Molybdenum ion (1+)
- Formula: Mo+
- Molecular weight: 95.96
- IUPAC Standard InChI: InChI=1S/Mo/q+1
- IUPAC Standard InChIKey: XJCQKXPYXRYZQM-UHFFFAOYSA-N
- CAS Registry Number: 16727-12-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Molybdenum cation
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Robert C. Dunbar
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
+
= (
•
)
By formula: Mo+ + CS = (Mo+ • CS)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 38.7 ± 3.2 | kcal/mol | CIDT | Schroeder, Kretzschmar, et al., 2003 | |
| ΔrH° | 38.7 ± 4.3 | kcal/mol | CIDT | Rodgers and Armentrout, 2000 |
+
= (
•
)
By formula: Mo+ + CS2 = (Mo+ • CS2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 16.1 ± 3.0 | kcal/mol | CIDT | Schroeder, Kretzschmar, et al., 2003 |
+
= (
•
)
By formula: Mo+ + C4H5N = (Mo+ • C4H5N)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | >69. | kcal/mol | RAK | Gapeev and Yang, 2000 |
+
= (
•
)
By formula: Mo+ + S2 = (Mo+ • S2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 78.7 ± 2.5 | kcal/mol | CIDT | Schroeder, Kretzschmar, et al., 2003 |
( •
) +
= (
• 2
)
By formula: (Mo+ • S2) + S2 = (Mo+ • 2S2)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 71.6 ± 3.0 | kcal/mol | CIDT | Schroeder, Kretzschmar, et al., 2003 |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B.,
Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase,
Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4
. [all data]
Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B.,
Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation,
Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X
. [all data]
Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N.,
Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results,
J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d
. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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