Deuterium, deuteronated
- Formula: D3+
- Molecular weight: 6.0417567535
- CAS Registry Number: 12595-96-9
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: D3+ + Ar = (D3+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.0 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 14.5 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • Ar) + Ar = (D3+ • 2Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.8 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.5 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 2Ar) + Ar = (D3+ • 3Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.4 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 3Ar) + Ar = (D3+ • 4Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.4 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.6 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 4Ar) + Ar = (D3+ • 5Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.3 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 5Ar) + Ar = (D3+ • 6Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.2 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.1 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 6Ar) + Ar = (D3+ • 7Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 25.2 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: D3+ + D2 = (D3+ • D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.1 ± 0.3 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.8 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • D2) + D2 = (D3+ • 2D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.5 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.9 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 2D2) + D2 = (D3+ • 3D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.4 ± 0.2 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.0 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 3D2) + D2 = (D3+ • 4D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.8 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.2 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 4D2) + D2 = (D3+ • 5D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.8 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.1 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 5D2) + D2 = (D3+ • 6D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.7 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 21.8 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 6D2) + D2 = (D3+ • 7D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.9 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 12.8 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 7D2) + D2 = (D3+ • 8D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.8 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 15.3 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 8D2) + D2 = (D3+ • 9D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.7 ± 0.1 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.4 | cal/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 9D2) + D2 = (D3+ • 10D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.6 | kcal/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20. | cal/mol*K | N/A | Hiraoka and Mori, 1989, 2 | gas phase; Entropy change calculated or estimated |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T.,
Isotope Effect and Nature of Bonding in the Cluster Ions H3+(Ar)n and D3+(Ar)n,
J. Chem. Phys., 1989, 91, 8, 4821, https://doi.org/10.1063/1.456720
. [all data]
Hiraoka and Mori, 1989, 2
Hiraoka, K.; Mori, T.,
Thermochemical Stabilities of D3+(D2)n with n = 1 - 10,
Chem. Phys. Lett., 1989, 157, 5, 467, https://doi.org/10.1016/0009-2614(89)87282-3
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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