tetrakis(trifluorophosphine)nickel
- Formula: F12NiP4
- Molecular weight: 410.5693
- IUPAC Standard InChI: InChI=1S/4F3P.Ni/c4*1-4(2)3;
- IUPAC Standard InChIKey: TXBNRHVYQQTHJK-UHFFFAOYSA-N
- CAS Registry Number: 13859-65-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Nickel, tetrakis(phosphorus trifluoride)-
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.82 ± 0.06 | PE | Bassett, Higginson, et al., 1974 | LLK |
| 8.77 | PE | Muller, Fenderl, et al., 1971 | LLK |
| 8.81 | EI | Muller, Fenderl, et al., 1971 | LLK |
| 8.7 | EI | Kiser, Krassoi, et al., 1967 | RDSH |
| 9.69 | PE | Hillier, Saunders, et al., 1970 | Vertical value; RDSH |
| 9.6 | PE | Green, King, et al., 1970 | Vertical value; RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| NiPF3+ | 14.0 | ? | EI | Kiser, Krassoi, et al., 1967 | RDSH |
| NiP2F6+ | 11.4 | ? | EI | Kiser, Krassoi, et al., 1967 | RDSH |
| NiP3F9+ | 9.7 | ? | EI | Kiser, Krassoi, et al., 1967 | RDSH |
| Ni+ | 17.3 | ? | EI | Kiser, Krassoi, et al., 1967 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bassett, Higginson, et al., 1974
Bassett, P.J.; Higginson, B.R.; Lloyd, D.R.; Lynaugh, N.; Roberts, P.J.,
Helium-I photoelectron spectra of tetrakis(trifluoro- phosphine)-nickel(O), -palladium(O), and -platinum(O),
J. Chem. Soc. Dalton Trans., 1974, 2316. [all data]
Muller, Fenderl, et al., 1971
Muller, J.; Fenderl, K.; Mertschenk, B.,
Die Donor-Akzeptor-Eigenschaften des Liganden Trifluorphosphin in Ubergangsmetallkomplexen,
Chem. Ber., 1971, 104, 700. [all data]
Kiser, Krassoi, et al., 1967
Kiser, R.W.; Krassoi, M.A.; Clark, R.J.,
Mass spectrometric study of tetrakis(trifluorophosphine)nickel(0),
J. Am. Chem. Soc., 1967, 89, 3653. [all data]
Hillier, Saunders, et al., 1970
Hillier, I.H.; Saunders, V.R.; Ware, M.J.; Bassett, P.J.; Lloyd, D.R.; Lynaugh, N.,
On the bonding and the photoelectron spectra of Ni(PF3)4 and Pt(PF3)4,
Chem. Commun., 1970, 1316. [all data]
Green, King, et al., 1970
Green, J.C.; King, D.I.; Eland, J.H.D.,
Photoelectron spectra of trifluorophosphine and its complexes Ni(PF3), and Pt(PF3)4,
Chem. Commun., 1970, 1121. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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