Bis(cyclopentadienyl)zirconium dichloride

• Formula: C₁₀H₁₀Cl₂Zr
• Molecular weight: 292.316
• IUPAC Standard InChI: InChI=1S/2C5H5.2ClH.Zr/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2 Copy

  
• IUPAC Standard InChIKey: QRUYYSPCOGSZGQ-UHFFFAOYSA-L Copy
• CAS Registry Number: 1291-32-3
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Zirconocene dichloride; Dicyclopentadienylzirconium dichloride; Zirconium, dichlorobis(η(5)-2,4-cyclopentadien-1-yl)-; Bis-π-cyclopentadienyldichlorozirconium; Dichlorobis(cyclopentadienyl) zirconium; Dichlorodi-π-cyclopentadienylzirconium; Dichlorodi-π-dicyclopentadienylzirconium; Dichlorodicyclopentadienylzirconium; Dichlorozirconocene; Dicyclopentadienyldichlorozirconium; Zirconcene dichloride; Zirconium dicyclopentadiene dichloride; Zirconium, dichlorobis(2,4-cyclopentadien-1-yl)-; Zirconium, dichlorodi-π-cyclopentadienyl-; Bis(cyclopentadienyl)dichlorozirconium; Dichlorobis(η5-2,4-cyclopentadien-1-yl)zirconium; NSC 93930; bis(3-cyclopentadienyl)dichlorozirconium
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• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Mass spectrum (electron ionization)
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dillard and Kiser, 1969
Dillard, J.G.; Kiser, R.W., The formation of gaseous ions from dicyclopentadienyltitanium dichloride and dicyclopentadienylzirconium dichloride upon electron impact, J. Organometal. Chem., 1969, 16, 265. [all data]

Cauletti, Clark, et al., 1980
Cauletti, C.; Clark, J.P.; Green, J.C.; Jackson, S.E.; Fragala, I.L.; Ciliberto, E.; Coleman, A.W., Photoelectron spectra of bis-cyclopentadienyl metal dihalides, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 61. [all data]

Condorelli, Fragala, et al., 1975
Condorelli, G.; Fragala, I.; Centineo, A.; Tondello, E., The electronic structure and photoelectron spectra of dichlorodi-π-cyclopentadienyl- titanium(IV), -zirconium(IV) and- hafnium(IV), J. Organomet. Chem., 1975, 87, 311. [all data]

Notes

Go To: Top, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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