Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Chromium, pentacarbonyl(hexamethylphosphorous triamide-P)-, (OC-6-22)-


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
6.6 ± 0.05EISaalfeld, DeCorpo, et al., 1972 
7.6PEYarbrough and Hall, 1978Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H18N3PCr+12.5 ± 0.055COEISaalfeld, DeCorpo, et al., 1972 
C7H18N3OPCr+9.8 ± 0.054COEISaalfeld, DeCorpo, et al., 1972 
C9H18N3O3PCr+8.6 ± 0.052COEISaalfeld, DeCorpo, et al., 1972 
C10H18N3O4PCr+7.6 ± 0.05COEISaalfeld, DeCorpo, et al., 1972 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Saalfeld, DeCorpo, et al., 1972
Saalfeld, F.E.; DeCorpo, J.J.; McDowell, M.V., The mass spectra of some metal carbonyl complexes of tris(dimethylamino)phosphine, J. Organomet. Chem., 1972, 44, 333. [all data]

Yarbrough and Hall, 1978
Yarbrough, L.W., II; Hall, M.B., Photoelectron spectra of substituted chromium, molybdenum, and tungsten pentacarbonyls. Relative «pi»-acceptor and «sigma»-donor properties of various phosphorus ligands, Inorg. Chem., 1978, 17, 2269. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References