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3-Methylheptacosane


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spec Data Center, S.E. Stein, director

Kovats' RI, non-polar column, isothermal

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Column typeActive phaseTemperature (C)IReferenceComment
CapillaryDB-1250.2772.Szafranek, Malinski, et al., 2001Ar; Column length: 30. m; Column diameter: 0.28 mm
CapillaryOV-1255.2775.Hebanowska, Malinski, et al., 1989Ar; Column length: 30. m; Phase thickness: 0.1 «mu»m
CapillaryDexsil 300255.2772.Hebanowska, Malinski, et al., 1989Ar; Column length: 30. m; Phase thickness: 0.1 «mu»m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column typeActive phaseIReferenceComment
CapillaryDB-5MS2773.Steiner, Steidle, et al., 200530. m/0.32 mm/0.25 «mu»m, He, 2. K/min; Tstart: 150. C; Tend: 300. C
CapillaryDB-5MS2771.Steinmetz, Schmolz, et al., 200330. m/0.32 mm/0.25 «mu»m, He, 3. K/min; Tstart: 150. C; Tend: 280. C
CapillaryDB-52773.Ruther, Sieben, et al., 199830. m/0.32 mm/0.25 «mu»m, He, 3. K/min; Tstart: 150. C; Tend: 280. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column typeActive phaseIReferenceComment
CapillaryHP-5MS2771.6Andriamaharavo, 201430. m/0.25 mm/0.25 «mu»m, He; Program: 60C (1 min) => 5 C/min => 210C => 10 C/min => 280C (15 min)
CapillaryDB-52775.Zaikin and Borisov, 2002He; Column length: 30. m; Column diameter: 0.25 mm; Program: 30C => 5K/min=120C => 10C/min => 270C
CapillaryDB-12775.Sutton and Carlson, 1993He; Column length: 30. m; Column diameter: 0.25 mm; Program: 60C => 20C/min => 230C => 5C/min => 330C

Normal alkane RI, non-polar column, temperature ramp

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Column typeActive phaseIReferenceComment
CapillaryOV-12776.1Krkosova, Kubinec, et al., 2007100. m/0.32 mm/0.25 «mu»m, Helium, 5. K/min, 310. C @ 5. min; Tstart: 30. C
CapillaryUltra-12770.Nelson and Charlet, 2003He, 4. K/min; Column length: 12.5 m; Column diameter: 0.2 mm; Tstart: 150. C; Tend: 320. C
CapillaryDB-52775.Juárez, Blomquist, et al., 2001He, 3. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 200. C; Tend: 280. C
CapillaryDB-12774.Katritzky, Chen, et al., 200030. m/0.32 mm/0.25 «mu»m; Tstart: 60. C; Tend: 320. C
CapillaryOV-12775.Szafranek, Malinski, et al., 1994Ar, 2. K/min; Column length: 40. m; Tstart: 200. C; Tend: 310. C
CapillaryOV-12775.Hebanowska, Malinski, et al., 19902. K/min; Column length: 40. m; Column diameter: 0.25 mm; Tstart: 140. C; Tend: 300. C
CapillaryBP-12772.Lockey and Oraha, 199012. m/0.22 mm/0.25 «mu»m, Helium, 2. K/min; Tstart: 100. C; Tend: 300. C
CapillaryBP-12773.Lockey and Oraha, 199012. m/0.22 mm/0.25 «mu»m, Helium, 2. K/min; Tstart: 100. C; Tend: 300. C
CapillaryBP-12774.Lockey and Dularay, 198625. m/0.25 mm/0.25 «mu»m, Helium, 1.5 K/min; Tstart: 160. C; Tend: 300. C
CapillaryBP-12779.Lockey and Dularay, 198625. m/0.25 mm/0.25 «mu»m, Helium, 1.5 K/min; Tstart: 160. C; Tend: 300. C
CapillaryDexsil 3002773.Lockey, 19785. K/min; Column length: 15. m; Tstart: 50. C; Tend: 370. C
CapillaryDexsil 3002775.Lockey, 19785. K/min; Column length: 15. m; Tstart: 50. C; Tend: 370. C
CapillaryDexsil 3002772.Lockey, 1978, 22. K/min; Column length: 15. m; Tstart: 240. C; Tend: 330. C
CapillaryDexsil 3002772.Lockey, 1978, 22. K/min; Column length: 15. m; Tstart: 240. C; Tend: 330. C
PackedDexsil 3002773.Lockey, 1976Nitrogen, Chromosorb W (80-100 mesh), 3.3 K/min; Column length: 2. m; Tstart: 80. C; Tend: 340. C

Normal alkane RI, non-polar column, custom temperature program

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Column typeActive phaseIReferenceComment
CapillaryPolydimethyl siloxane2774.Junkes, Castanho, et al., 2003Program: not specified
CapillaryMethyl Silicone2774.Sullivan, 2002Program: not specified
CapillaryDB-12775.Carlson, Geden, et al., 199930. m/0.32 mm/0.25 «mu»m, He; Program: 60C (2min) => 10C/min => 220C => 3C/min => 310C (12 - 42 min)
CapillaryCP Sil 5 CB2772.Kenig, Sinninghe Damsté, et al., 199525. m/0.32 mm/0.2 «mu»m, He; Program: 50C => 20C/min => 130C => 4C/min => 300C (20min)
CapillaryDexsil 3002784.Lockey, 1981Column length: 15. m; Program: 50 0C 5 0C/min -> 200 0C 2 0C/min -> 340 0C

References

Go To: Top, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Szafranek, Malinski, et al., 2001
Szafranek, B.; Malinski, E.; Nawrot, J.; Sosnowska, D.; Ruszkowska, M.; Pihlaja, K.; Trumpakaj, Z.; Szafranek, J., In Vitro effects of cuticular lipids of the aphids Sitobion avenae, Hyalopterus pruni and Brevicoryne brassicae on growth and sporulation of the Paecilomyces fumosoroseus and Beauveria bassiana, Arkivoc, 2001, 2001, 3, 81-94. [doi:10.3998/ark.5550190.0002.311] [all data]

Hebanowska, Malinski, et al., 1989
Hebanowska, E.; Malinski, E.; Dubis, E.; Pihlaja, K.; Oksman, P.; Winamaki, K.; Nawrot, J.; Szafranek, J., The composition of cuticular hydrocarbons of the Tribolium destructor, Comp. Biochem. Physiol. B: Comp. Biochem., 1989, 93, 2, 437-442. [all data]

Steiner, Steidle, et al., 2005
Steiner, S.; Steidle, J.L.M.; Ruther, J., Female sex pheromone in immature insect males - a case of pre-emergence chemical mimicry?, Behavioral Ecology and Sociobiology, 2005, 58, 2, 111-120. [doi:10.1007/s00265-005-0930-x] [all data]

Steinmetz, Schmolz, et al., 2003
Steinmetz, I.; Schmolz, E.; Ruther, J., Cuticular lipids as trail pheromone in a social wasp, Proc. R. Soc. London B:, 2003, 270, 1513, 385-391. [doi:10.1098/rspb.2002.2256] [all data]

Ruther, Sieben, et al., 1998
Ruther, J.; Sieben, S.; Schricker, B., Role of cuticular lipids in nestmate recognition of the European hornet Vespa crabro L. (Hymenoptera, Vespidae), Insectes Soc., 1998, 45, 2, 169-179. [doi:10.1007/s000400050077] [all data]

Andriamaharavo, 2014
Andriamaharavo, N.R., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2014. [all data]

Zaikin and Borisov, 2002
Zaikin, V.G.; Borisov, R.S., Chromatographic-mass spectrometric analysis of Fishcer-Tropsch synthesis products, J. Anal. Chem. USSR (Engl. Transl.), 2002, 57, 6, 544-551. [all data]

Sutton and Carlson, 1993
Sutton, B.D.; Carlson, D.A., Interspecific variation in tephritid fruit fly larvae surface hydrocarbons, Arch. Insect Biochem. Physiol., 1993, 23, 2, 53-65. [doi:10.1002/arch.940230202] [all data]

Krkosova, Kubinec, et al., 2007
Krkosova, Z.; Kubinec, R.; Addova, G.; Jurdakova, H.; Blasko, J.; Ostrovsky, I.; Sojak, L., Gas chromatographic - mass spectrometric characterization of monomethylalkanes from fuel diesel, Petroleum Coal, 2007, 49, 3, 51-62. [all data]

Nelson and Charlet, 2003
Nelson, D.R.; Charlet, L.D., Cuticular hydrocarbons of the sunflower beetle,Zygogramma exclamationis, Comp. Biochem. Physiol. B: Comp. Biochem., 2003, 135, 2, 273-284. [doi:10.1016/S1096-4959(03)00080-0] [all data]

Juárez, Blomquist, et al., 2001
Juárez, P.; Blomquist, G.J.; Schofield, C.J., Hydrocarbons of Rhodnius prolixus, a Chagas disease vector, Comp. Biochem. Physiol. B: Comp. Biochem., 2001, 129, 4, 733-746. [doi:10.1016/S1096-4959(01)00380-3] [all data]

Katritzky, Chen, et al., 2000
Katritzky, A.R.; Chen, K.; Maran, U.; Carlson, D.A., QSPR Correlation and predictions of GC retention indexes for methyl-branched hydrocarbons produced by insects, Anal. Chem., 2000, 72, 1, 101-109. [doi:10.1021/ac990800w] [all data]

Szafranek, Malinski, et al., 1994
Szafranek, J.; Malinski, E.; Dubis, E.; Hebanowska, E.; Nawrot, J.; Oksman, P.; Pihlaja, K., Identification of branched alkanes in lipids of Leptinotarsa decemlineata say and Tribolium destructor by GC-MS: a comparison of main-beam and link-scanned spectra, J. Chem. Ecol., 1994, 20, 9, 2197-2212. [doi:10.1007/BF02033197] [all data]

Hebanowska, Malinski, et al., 1990
Hebanowska, E.; Malinski, E.; Dubis, E.; Oksman, P.; Pihlaja, K.; Nawrot, J.; Szafranek, J., The cuticular hydrocarbons of the larvae of Anagasta kuehniella Z., Comp. Biochem. Physiol. B: Comp. Biochem., 1990, 95, 4, 699-703. [all data]

Lockey and Oraha, 1990
Lockey, K.H.; Oraha, V.S., Cuticular lipids of adult Locusta Migratoria Migratoriodes (R and F), Schstocerca Gregaria (Forskal) (Acrididae) and other orthopteran species - II. Hydrocarbons, Comp. Biochem. Physiol., 1990, 95B, 4, 721-744. [all data]

Lockey and Dularay, 1986
Lockey, K.H.; Dularay, B., Cuticular methylalkanes of adult cockroaches, Blatta orientalis and Periplaneta Americana, Comp. Biochem. Physiol., 1986, 85B, 3, 567-572. [all data]

Lockey, 1978
Lockey, K.H., The adult cuticular hydrocarbons of Tenebrio Molitor L. and Tenebrio Obscurus F. (Coleoptera: Tenebrionidae), Insect Biochem., 1978, 8, 4, 237-250. [doi:10.1016/0020-1790(78)90032-X] [all data]

Lockey, 1978, 2
Lockey, K.H., Hydrocarbons of adult Tribolum castaneum Hbst. and Tribolium confusum duv. (Coleoptera: Tenebrionidae), Comparative Biochem. Physiol., 1978, 61B, 401-407. [all data]

Lockey, 1976
Lockey, K.H., Cuticular hydrocarbons of Locusta, Schistocerca, and Periplaneta, and their role in waterproofing, Insect Biochem., 1976, 6, 5, 457-472. [doi:10.1016/0020-1790(76)90068-8] [all data]

Junkes, Castanho, et al., 2003
Junkes, B.S.; Castanho, R.D.M.; Amboni, C.; Yunes, R.A.; Heinzen, V.E.F., Semiempirical Topological Index: A Novel Molecular Descriptor for Quantitative Structure-Retention Relationship Studies, Internet Electronic Journal of Molecular Design, 2003, 2, 1, 33-49. [all data]

Sullivan, 2002
Sullivan, B.T., Evidence for a sex pheromone in bark beetle parasitoid Roptrpcerus xylophagorum, J. Chem. Ecology, 2002, 28, 5, 1045-1063. [doi:10.1023/A:1015270003717] [all data]

Carlson, Geden, et al., 1999
Carlson, D.A.; Geden, C.J.; Bernier, U.R., Identification of pupal exiviae of Nasania vitripennis and Muscidifurax raptorellus parasitoids using cuticular hydrocarbons, Biol. Control, 1999, 15, 2, 97-106. [doi:10.1006/bcon.1999.0708] [all data]

Kenig, Sinninghe Damsté, et al., 1995
Kenig, F.; Sinninghe Damsté, J.S.; Kock-van Dalen, A.C.; Rijpstra, W.I.C.; Huc, A.Y.; de Leeuw, J.W., Occurrence and origin of mono-, di-, and trimethylalkanes in modern and holocene cyanobacterial mats from Abu Dhabi, United Arab Emirates, Geochim. Cosmochim. Acta, 1995, 59, 14, 2999-3015. [doi:10.1016/0016-7037(95)00190-5] [all data]

Lockey, 1981
Lockey, K.H., Cuticular hydrocarbons of adult Cylindrinotus laevioctostriatus (Goeze) and Phylan gibbus (Fabricius) (Coleoptera: Tenebrionidae), Insect. Biochem., 1981, 11, 5, 549-561. [doi:10.1016/0020-1790(81)90023-8] [all data]


Notes

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