Manganese, pentacarbonyliodo-
- Formula: C5IMnO5
- Molecular weight: 321.8930
- IUPAC Standard InChI: InChI=1S/5CO.HI.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
- IUPAC Standard InChIKey: IGYXZZLAUYRNTO-UHFFFAOYSA-M
- CAS Registry Number: 14879-42-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Manganese pentacarbonyl iodide; Manganese, pentacarbonyliodo-, (OC-6-22)-; Iodine manganese pentacarbonyl; Iodomanganese pentacarbonyl; Pentacarbonyliodomanganese; Mn(CO)5I
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(cr) +
(cr) = 2
(cr)
By formula: C10Mn2O10 (cr) + I2 (cr) = 2C5IMnO5 (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -185.0 ± 8.7 | kJ/mol | PC | Harel and Adamson, 1986 | The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -187.9 ± 8.4 kJ/mol Harel and Adamson, 1986, and from the solution enthalpies of Mn2(CO)10(cr), 36.0 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Mn(CO)5(I)(cr), 26.8 ± 0.5 kJ/mol Harel and Adamson, 1986. The latter value refers to the solution in benzene and is therefore taken as an approximation |
(l) +
(cr) =
(g) +
(cr)
By formula: C5HMnO5 (l) + I2 (cr) = HI (g) + C5IMnO5 (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -108. ± 8. | kJ/mol | RSC | Connor, Zafarani-Moattar, et al., 1982 | The reaction enthalpy relies on -25. ± 5. kJ/mol for the enthalpy of solution of HI(g) in benzene Connor, Zafarani-Moattar, et al., 1982. |
C10MnO10Re (solution) + (solution) =
(solution) +
(solution)
By formula: C10MnO10Re (solution) + I2 (solution) = C5IO5Re (solution) + C5IMnO5 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -233. ± 13. | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane |
(solution) +
(solution) = 2
(solution)
By formula: C10Mn2O10 (solution) + I2 (solution) = 2C5IMnO5 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -187.9 ± 8.4 | kJ/mol | PC | Harel and Adamson, 1986 | solvent: Cyclohexane |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harel and Adamson, 1986
Harel, Y.; Adamson, A.W.,
J. Phys. Chem., 1986, 90, 6693. [all data]
Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A.,
Organomet., 1982, 1, 1166. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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