl- bullet 5C2H6O)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar30.6cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 5Ethanol) + Ethanol = (Chlorine anion bullet 6Ethanol)

By formula: (Cl- bullet 5C2H6O) + C2H6O = (Cl- bullet 6C2H6O)

Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.0cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Ethanol) + Ethanol = (Chlorine anion bullet 7Ethanol)

By formula: (Cl- bullet 6C2H6O) + C2H6O = (Cl- bullet 7C2H6O)

Quantity Value Units Method Reference Comment
Deltar9.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Ethanol) + Ethanol = (Chlorine anion bullet 8Ethanol)

By formula: (Cl- bullet 7C2H6O) + C2H6O = (Cl- bullet 8C2H6O)

Quantity Value Units Method Reference Comment
Deltar9.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 8Ethanol) + Ethanol = (Chlorine anion bullet 9Ethanol)

By formula: (Cl- bullet 8C2H6O) + C2H6O = (Cl- bullet 9C2H6O)

Quantity Value Units Method Reference Comment
Deltar9.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.5 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion bullet 9Ethanol) + Ethanol = (Chlorine anion bullet 10Ethanol)

By formula: (Cl- bullet 9C2H6O) + C2H6O = (Cl- bullet 10C2H6O)

Quantity Value Units Method Reference Comment
Deltar8.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
Deltar7.50 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.9 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 1,2-Ethanediol = (Chlorine anion bullet 1,2-Ethanediol)

By formula: Cl- + C2H6O2 = (Cl- bullet C2H6O2)

Quantity Value Units Method Reference Comment
Deltar25.3 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar16.6 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 1,2-Ethanediol) + 1,2-Ethanediol = (Chlorine anion bullet 21,2-Ethanediol)

By formula: (Cl- bullet C2H6O2) + C2H6O2 = (Cl- bullet 2C2H6O2)

Quantity Value Units Method Reference Comment
Deltar15.9 ± 1.2kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.3 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion bullet 2-Propanone, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3F6O = (Cl- bullet C3F6O)

Quantity Value Units Method Reference Comment
Deltar28.8 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar22.9 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.6 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar16.3 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Deltar16.3kcal/molICRLarson and McMahon, 1984, 3gas phase; switching reaction(Cl-)(C2H5)3B; M

Chlorine anion + Propene, hexafluoro- = C3ClF6-

By formula: Cl- + C3F6 = C3ClF6-

Quantity Value Units Method Reference Comment
Deltar12.60 ± 0.30kcal/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar5.15 ± 0.30kcal/molTDAsHiraoka, Takao, et al., 2002gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3-pentafluoro- = (Chlorine anion bullet 2-Propanone, 1,1,1,3,3-pentafluoro-)

By formula: Cl- + C3HF5O = (Cl- bullet C3HF5O)

Quantity Value Units Method Reference Comment
Deltar26.1 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar23.4kcal/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar23.9cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar17.2 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar16.3 ± 2.0kcal/molIMRELarson and McMahon, 1984, 3gas phase; B,M,M

Chlorine anion + 1,1,3,3-tetrafluoroacetone = (Chlorine anion bullet 1,1,3,3-tetrafluoroacetone)

By formula: Cl- + C3H2F4O = (Cl- bullet C3H2F4O)

Quantity Value Units Method Reference Comment
Deltar18.1 ± 2.0kcal/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + 2-Propanol, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion bullet 2-Propanol, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3H2F6O = (Cl- bullet C3H2F6O)

Quantity Value Units Method Reference Comment
Deltar26.5kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar19.0kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M

Chlorine anion + C3H3F3O- = C2H3ClF3O-

By formula: Cl- + C3H3F3O- = C2H3ClF3O-

Quantity Value Units Method Reference Comment
Deltar13.60 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.7 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 2-Propanone, 1,1,1-trifluoro- = C3H3ClF3O-

By formula: Cl- + C3H3F3O = C3H3ClF3O-

Quantity Value Units Method Reference Comment
Deltar13.7 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B

Chlorine anion + 2-Propanone, 1-fluoro- = C3H5ClFO-

By formula: Cl- + C3H5FO = C3H5ClFO-

Quantity Value Units Method Reference Comment
Deltar18.4 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.0kcal/molTDAsBofdanov and McMahon, 2002gas phase; B

Chlorine anion + 1,3-Difluoro-2-propanol = (Chlorine anion bullet 1,3-Difluoro-2-propanol)

By formula: Cl- + C3H6F2O = (Cl- bullet C3H6F2O)

Quantity Value Units Method Reference Comment
Deltar23.6kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar16.1kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Acetone = (Chlorine anion bullet Acetone)

By formula: Cl- + C3H6O = (Cl- bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar14. ± 2.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar18.2cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar19.6cal/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Deltar17.1cal/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar19.7cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar8.08 ± 0.20kcal/molTDAsBofdanov and McMahon, 2002gas phase; B
Deltar7.30kcal/molTDAsHiraoka, Morise, et al., 1986gas phase; B
Deltar8.80 ± 0.30kcal/molTDAsSieck, 1985gas phase; B
Deltar8.2 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar7.9 ± 2.0kcal/molTDAsFrench, Ikuta, et al., 1982gas phase; B

(Chlorine anion bullet Acetone) + Acetone = (Chlorine anion bullet 2Acetone)

By formula: (Cl- bullet C3H6O) + C3H6O = (Cl- bullet 2C3H6O)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 1.0kcal/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.3cal/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.4 ± 2.2kcal/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B

(Chlorine anion bullet 2Acetone) + Acetone = (Chlorine anion bullet 3Acetone)

By formula: (Cl- bullet 2C3H6O) + C3H6O = (Cl- bullet 3C3H6O)

Quantity Value Units Method Reference Comment
Deltar10.4 ± 2.0kcal/molTDAsHiraoka, Takimoto, et al., 1986gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka, Takimoto, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3.8 ± 4.5kcal/molTDAsHiraoka, Takimoto, et al., 1986gas phase; Entropy estimated; B

Chlorine anion + Propane, 2-bromo- = (Chlorine anion bullet Propane, 2-bromo-)

By formula: Cl- + C3H7Br = (Cl- bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar15.2 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.52 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 1-bromo- = (Chlorine anion bullet Propane, 1-bromo-)

By formula: Cl- + C3H7Br = (Cl- bullet C3H7Br)

Quantity Value Units Method Reference Comment
Deltar14.2 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.24 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 2-chloro- = (Chlorine anion bullet Propane, 2-chloro-)

By formula: Cl- + C3H7Cl = (Cl- bullet C3H7Cl)

Quantity Value Units Method Reference Comment
Deltar14.7 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.80 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Isopropyl Alcohol = (Chlorine anion bullet Isopropyl Alcohol)

By formula: Cl- + C3H8O = (Cl- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar19.40 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar18.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Deltar17.6 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar24.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar23.2cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar11.32kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar10.90kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar10.7 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion bullet Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 2Isopropyl Alcohol)

By formula: (Cl- bullet C3H8O) + C3H8O = (Cl- bullet 2C3H8O)

Quantity Value Units Method Reference Comment
Deltar16.70 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar15.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.67kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar8.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 2Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 3Isopropyl Alcohol)

By formula: (Cl- bullet 2C3H8O) + C3H8O = (Cl- bullet 3C3H8O)

Quantity Value Units Method Reference Comment
Deltar14.90 ± 0.50kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.5 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 3Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 4Isopropyl Alcohol)

By formula: (Cl- bullet 3C3H8O) + C3H8O = (Cl- bullet 4C3H8O)

Quantity Value Units Method Reference Comment
Deltar11.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar28.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 4Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 5Isopropyl Alcohol)

By formula: (Cl- bullet 4C3H8O) + C3H8O = (Cl- bullet 5C3H8O)

Quantity Value Units Method Reference Comment
Deltar11.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar30.5cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 5Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 6Isopropyl Alcohol)

By formula: (Cl- bullet 5C3H8O) + C3H8O = (Cl- bullet 6C3H8O)

Quantity Value Units Method Reference Comment
Deltar11.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 7Isopropyl Alcohol)

By formula: (Cl- bullet 6C3H8O) + C3H8O = (Cl- bullet 7C3H8O)

Quantity Value Units Method Reference Comment
Deltar11.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.3cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 8Isopropyl Alcohol)

By formula: (Cl- bullet 7C3H8O) + C3H8O = (Cl- bullet 8C3H8O)

Quantity Value Units Method Reference Comment
Deltar10.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar31.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + 1-Propanol = (Chlorine anion bullet 1-Propanol)

By formula: Cl- + C3H8O = (Cl- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar20.40 ± 0.50kcal/molTDAsHiraoka, 1987gas phase; B,B,M
Deltar17.7 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar29.0cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar23.2cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar11.70kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar11.7 ± 2.0kcal/molTDAsHiraoka, 1987gas phase; B
Deltar10.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion bullet 1-Propanol) + 1-Propanol = (Chlorine anion bullet 21-Propanol)

By formula: (Cl- bullet C3H8O) + C3H8O = (Cl- bullet 2C3H8O)

Quantity Value Units Method Reference Comment
Deltar15.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.4cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 21-Propanol) + 1-Propanol = (Chlorine anion bullet 31-Propanol)

By formula: (Cl- bullet 2C3H8O) + C3H8O = (Cl- bullet 3C3H8O)

Quantity Value Units Method Reference Comment
Deltar14.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 31-Propanol) + 1-Propanol = (Chlorine anion bullet 41-Propanol)

By formula: (Cl- bullet 3C3H8O) + C3H8O = (Cl- bullet 4C3H8O)

Quantity Value Units Method Reference Comment
Deltar13.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar32.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 41-Propanol) + 1-Propanol = (Chlorine anion bullet 51-Propanol)

By formula: (Cl- bullet 4C3H8O) + C3H8O = (Cl- bullet 5C3H8O)

Quantity Value Units Method Reference Comment
Deltar12.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar32.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 51-Propanol) + 1-Propanol = (Chlorine anion bullet 61-Propanol)

By formula: (Cl- bullet 5C3H8O) + C3H8O = (Cl- bullet 6C3H8O)

Quantity Value Units Method Reference Comment
Deltar11.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.0cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 61-Propanol) + 1-Propanol = (Chlorine anion bullet 71-Propanol)

By formula: (Cl- bullet 6C3H8O) + C3H8O = (Cl- bullet 7C3H8O)

Quantity Value Units Method Reference Comment
Deltar11.0 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar30.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 71-Propanol) + 1-Propanol = (Chlorine anion bullet 81-Propanol)

By formula: (Cl- bullet 7C3H8O) + C3H8O = (Cl- bullet 8C3H8O)

Quantity Value Units Method Reference Comment
Deltar10.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar30.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + C3H9ClGe = C3H9Cl2Ge-

By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-

Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.4kcal/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Silane, chlorotrimethyl- = C3H9Cl2Si-

By formula: Cl- + C3H9ClSi = C3H9Cl2Si-

Quantity Value Units Method Reference Comment
Deltar14.3 ± 1.4kcal/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Stannane, chlorotrimethyl- = C3H9Cl2Sn-

By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-

Quantity Value Units Method Reference Comment
Deltar31.3 ± 1.7kcal/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + C4H4F6O = (Chlorine anion bullet C4H4F6O)

By formula: Cl- + C4H4F6O = (Cl- bullet C4H4F6O)

Quantity Value Units Method Reference Comment
Deltar26.5kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar19.0kcal/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, «DELTA»rH>; Larson and McMahon, 1984, 2; M

Chlorine anion + Pyrrole = (Chlorine anion bullet Pyrrole)

By formula: Cl- + C4H5N = (Cl- bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar18.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B
Deltar14.00kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.6421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 2-Butyne-1,4-diol = (Chlorine anion bullet 2-Butyne-1,4-diol)

By formula: Cl- + C4H6O2 = (Cl- bullet C4H6O2)

Quantity Value Units Method Reference Comment
Deltar28.9 ± 1.1kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.0 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 2-Butyne-1,4-diol) + 2-Butyne-1,4-diol = (Chlorine anion bullet 22-Butyne-1,4-diol)

By formula: (Cl- bullet C4H6O2) + C4H6O2 = (Cl- bullet 2C4H6O2)

Quantity Value Units Method Reference Comment
Deltar22.30 ± 0.70kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.9 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + 2-Butanone = (Chlorine anion bullet 2-Butanone)

By formula: Cl- + C4H8O = (Cl- bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar14.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CH3)2CO, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar8.5 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2-Butene-1,4-diol, (Z)- = (Chlorine anion bullet 2-Butene-1,4-diol, (Z)-)

By formula: Cl- + C4H8O2 = (Cl- bullet C4H8O2)

Quantity Value Units Method Reference Comment
Deltar32.9 ± 1.5kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar19.7 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 2-Butene-1,4-diol, (Z)-) + 2-Butene-1,4-diol, (Z)- = (Chlorine anion bullet 22-Butene-1,4-diol, (Z)-)

By formula: (Cl- bullet C4H8O2) + C4H8O2 = (Cl- bullet 2C4H8O2)

Quantity Value Units Method Reference Comment
Deltar22.90 ± 0.40kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.7 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + Propane, 2-bromo-2-methyl- = (Chlorine anion bullet Propane, 2-bromo-2-methyl-)

By formula: Cl- + C4H9Br = (Cl- bullet C4H9Br)

Quantity Value Units Method Reference Comment
Deltar17.7 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.90 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 2-chloro-2-methyl- = (Chlorine anion bullet Propane, 2-chloro-2-methyl-)

By formula: Cl- + C4H9Cl = (Cl- bullet C4H9Cl)

Quantity Value Units Method Reference Comment
Deltar16.6 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar14.3 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.2cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar8.30 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Deltar8.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Propane, 2-fluoro-2-methyl- = (Chlorine anion bullet Propane, 2-fluoro-2-methyl-)

By formula: Cl- + C4H9F = (Cl- bullet C4H9F)

Quantity Value Units Method Reference Comment
Deltar13.3 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.8cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl ether = C4H10ClO-

By formula: Cl- + C4H10O = C4H10ClO-

Quantity Value Units Method Reference Comment
Deltar9.00 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 1-Butanol = (Chlorine anion bullet 1-Butanol)

By formula: Cl- + C4H10O = (Cl- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar17.6 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.2cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar10.7 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2-Propanol, 2-methyl- = (Chlorine anion bullet 2-Propanol, 2-methyl-)

By formula: Cl- + C4H10O = (Cl- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar19. ± 4.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar27.4cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Deltar24.0cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar23.4cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar27.cal/mol*KPHPMSKebarle, 1977gas phase; M
Deltar10.3cal/mol*KN/AYamdagni and Kebarle, 1971gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar11.58kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar12.30 ± 0.30kcal/molTDAsSieck, 1985gas phase; B
Deltar11.60kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
Deltar11.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar11.1 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B

(Chlorine anion bullet 2-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 22-Propanol, 2-methyl-)

By formula: (Cl- bullet C4H10O) + C4H10O = (Cl- bullet 2C4H10O)

Quantity Value Units Method Reference Comment
Deltar16.90 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar14.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar25.8cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.36kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar7.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 22-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 32-Propanol, 2-methyl-)

By formula: (Cl- bullet 2C4H10O) + C4H10O = (Cl- bullet 3C4H10O)

Quantity Value Units Method Reference Comment
Deltar15.80 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar13.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.0cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.07kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Deltar4.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 32-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 42-Propanol, 2-methyl-)

By formula: (Cl- bullet 3C4H10O) + C4H10O = (Cl- bullet 4C4H10O)

Quantity Value Units Method Reference Comment
Deltar12.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.3cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 42-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 52-Propanol, 2-methyl-)

By formula: (Cl- bullet 4C4H10O) + C4H10O = (Cl- bullet 5C4H10O)

Quantity Value Units Method Reference Comment
Deltar11.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar32.3cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 52-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 62-Propanol, 2-methyl-)

By formula: (Cl- bullet 5C4H10O) + C4H10O = (Cl- bullet 6C4H10O)

Quantity Value Units Method Reference Comment
Deltar11.4 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar32.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + 1,4-Butanediol = (Chlorine anion bullet 1,4-Butanediol)

By formula: Cl- + C4H10O2 = (Cl- bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar30.2 ± 1.7kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar17.5 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion bullet 1,4-Butanediol) + 1,4-Butanediol = (Chlorine anion bullet 21,4-Butanediol)

By formula: (Cl- bullet C4H10O2) + C4H10O2 = (Cl- bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar21.20 ± 0.80kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.6 ± 1.0kcal/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + Cyclopentene, octafluoro- = C5ClF8-

By formula: Cl- + C5F8 = C5ClF8-

Quantity Value Units Method Reference Comment
Deltar13.80 ± 0.20kcal/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Quantity Value Units Method Reference Comment
Deltar8.14 ± 0.20kcal/molTDAsHiraoka, Fujita, et al., 1905gas phase; B

Chlorine anion + Iron pentacarbonyl = (Chlorine anion bullet Iron pentacarbonyl)

By formula: Cl- + C5FeO5 = (Cl- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar13.9 ± 3.0kcal/molIMRBLane, Sallans, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar7.9 ± 3.0kcal/molIMRBLane, Sallans, et al., 1985gas phase; B

Chlorine anion + Pyridine = (Chlorine anion bullet Pyridine)

By formula: Cl- + C5H5N = (Cl- bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar12.7 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.7cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.8 ± 2.6kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

(Chlorine anion bullet Pyridine) + Pyridine = (Chlorine anion bullet 2Pyridine)

By formula: (Cl- bullet C5H5N) + C5H5N = (Cl- bullet 2C5H5N)

Quantity Value Units Method Reference Comment
Deltar11.7kcal/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M

Chlorine anion + 1,3-Cyclopentadiene = (Chlorine anion bullet 1,3-Cyclopentadiene)

By formula: Cl- + C5H6 = (Cl- bullet C5H6)

Quantity Value Units Method Reference Comment
Deltar<2.50kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.5300.PHPMSFrench, Ikuta, et al., 1982gas phase; DG<; M

Chlorine anion + Acetylacetone = (Chlorine anion bullet Acetylacetone)

By formula: Cl- + C5H8O2 = (Cl- bullet C5H8O2)

Quantity Value Units Method Reference Comment
Deltar13.40kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
11.0421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 1,4-Pentadiene = (Chlorine anion bullet 1,4-Pentadiene)

By formula: Cl- + C5H8 = (Cl- bullet C5H8)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.7300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 1,3-Pentadiene, (E)- = (Chlorine anion bullet 1,3-Pentadiene, (E)-)

By formula: Cl- + C5H8 = (Cl- bullet C5H8)

Quantity Value Units Method Reference Comment
Deltar3.70kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Propanenitrile, 2,2-dimethyl- = (Chlorine anion bullet Propanenitrile, 2,2-dimethyl-)

By formula: Cl- + C5H9N = (Cl- bullet C5H9N)

Quantity Value Units Method Reference Comment
Deltar18.5 ± 1.0kcal/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.05 ± 0.20kcal/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + 3-Pentanone = (Chlorine anion bullet 3-Pentanone)

By formula: Cl- + C5H10O = (Cl- bullet C5H10O)

Quantity Value Units Method Reference Comment
Deltar14.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CH3)2CO, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar8.2 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Propanal, 2,2-dimethyl- = (Chlorine anion bullet Propanal, 2,2-dimethyl-)

By formula: Cl- + C5H10O = (Cl- bullet C5H10O)

Quantity Value Units Method Reference Comment
Deltar15.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.9cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + p-Benzoquinone, 2,3,5,6-tetrafluoro- = (Chlorine anion bullet p-Benzoquinone, 2,3,5,6-tetrafluoro-)

By formula: Cl- + C6F4O2 = (Cl- bullet C6F4O2)

Quantity Value Units Method Reference Comment
Deltar27.0 ± 1.0kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.7cal/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.2 ± 1.6kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzene, hexafluoro- = (Chlorine anion bullet Benzene, hexafluoro-)

By formula: Cl- + C6F6 = (Cl- bullet C6F6)

Quantity Value Units Method Reference Comment
Deltar16.8 ± 1.0kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Deltar15.5 ± 1.0kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Deltar26.9cal/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 1.6kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B
Deltar8.7 ± 1.6kcal/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Chlorine anion bullet Benzene, hexafluoro-) + Benzene, hexafluoro- = (Chlorine anion bullet 2Benzene, hexafluoro-)

By formula: (Cl- bullet C6F6) + C6F6 = (Cl- bullet 2C6F6)

Quantity Value Units Method Reference Comment
Deltar13.8kcal/molPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M

Chlorine anion + Benzene, 1-fluoro-3-nitro- = (Chlorine anion bullet Benzene, 1-fluoro-3-nitro-)

By formula: Cl- + C6H4FNO2 = (Cl- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar18.7 ± 1.0kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.2cal/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar12.3 ± 1.6kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzene, 1,2-difluoro- = (Chlorine anion bullet Benzene, 1,2-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- bullet C6H4F2)

Quantity Value Units Method Reference Comment
Deltar14.3 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar7.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Benzene, 1,3-difluoro- = (Chlorine anion bullet Benzene, 1,3-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- bullet C6H4F2)

Quantity Value Units Method Reference Comment
Deltar14.6 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.6cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar7.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar7.7 ± 1.0kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Benzene, 1,4-difluoro- = (Chlorine anion bullet Benzene, 1,4-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- bullet C6H4F2)

Quantity Value Units Method Reference Comment
Deltar13.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.6cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Deltar7.3 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Benzene, bromo- = (Chlorine anion bullet Benzene, bromo-)

By formula: Cl- + C6H5Br = (Cl- bullet C6H5Br)

Quantity Value Units Method Reference Comment
Deltar6.80kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B,M

Chlorine anion + Phenol, 4-chloro- = (Chlorine anion bullet Phenol, 4-chloro-)

By formula: Cl- + C6H5ClO = (Cl- bullet C6H5ClO)

Quantity Value Units Method Reference Comment
Deltar29.6 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Deltar30.1kcal/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar26.3cal/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar22.1 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
19.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
21.0300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzene, chloro- = (Chlorine anion bullet Benzene, chloro-)

By formula: Cl- + C6H5Cl = (Cl- bullet C6H5Cl)

Quantity Value Units Method Reference Comment
Deltar12.00 ± 0.10kcal/molTDAsSieck, 1985gas phase; B,M
Deltar13.6 ± 1.0kcal/molIMRELarson and McMahon, 1984, 2gas phase; B,B,M
Deltar12.6kcal/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar16.5cal/mol*KPHPMSSieck, 1985gas phase; M
Deltar22.4cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar7.10 ± 0.20kcal/molTDAsSieck, 1985gas phase; B
Deltar6.9 ± 1.0kcal/molIMRELarson and McMahon, 1984, 2gas phase; B,B,M
Deltar6.50kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
6.6300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
6.5300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phenol, 4-fluoro- = (Chlorine anion bullet Phenol, 4-fluoro-)

By formula: Cl- + C6H5FO = (Cl- bullet C6H5FO)

Quantity Value Units Method Reference Comment
Deltar27.9 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Deltar28.6kcal/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar25.3cal/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar20.6 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
18.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
19.3300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzene, fluoro- = (Chlorine anion bullet Benzene, fluoro-)

By formula: Cl- + C6H5F = (Cl- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar5.90kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.9300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, iodo- = (Chlorine anion bullet Benzene, iodo-)

By formula: Cl- + C6H5I = (Cl- bullet C6H5I)

Quantity Value Units Method Reference Comment
Deltar7.20kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.2300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, nitro- = (Chlorine anion bullet Benzene, nitro-)

By formula: Cl- + C6H5NO2 = (Cl- bullet C6H5NO2)

Quantity Value Units Method Reference Comment
Deltar16.3 ± 1.0kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Deltar16.5kcal/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar19.4cal/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.5 ± 1.6kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B
Deltar7.10kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.5300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
7.7300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phenol = (Chlorine anion bullet Phenol)

By formula: Cl- + C6H6O = (Cl- bullet C6H6O)

Quantity Value Units Method Reference Comment
Deltar26.0 ± 2.0kcal/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Deltar26.0 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Deltar27.4kcal/molPHPMSKebarle, 1977gas phase; M
Deltar26.5kcal/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar19.4 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.0cal/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Deltar25.cal/mol*KPHPMSKebarle, 1977gas phase; M
Deltar25.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar15.5cal/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.2 ± 2.0kcal/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Deltar18.5 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Deltar14.8 ± 2.0kcal/molTDAsYamdagni and Kebarle, 1971gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.9423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Chlorine anion + Benzene = (Chlorine anion bullet Benzene)

By formula: Cl- + C6H6 = (Cl- bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar6.00 ± 0.46kcal/molN/ATschurl, Ueberfluss, et al., 2007gas phase; B
Deltar9.4 ± 2.0kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Deltar9.90kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar8.7kcal/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar10.4kcal/molPHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Deltar17.cal/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Deltar17.1cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar22.cal/mol*KN/ASunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.0 ± 2.6kcal/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Deltar3.8 ± 1.6kcal/molIMREChowdhury and Kebarle, 1986gas phase; B
Deltar4.8 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar3.80kcal/molIMREFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.6300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
3.8300.PHPMSChowdhury and Kebarle, 1986gas phase; M
3.8300.PHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Chlorine anion + L-Alanine, N-acetyl-, methyl ester = (Chlorine anion bullet L-Alanine, N-acetyl-, methyl ester)

By formula: Cl- + C6H11NO3 = (Cl- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar29.4kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar29.4kcal/molPHPMSMeot-ner, 1988gas phase; CH3CO-Ala-OCH3; M
Quantity Value Units Method Reference Comment
Deltar28.3cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar28.3cal/mol*KPHPMSMeot-ner, 1988gas phase; CH3CO-Ala-OCH3; M

(Chlorine anion bullet L-Alanine, N-acetyl-, methyl ester) + L-Alanine, N-acetyl-, methyl ester = (Chlorine anion bullet 2L-Alanine, N-acetyl-, methyl ester)

By formula: (Cl- bullet C6H11NO3) + C6H11NO3 = (Cl- bullet 2C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar19.8kcal/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar19.8kcal/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.0cal/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M
Deltar27.0cal/mol*KPHPMSMeot-ner, 1988gas phase; M

Chlorine anion + CH3CONHCH(CH3)COOCH3 = (Chlorine anion bullet CH3CONHCH(CH3)COOCH3)

By formula: Cl- + C6H11NO3 = (Cl- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar29.4 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar20.9 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B

Chlorine anion + Borane, triethyl- = (Chlorine anion bullet Borane, triethyl-)

By formula: Cl- + C6H15B = (Cl- bullet C6H15B)

Quantity Value Units Method Reference Comment
Deltar23.8 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Deltar23.8kcal/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Deltar22.0cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar17.2 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Deltar17.2kcal/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzonitrile, pentafluoro- = (Chlorine anion bullet Benzonitrile, pentafluoro-)

By formula: Cl- + C7F5N = (Cl- bullet C7F5N)

Quantity Value Units Method Reference Comment
Deltar19.9cal/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.5 ± 1.6kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Perfluoro(methylcyclohexane) = (Chlorine anion bullet Perfluoro(methylcyclohexane))

By formula: Cl- + C7F14 = (Cl- bullet C7F14)

Quantity Value Units Method Reference Comment
Deltar<1.80kcal/molIMRBChowdhury and Kebarle, 1986gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
1.8300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

Chlorine anion + Benzene, 1-nitro-3-(trifluoromethyl)- = (Chlorine anion bullet Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: Cl- + C7H4F3NO2 = (Cl- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar19.5 ± 1.0kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.1 ± 1.6kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzonitrile, 4-nitro- = (Chlorine anion bullet Benzonitrile, 4-nitro-)

By formula: Cl- + C7H4N2O2 = (Cl- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar20.0 ± 1.0kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.0 ± 1.6kcal/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzonitrile, 4-hydroxy- = (Chlorine anion bullet Benzonitrile, 4-hydroxy-)

By formula: Cl- + C7H5NO = (Cl- bullet C7H5NO)

Quantity Value Units Method Reference Comment
Deltar35.1 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M,M
Deltar35.3kcal/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar28.cal/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar26.cal/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar27.3 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
24.7423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
26.2300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
25.8300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzonitrile = (Chlorine anion bullet Benzonitrile)

By formula: Cl- + C7H5N = (Cl- bullet C7H5N)

Quantity Value Units Method Reference Comment
Deltar16.0kcal/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
10.0300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M

Chlorine anion + Benzene, 1-methyl-4-nitro- = (Chlorine anion bullet Benzene, 1-methyl-4-nitro-)

By formula: Cl- + C7H7NO2 = (Cl- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar7.50kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.5300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Anisole = (Chlorine anion bullet Anisole)

By formula: Cl- + C7H8O = (Cl- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar7.30kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.3300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + p-Cresol = (Chlorine anion bullet p-Cresol)

By formula: Cl- + C7H8O = (Cl- bullet C7H8O)

Quantity Value Units Method Reference Comment
Deltar25.6 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Deltar25.9kcal/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.cal/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Deltar26.7cal/mol*KPHPMSCummings, French, et al., 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.9 ± 2.0kcal/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
15.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
16.6300.PHPMSCummings, French, et al., 1977gas phase; M

Chlorine anion + Toluene = (Chlorine anion bullet Toluene)

By formula: Cl- + C7H8 = (Cl- bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar4.00kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.0300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Acetophenone = (Chlorine anion bullet Acetophenone)

By formula: Cl- + C8H8O = (Cl- bullet C8H8O)

Quantity Value Units Method Reference Comment
Deltar9.50kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.1421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Ethylbenzene = (Chlorine anion bullet Ethylbenzene)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar5.00kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.0300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + p-Xylene = (Chlorine anion bullet p-Xylene)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar3.90kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.9300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, 1,3-dimethyl- = (Chlorine anion bullet Benzene, 1,3-dimethyl-)

By formula: Cl- + C8H10 = (Cl- bullet C8H10)

Quantity Value Units Method Reference Comment
Deltar3.90kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.4300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzyl methyl ketone = (Chlorine anion bullet Benzyl methyl ketone)

By formula: Cl- + C9H10O = (Cl- bullet C9H10O)

Quantity Value Units Method Reference Comment
Deltar10.70kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
8.3421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, (1-methylethyl)- = (Chlorine anion bullet Benzene, (1-methylethyl)-)

By formula: Cl- + C9H12 = (Cl- bullet C9H12)

Quantity Value Units Method Reference Comment
Deltar5.50kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.0300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, propyl- = (Chlorine anion bullet Benzene, propyl-)

By formula: Cl- + C9H12 = (Cl- bullet C9H12)

Quantity Value Units Method Reference Comment
Deltar5.00kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.5300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Mesitylene = (Chlorine anion bullet Mesitylene)

By formula: Cl- + C9H12 = (Cl- bullet C9H12)

Quantity Value Units Method Reference Comment
Deltar4.50kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.5300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Diphenylmethane = (Chlorine anion bullet Diphenylmethane)

By formula: Cl- + C13H12 = (Cl- bullet C13H12)

Quantity Value Units Method Reference Comment
Deltar7.40kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
7.4300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Triphenylmethane = (Chlorine anion bullet Triphenylmethane)

By formula: Cl- + C19H16 = (Cl- bullet C19H16)

Quantity Value Units Method Reference Comment
Deltar4.10kcal/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.1300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phosphorus difluoride monochloride = Cl2F2P-

By formula: Cl- + ClF2P = Cl2F2P-

Quantity Value Units Method Reference Comment
Deltar23.66kcal/molN/ACheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Cl2Nd = (Chlorine anion bullet Cl2Nd)

By formula: Cl- + Cl2Nd = (Cl- bullet Cl2Nd)

Quantity Value Units Method Reference Comment
Deltar65.5 ± 3.6kcal/molTDAsKudin, Pogrebnoi, et al., 1993gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Thionyl chloride = Cl3OS-

By formula: Cl- + Cl2OS = Cl3OS-

Quantity Value Units Method Reference Comment
Deltar20.4 ± 1.8kcal/molCIDTBachrach, Hayes, et al., 2001gas phase; B

Chlorine anion + seleninyl dichloride = Cl3OSe-

By formula: Cl- + Cl2OSe = Cl3OSe-

Quantity Value Units Method Reference Comment
Deltar35.80kcal/molN/ALobring, Hao, et al., 2003gas phase; B

Chlorine anion + Sulfur dichloride = Cl3S-

By formula: Cl- + Cl2S = Cl3S-

Quantity Value Units Method Reference Comment
Deltar20.3 ± 1.9kcal/molCIDTGailbreath, Pommerening, et al., 2000gas phase; B

Chlorine anion + Selenium dichloride = Cl3Se-

By formula: Cl- + Cl2Se = Cl3Se-

Quantity Value Units Method Reference Comment
Deltar31.8 ± 2.2kcal/molCIDTLobring, Hao, et al., 2003gas phase; B

Chlorine anion + Cl2Yb = (Chlorine anion bullet Cl2Yb)

By formula: Cl- + Cl2Yb = (Cl- bullet Cl2Yb)

Quantity Value Units Method Reference Comment
Deltar>56.40kcal/molN/AKuznetsov, Kudin, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Chlorine = (Chlorine anion bullet Chlorine)

By formula: Cl- + Cl2 = (Cl- bullet Cl2)

Quantity Value Units Method Reference Comment
Deltar17.0kcal/molSAMSRobbiani and Franklin, 1979gas phase; based on Cl- + SO2Cl2 <--> Cl3- + SO2; National Bureau of Standards, 1968; M

Chlorine anion + Chlorine = Cl3-

By formula: Cl- + Cl2 = Cl3-

Quantity Value Units Method Reference Comment
Deltar23.7 ± 1.2kcal/molCIDTNizzi, Pommerening, et al., 1998gas phase; B
Deltar16.70kcal/molTherRobbiani and Franklin, 1979, 2gas phase; «DELTA»G~=+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2; B
Deltar<43.60kcal/molPDisLee, Smith, et al., 1979gas phase; B

Chlorine anion + Cl3Er = Cl4Er-

By formula: Cl- + Cl3Er = Cl4Er-

Quantity Value Units Method Reference Comment
Deltar82.2 ± 5.0kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar78.1 ± 3.9kcal/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Cl3Er = Cl7Er2-

By formula: Cl- + Cl3Er = Cl7Er2-

Quantity Value Units Method Reference Comment
Deltar57.1 ± 8.8kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar81.2 ± 8.9kcal/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Cl3Er = Cl10Er3-

By formula: Cl- + Cl3Er = Cl10Er3-

Quantity Value Units Method Reference Comment
Deltar80. ± 14.kcal/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Trichlorofluorosilane = Cl4FSi-

By formula: Cl- + Cl3FSi = Cl4FSi-

Quantity Value Units Method Reference Comment
Deltar27.5 ± 1.7kcal/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Cl3La = (Chlorine anion bullet Cl3La)

By formula: Cl- + Cl3La = (Cl- bullet Cl3La)

Quantity Value Units Method Reference Comment
Deltar79.4 ± 4.1kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion bullet Cl3La) + Cl3La = (Chlorine anion bullet 2Cl3La)

By formula: (Cl- bullet Cl3La) + Cl3La = (Cl- bullet 2Cl3La)

Quantity Value Units Method Reference Comment
Deltar32.4 ± 3.5kcal/molMSButman, Kudin, et al., 1987gas phase; Knudsen cell; M

Chlorine anion + Cl3Lu = (Chlorine anion bullet Cl3Lu)

By formula: Cl- + Cl3Lu = (Cl- bullet Cl3Lu)

Quantity Value Units Method Reference Comment
Deltar71.0 ± 3.6kcal/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; EA estimated as 3.7±1.0 eV; value altered from reference due to conversion from electron convention to ion convention; B
Deltar85.8 ± 2.4kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Phosphorus oxychloride = Cl4OP-

By formula: Cl- + Cl3OP = Cl4OP-

Quantity Value Units Method Reference Comment
Deltar10.3 ± 1.2kcal/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Thiophosphoryl chloride = Cl4PS-

By formula: Cl- + Cl3PS = Cl4PS-

Quantity Value Units Method Reference Comment
Deltar9.80 ± 0.96kcal/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Phosphorus trichloride = Cl4P-

By formula: Cl- + Cl3P = Cl4P-

Quantity Value Units Method Reference Comment
Deltar21.5 ± 1.7kcal/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Deltar38.2 ± 1.9kcal/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Cl3Sm = Cl4Sm-

By formula: Cl- + Cl3Sm = Cl4Sm-

Quantity Value Units Method Reference Comment
Deltar69.1 ± 3.8kcal/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar86.5 ± 5.0kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Cl3Tb = Cl4Tb-

By formula: Cl- + Cl3Tb = Cl4Tb-

Quantity Value Units Method Reference Comment
Deltar84.4 ± 4.3kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar72.7 ± 1.6kcal/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Cl3Yb = (Chlorine anion bullet Cl3Yb)

By formula: Cl- + Cl3Yb = (Cl- bullet Cl3Yb)

Quantity Value Units Method Reference Comment
Deltar74.3 ± 7.2kcal/molTDAsKuznetsov, Kudin, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Deltar83.2 ± 4.5kcal/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Germanium tetrachloride = Cl5Ge-

By formula: Cl- + Cl4Ge = Cl5Ge-

Quantity Value Units Method Reference Comment
Deltar33.7 ± 1.4kcal/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Silicon tetrachloride = (Chlorine anion bullet Silicon tetrachloride)

By formula: Cl- + Cl4Si = (Cl- bullet Cl4Si)

Quantity Value Units Method Reference Comment
Deltar25.1 ± 1.9kcal/molCIDTHao, Kaspar, et al., 2005gas phase; B
Deltar24.2 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar17.6 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B

Chlorine anion + Tin(IV) chloride = Cl5Sn-

By formula: Cl- + Cl4Sn = Cl5Sn-

Quantity Value Units Method Reference Comment
Deltar56.2 ± 1.9kcal/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Cl4Th = (Chlorine anion bullet Cl4Th)

By formula: Cl- + Cl4Th = (Cl- bullet Cl4Th)

Quantity Value Units Method Reference Comment
Deltar24.2kcal/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar17.6kcal/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M

Chlorine anion + Hydrochloric acid-d = (Chlorine anion bullet Hydrochloric acid-d)

By formula: Cl- + DCl = (Cl- bullet DCl)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
16.8300.ICRLarson and McMahon, 1987gas phase; switching reaction(Cl-)HCl; Caldwell and Kebarle, 1985; M

Chlorine anion + Deuterium oxide = (Chlorine anion bullet Deuterium oxide)

By formula: Cl- + D2O = (Cl- bullet D2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar14.70 ± 0.20kcal/molIMRELarson and McMahon, 1988gas phase; Anchored to Keesee and Castleman, 19802: HOH..Cl- + DOD <=> DOD..Cl- + HOH, Keq=0.77; B

Chlorine anion + Thionyl fluoride = (Chlorine anion bullet Thionyl fluoride)

By formula: Cl- + F2OS = (Cl- bullet F2OS)

Quantity Value Units Method Reference Comment
Deltar17.1 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar10.2 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Phosphoryl fluoride = (Chlorine anion bullet Phosphoryl fluoride)

By formula: Cl- + F3OP = (Cl- bullet F3OP)

Quantity Value Units Method Reference Comment
Deltar13.9 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar7.6 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Phosphorus trifluoride = (Chlorine anion bullet Phosphorus trifluoride)

By formula: Cl- + F3P = (Cl- bullet F3P)

Quantity Value Units Method Reference Comment
Deltar15.5 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B
Deltar15.5kcal/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar21.0cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B
Deltar9.2kcal/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Silicon tetrafluoride = (Chlorine anion bullet Silicon tetrafluoride)

By formula: Cl- + F4Si = (Cl- bullet F4Si)

Quantity Value Units Method Reference Comment
Deltar23.4 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16.8 ± 2.0kcal/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + F6S- = (Chlorine anion bullet F6S-)

By formula: Cl- + F6S- = (Cl- bullet F6S-)

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
1.8300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

Chlorine anion + Sulfur hexafluoride = (Chlorine anion bullet Sulfur hexafluoride)

By formula: Cl- + F6S = (Cl- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<1.80kcal/molIMRBChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Hydrogen chloride = (Chlorine anion bullet Hydrogen chloride)

By formula: Cl- + HCl = (Cl- bullet HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar29.6 ± 1.0kcal/molN/AMetz, Kitsopoulos, et al., 1988gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Deltar23.8 ± 2.0kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Deltar23.1 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar23.70 ± 0.20kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Deltar20.4kcal/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl-)SO2; M
Deltar23.5cal/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Deltar23.5cal/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Deltar22.8cal/mol*KN/AUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M
Quantity Value Units Method Reference Comment
Deltar16.3 ± 2.0kcal/molIMRELarson and McMahon, 1987gas phase; K = 0.60 for HCl..Cl- + DCL <=> DCl..Cl- + HCl, anchored to Larson and McMahon, 1984, 32; B
Deltar17.1 ± 2.6kcal/molTDEqCaldwell and Kebarle, 1985gas phase; B
Deltar16.0 ± 2.0kcal/molIMRELarson and McMahon, 1984gas phase; B,M
Deltar16.70 ± 0.30kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B
Deltar13.6kcal/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M

(Chlorine anion bullet Hydrogen chloride) + Hydrogen chloride = (Chlorine anion bullet 2Hydrogen chloride)

By formula: (Cl- bullet HCl) + HCl = (Cl- bullet 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar15.20 ± 0.20kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Deltar14.0kcal/molPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Quantity Value Units Method Reference Comment
Deltar20.4cal/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Deltar24.4cal/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.90 ± 0.20kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion bullet 2Hydrogen chloride) + Hydrogen chloride = (Chlorine anion bullet 3Hydrogen chloride)

By formula: (Cl- bullet 2HCl) + HCl = (Cl- bullet 3HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar11.70 ± 0.30kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar23.4cal/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.70 ± 0.30kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion bullet 3Hydrogen chloride) + Hydrogen chloride = (Chlorine anion bullet 4Hydrogen chloride)

By formula: (Cl- bullet 3HCl) + HCl = (Cl- bullet 4HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.30 ± 0.70kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar26.7cal/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar2.3 ± 1.0kcal/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion bullet Hydrogen chloride) + Water = (Chlorine anion bullet Water bullet Hydrogen chloride)

By formula: (Cl- bullet HCl) + H2O = (Cl- bullet H2O bullet HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.5kcal/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar18.7cal/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M

(Chlorine anion bullet 2Hydrogen chloride) + Water = (Chlorine anion bullet Water bullet 2Hydrogen chloride)

By formula: (Cl- bullet 2HCl) + H2O = (Cl- bullet H2O bullet 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar7.6kcal/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar15.2cal/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M

(Chlorine anion bullet Hydrogen chloride bullet Water) + Hydrogen chloride = (Chlorine anion bullet 2Hydrogen chloride bullet Water)

By formula: (Cl- bullet HCl