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Bis(«pi»-cyclopentadienyl)vanadium

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - J.A. Martinho Simões
DH - E.S. Domalski and E.D. Hearing

QuantityValueUnitsMethodReferenceComment
Deltafsolid144.7 ± 8.9kJ/molReviewMartinho SimõesMS
Deltafsolid123. ± 4.kJ/molCC-SBChipperfield, Sneyd, et al., 1979Value corrected based on a set of ancillary data by J.A. Martinho Simões; The enthalpy of combustion is not reported in Chipperfield, Sneyd, et al., 1979; MS
QuantityValueUnitsMethodReferenceComment
Deltacsolid-6284.4 ± 8.4kJ/molCC-SBTel' noi, Rabinovich, et al., 1971Please also see Pedley and Rylance, 1977 and Tel'noi and Rabinovich, 1977.; MS
QuantityValueUnitsMethodReferenceComment
solid,1 bar240.2J/mol*KN/ARabinovich, Nistratov, et al., 1978DH
solid,1 bar240.2J/mol*KN/ARabinovich, Nistratov, et al., 1975DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K)Temperature (K)ReferenceComment
203.3298.Calvarin, Berar, et al., 1980T = 100 to 300 K. Cp between 235 to 300 K given by equation.; DH
204.6298.15Rabinovich, Nistratov, et al., 1978T = 5 to 300 K.; DH
204.3298.15Rabinovich, Nistratov, et al., 1975T = 5 to 298.15 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Chipperfield, Sneyd, et al., 1979
Chipperfield, J.R.; Sneyd, J.C.R.; Webster, D.E., J. Organometal. Chem., 1979, 178, 177. [all data]

Tel' noi, Rabinovich, et al., 1971
Tel' noi, V.I.; Rabinovich, I.B.; Latyaeva, V.N.; Lineva, A.N., Dokl. Akad. Nauk SSSR, 1971, 197, 353. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Rabinovich, Nistratov, et al., 1978
Rabinovich, I.B.; Nistratov, V.P.; Sheiman, M.S.; Burchalova, G.V., Heat capacities of dicyclopentadienyl compounds of vanadium, chromium, manganese, cobalt, and nickel, J. Chem. Thermodynam., 1978, 10, 523-536. [all data]

Rabinovich, Nistratov, et al., 1975
Rabinovich, I.B.; Nistratov, V.P.; Sheiman, M.S.; Burchalova, G.V., Heat capacity and transitions in solid state. Dicyclopentadienyl compounds of transition elements,Quatrieme Conference International de Thermodynamique Chimique II, Thermophysiques (capacites thermiques) pp., 1975, 69-76, 136. [all data]

Calvarin, Berar, et al., 1980
Calvarin, G.; Berar, J.F.; Chhor, K.; Pommier, C., Etude de la transition de phase ordre-desordre du vanadocene V(C5H5)2, Mol. Cryst. Liq. Cryst., 1980, 59, 149-158. [all data]


Notes

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