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Bis(«pi»-cyclopentadienyl)vanadium

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - S.G. Lias and J.F. Liebman
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi
RDSH - H.M. Rosenstock, K. Draxl, B.W. Steiner, and J.T. Herron

Ionization energy determinations

IE (eV)MethodReferenceComment
6.75PERyan, Eyler, et al., 1992Unpublished results of D.L. Lichtenberger and M.E.Rempe; LL
~6.7EQRyan, Eyler, et al., 1992T = 350K; LL
7.3 ± 0.1EIMuller and D'Or, 1967RDSH
6.81PECauletti, Green, et al., 1980Vertical value; LLK
6.78PEEvans, Green, et al., 1974Vertical value; LLK

Appearance energy determinations

IonAE (eV)Other ProductsMethodReferenceComment
C5H5V+12.7 ± 0.1?EIMuller and D'Or, 1967RDSH
V+14.5 ± 0.5?EIMuller and D'Or, 1967RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ryan, Eyler, et al., 1992
Ryan, M.F.; Eyler, J.R.; Richardson, D.E., Adiabatic ionization energies, bond disruption enthalpies, and solvation free energies for gas-phase metallocenes and metallocenium ions, J. Am. Chem. Soc., 1992, 114, 8611. [all data]

Muller and D'Or, 1967
Muller, J.; D'Or, L., Massenspektrometrische Untersuchungen an Dicyclopentadienylkomplexen von Ubergangsmetallen, J.Organometal. Chem., 1967, 10, 313. [all data]

Cauletti, Green, et al., 1980
Cauletti, C.; Green, J.C.; Kelly, M.R.; Powell, P.; Van Tilborg, J., Photoelectron spectra of metallocenes, J. Electron Spectrosc. Relat. Phenom., 1980, 19, 327. [all data]

Evans, Green, et al., 1974
Evans, S.; Green, M.L.H.; Jewitt, B.; King, G.H.; Orchard, A.F., Electronic structures of metal complexes containing the «pi»-cyclopentadienyl and related ligands Part 2. He I photoelectron spectra of the open-shell metallocenes, J. Chem. Soc. Faraday Trans. 2, 1974, 70, 356. [all data]


Notes

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