Arsine, silyl-
- Formula: AsH5Si
- Molecular weight: 108.0468
- IUPAC Standard InChI: InChI=1S/AsH5Si/c1-2/h1H2,2H3
- IUPAC Standard InChIKey: QNXQPPKJWUDNQJ-UHFFFAOYSA-N
- CAS Registry Number: 15455-99-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Silane, arsino-
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 10.1 ± 0.1 | EI | Saalfeld and McDowell, 1967 |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| AsSiH+ | 13.4 ± 0.1 | 2H2 | EI | Saalfeld and McDowell, 1967 | |
| AsH2+ | 12.4 ± 0.2 | ? | EI | Saalfeld and McDowell, 1967 | |
| AsSiH2+ | 13.7 ± 0.2 | H2+H | EI | Saalfeld and McDowell, 1967 | |
| AsH3+ | 13.1 ± 0.6 | ? | EI | Saalfeld and McDowell, 1967 | |
| AsSiH3+ | 9.7 ± 0.1 | H2 | EI | Saalfeld and McDowell, 1967 | |
| AsSiH4+ | 11.0 ± 0.3 | H | EI | Saalfeld and McDowell, 1967 | |
| AsSi+ | 16.8 ± 0.3 | 2H2+H | EI | Saalfeld and McDowell, 1967 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Saalfeld and McDowell, 1967
Saalfeld, F.E.; McDowell, M.V.,
The mass spectra of volatile hydrides. V. Silylarsine,
Inorg. Chem., 1967, 6, 96. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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