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Titanocene dichloride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C10H10I2Ti (solution) + Titanocene dichloride (solution) = 2C10H10ClITi (solution)

By formula: C10H10I2Ti (solution) + C10H10Cl2Ti (solution) = 2C10H10ClITi (solution)

Quantity Value Units Method Reference Comment
Deltar-3.4kJ/molEqSBruce and Tyler, 1985solvent: Perdeuterated benzene; The reaction enthalpy relies on a single value for the equilibrium constant. It assumes a negligible reaction entropy

C30H28Fe2Ti (cr) + 2(Hydrogen chloride bullet 4.40Water) (solution) = 2Ferrocene (cr) + Titanocene dichloride (cr)

By formula: C30H28Fe2Ti (cr) + 2(HCl bullet 4.40H2O) (solution) = 2C10H10Fe (cr) + C10H10Cl2Ti (cr)

Quantity Value Units Method Reference Comment
Deltar-253.5 ± 4.5kJ/molRSCDias, Salema, et al., 1982Please also see Calhorda, Dias, et al., 1987.

C22H20O2Ti (cr) + 2(Hydrogen chloride bullet 5.55Water) (solution) = 2Phenol (cr) + Titanocene dichloride (cr)

By formula: C22H20O2Ti (cr) + 2(HCl bullet 5.55H2O) (solution) = 2C6H6O (cr) + C10H10Cl2Ti (cr)

Quantity Value Units Method Reference Comment
Deltar-5.8 ± 2.5kJ/molRSCDias, Salema, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.

C14H10Cl6O4Ti (cr) + 2(Hydrogen chloride bullet 4.40Water) (solution) = Titanocene dichloride (cr) + 2Trichloroacetic Acid (cr)

By formula: C14H10Cl6O4Ti (cr) + 2(HCl bullet 4.40H2O) (solution) = C10H10Cl2Ti (cr) + 2C2HCl3O2 (cr)

Quantity Value Units Method Reference Comment
Deltar13.4 ± 2.6kJ/molRSCDias, Salema, et al., 1984Please also see Calhorda, Carrondo, et al., 1986.

C10H10N6Ti (cr) + 2(Hydrogen chloride bullet 4.18Water) (solution) = Titanocene dichloride (cr) + 2Hydrogen azide (g)

By formula: C10H10N6Ti (cr) + 2(HCl bullet 4.18H2O) (solution) = C10H10Cl2Ti (cr) + 2HN3 (g)

Quantity Value Units Method Reference Comment
Deltar75.7 ± 5.8kJ/molRSCCalhorda, Gomes da Costa, et al., 1982Please also see Dias, Dias, et al., 1987.

C14H10F6O4Ti (cr) + 2(Hydrogen chloride bullet 4.40Water) (solution) = Titanocene dichloride (cr) + 2Trifluoroacetic acid (l)

By formula: C14H10F6O4Ti (cr) + 2(HCl bullet 4.40H2O) (solution) = C10H10Cl2Ti (cr) + 2C2HF3O2 (l)

Quantity Value Units Method Reference Comment
Deltar37.8 ± 2.3kJ/molRSCCalado, Dias, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.

Titanium, bis(η5-2,4-cyclopentadien-1-yl)dimethyl- (cr) + 2(Hydrogen chloride bullet 5.55Water) (solution) = Titanocene dichloride (cr) + 2Methane (g)

By formula: C12H16Ti (cr) + 2(HCl bullet 5.55H2O) (solution) = C10H10Cl2Ti (cr) + 2CH4 (g)

Quantity Value Units Method Reference Comment
Deltar-192.0 ± 5.9kJ/molRSCCalhorda, Dias, et al., 1987 

C11H13ClTi (cr) + (Hydrogen chloride bullet 4.40Water) (solution) = Titanocene dichloride (cr) + Methane (g)

By formula: C11H13ClTi (cr) + (HCl bullet 4.40H2O) (solution) = C10H10Cl2Ti (cr) + CH4 (g)

Quantity Value Units Method Reference Comment
Deltar-68.9 ± 3.1kJ/molRSCCalhorda, Dias, et al., 1987 

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bruce and Tyler, 1985
Bruce, M.R.M.; Tyler, D.R., Organometallics, 1985, 4, 528. [all data]

Dias, Salema, et al., 1982
Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., Organometallics, 1982, 1, 971. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]

Dias, Salema, et al., 1981
Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., J. Organometal. Chem., 1981, 222, 69. [all data]

Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C., Organometallics, 1986, 5, 660. [all data]

Dias, Salema, et al., 1984
Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., Rev. Port. Quím., 1984, 26, 227. [all data]

Calhorda, Gomes da Costa, et al., 1982
Calhorda, M.J.; Gomes da Costa, R.; Dias, A.R.; Martinho Simões, J.A., J. Chem. Soc., Dalton Trans., 1982, 2327.. [all data]

Dias, Dias, et al., 1987
Dias, A.R.; Dias, P.B.; Diogo, H.P.; Galvão, A.M.; Minas da Piedade, M.E.; Martinho Simões, J.A., Organometallics, 1987, 6, 1427. [all data]

Calado, Dias, et al., 1981
Calado, J.C.G.; Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., J. Chem. Soc., Dalton Trans., 1981, 1174.. [all data]


Notes

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