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Carbon dioxide

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

(Nitrogen oxide anion bullet 6Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 7Carbon dioxide)

By formula: (NO2- bullet 6CO2) + CO2 = (NO2- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar4.4 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet 7Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 8Carbon dioxide)

By formula: (NO2- bullet 7CO2) + CO2 = (NO2- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar4.2 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-2.3 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 2Carbon dioxide)

By formula: (NO2- bullet CO2) + CO2 = (NO2- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar19.0cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.0 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1992gas phase; B

O3S- + Carbon dioxide = (O3S- bullet Carbon dioxide)

By formula: O3S- + CO2 = (O3S- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar6.50 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar20.7cal/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.30 ± 0.20kcal/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Sodium ion (1+) bullet Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) bullet 2Carbon dioxide)

By formula: (Na+ bullet CO2) + CO2 = (Na+ bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar11.0kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
4.8310.DTKeller and Beyer, 1971gas phase; low E/N; M

CN- + Carbon dioxide = (CN- bullet Carbon dioxide)

By formula: CN- + CO2 = (CN- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar17.30 ± 0.80kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar31.5cal/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.90 ± 0.20kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B

(Nitric oxide anion bullet 5Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 6Carbon dioxide)

By formula: (NO- bullet 5CO2) + CO2 = (NO- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar5.0kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar28.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M

(Fluorine anion bullet 6Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 7Carbon dioxide)

By formula: (F- bullet 6CO2) + CO2 = (F- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar3.9kcal/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar18.cal/mol*KN/AHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M

(Formyl cation bullet 3Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 4Carbon dioxide)

By formula: (CHO+ bullet 3CO2) + CO2 = (CHO+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar8.4kcal/molPHPMSHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M

(CO3- bullet 6Carbon dioxide) + Carbon dioxide = (CO3- bullet 7Carbon dioxide)

By formula: (CO3- bullet 6CO2) + CO2 = (CO3- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar4.45kcal/molPHPMSHiraoka and Yamabe, 1992gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka and Yamabe, 1992gas phase; Entropy change calculated or estimated; M

(CO2+ bullet 5Carbon dioxide) + Carbon dioxide = (CO2+ bullet 6Carbon dioxide)

By formula: (CO2+ bullet 5CO2) + CO2 = (CO2+ bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar4.0kcal/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar22.cal/mol*KN/AHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M

(Oxygen cation bullet 5Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 6Carbon dioxide)

By formula: (O2+ bullet 5CO2) + CO2 = (O2+ bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar4.0kcal/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M

Cesium ion (1+) + Carbon dioxide = (Cesium ion (1+) bullet Carbon dioxide)

By formula: Cs+ + CO2 = (Cs+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar6.2kcal/molDTMcKnight and Sawina, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.3cal/mol*KDTMcKnight and Sawina, 1972gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
2.4301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Potassium ion (1+) + Carbon dioxide = (Potassium ion (1+) bullet Carbon dioxide)

By formula: K+ + CO2 = (K+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar8.5kcal/molHPMSCastleman and Keesee, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar15.2cal/mol*KHPMSCastleman and Keesee, 1981gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.7310.DTKeller and Beyer, 1971, 2gas phase; low E/N; M

(CHO2+ bullet 2Carbon dioxide) + Carbon dioxide = (CHO2+ bullet 3Carbon dioxide)

By formula: (CHO2+ bullet 2CO2) + CO2 = (CHO2+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar5.9kcal/molPHPMSHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar24.cal/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M

Tetrafluoromethane + 2Water = Carbon dioxide + 4hydrogen fluoride

By formula: CF4 + 2H2O = CO2 + 4HF

Quantity Value Units Method Reference Comment
Deltar-41.5 ± 1.0kcal/molCmGood, Scott, et al., 1956gas phase; HF has 10 moles H2O, see Scott, Good, et al., 1955; ALS
Deltar-41.5 ± 1.0kcal/molCmScott, Good, et al., 1955gas phase; Heat of hydrolysis; ALS

O2S+ + Carbon dioxide = (O2S+ bullet Carbon dioxide)

By formula: O2S+ + CO2 = (O2S+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 0.2kcal/molDTIllies, 1988gas phase; «DELTA»rH(0 K)=10.2 kcal/mol; M
Quantity Value Units Method Reference Comment
Deltar16.5cal/mol*KDTIllies, 1988gas phase; «DELTA»rH(0 K)=10.2 kcal/mol; M

Methyl cation + Carbon dioxide = (Methyl cation bullet Carbon dioxide)

By formula: CH3+ + CO2 = (CH3+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar49.4kcal/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 48.3 kcal/mol; Foster, Williamson, et al., 1974; M

(Iodide bullet 10Carbon dioxide) + Carbon dioxide = (Iodide bullet 11Carbon dioxide)

By formula: (I- bullet 10CO2) + CO2 = (I- bullet 11CO2)

Quantity Value Units Method Reference Comment
Deltar1.0 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 11Carbon dioxide) + Carbon dioxide = (Iodide bullet 12Carbon dioxide)

By formula: (I- bullet 11CO2) + CO2 = (I- bullet 12CO2)

Quantity Value Units Method Reference Comment
Deltar1.6 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 12Carbon dioxide) + Carbon dioxide = (Iodide bullet 13Carbon dioxide)

By formula: (I- bullet 12CO2) + CO2 = (I- bullet 13CO2)

Quantity Value Units Method Reference Comment
Deltar1.1 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 10Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 11Carbon dioxide)

By formula: (Br- bullet 10CO2) + CO2 = (Br- bullet 11CO2)

Quantity Value Units Method Reference Comment
Deltar0.5 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 9Carbon dioxide) + Carbon dioxide = (Iodide bullet 10Carbon dioxide)

By formula: (I- bullet 9CO2) + CO2 = (I- bullet 10CO2)

Quantity Value Units Method Reference Comment
Deltar0.9 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 9Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 10Carbon dioxide)

By formula: (Br- bullet 9CO2) + CO2 = (Br- bullet 10CO2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 8Carbon dioxide) + Carbon dioxide = (Iodide bullet 9Carbon dioxide)

By formula: (I- bullet 8CO2) + CO2 = (I- bullet 9CO2)

Quantity Value Units Method Reference Comment
Deltar2.8 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 2Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 3Carbon dioxide)

By formula: (Br- bullet 2CO2) + CO2 = (Br- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar5.1 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 3Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 4Carbon dioxide)

By formula: (Br- bullet 3CO2) + CO2 = (Br- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar5.2 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 4Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 5Carbon dioxide)

By formula: (Br- bullet 4CO2) + CO2 = (Br- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar4.2 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 5Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 6Carbon dioxide)

By formula: (Br- bullet 5CO2) + CO2 = (Br- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar4.0 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 6Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 7Carbon dioxide)

By formula: (Br- bullet 6CO2) + CO2 = (Br- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar3.6 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 7Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 8Carbon dioxide)

By formula: (Br- bullet 7CO2) + CO2 = (Br- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar3.7 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 8Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 9Carbon dioxide)

By formula: (Br- bullet 8CO2) + CO2 = (Br- bullet 9CO2)

Quantity Value Units Method Reference Comment
Deltar1.8 ± 2.0kcal/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

Carbon dioxide + Carbon Tetrachloride = 2Phosgene

By formula: CO2 + CCl4 = 2CCl2O

Quantity Value Units Method Reference Comment
Deltar16.8 ± 0.5kcal/molEqkLord and Pritchard, 1969gas phase; Two values for Hf; ALS
Deltar16.8 ± 0.5kcal/molEqkLord and Pritchard, 1969gas phase; Two values for Hf; ALS

(Sodium ion (1+) bullet 2Water) + Carbon dioxide = (Sodium ion (1+) bullet Carbon dioxide bullet 2Water)

By formula: (Na+ bullet 2H2O) + CO2 = (Na+ bullet CO2 bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar10.3kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.9cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Nitric oxide anion bullet 2Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 3Carbon dioxide)

By formula: (NO- bullet 2CO2) + CO2 = (NO- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar7.2 ± 0.4kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.8cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion bullet 3Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 4Carbon dioxide)

By formula: (NO- bullet 3CO2) + CO2 = (NO- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar5.7 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.4cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion bullet 4Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 5Carbon dioxide)

By formula: (NO- bullet 4CO2) + CO2 = (NO- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar5.2 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.9cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Sodium ion (1+) bullet Water) + Carbon dioxide = (Sodium ion (1+) bullet Carbon dioxide bullet Water)

By formula: (Na+ bullet H2O) + CO2 = (Na+ bullet CO2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar12.6kcal/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.5cal/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Nitric oxide anion bullet Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 2Carbon dioxide)

By formula: (NO- bullet CO2) + CO2 = (NO- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.4kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(CO3- bullet 2Carbon dioxide) + Carbon dioxide = (CO3- bullet 3Carbon dioxide)

By formula: (CO3- bullet 2CO2) + CO2 = (CO3- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar5.5 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.9cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO3- bullet 3Carbon dioxide) + Carbon dioxide = (CO3- bullet 4Carbon dioxide)

By formula: (CO3- bullet 3CO2) + CO2 = (CO3- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar5.2 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.3cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO3- bullet 4Carbon dioxide) + Carbon dioxide = (CO3- bullet 5Carbon dioxide)

By formula: (CO3- bullet 4CO2) + CO2 = (CO3- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar4.8 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.0cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO3- bullet 5Carbon dioxide) + Carbon dioxide = (CO3- bullet 6Carbon dioxide)

By formula: (CO3- bullet 5CO2) + CO2 = (CO3- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar4.7 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.9cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO2+ bullet 3Carbon dioxide) + Carbon dioxide = (CO2+ bullet 4Carbon dioxide)

By formula: (CO2+ bullet 3CO2) + CO2 = (CO2+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar4.8 ± 0.3kcal/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(CO2+ bullet 4Carbon dioxide) + Carbon dioxide = (CO2+ bullet 5Carbon dioxide)

By formula: (CO2+ bullet 4CO2) + CO2 = (CO2+ bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar4.3 ± 0.3kcal/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.7cal/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(Oxygen cation bullet 2Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 3Carbon dioxide)

By formula: (O2+ bullet 2CO2) + CO2 = (O2+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar6.2 ± 0.3kcal/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.8cal/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(Oxygen cation bullet 3Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 4Carbon dioxide)

By formula: (O2+ bullet 3CO2) + CO2 = (O2+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar5.1 ± 0.3kcal/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.6cal/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(Oxygen cation bullet 4Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 5Carbon dioxide)

By formula: (O2+ bullet 4CO2) + CO2 = (O2+ bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar4.5 ± 0.5kcal/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.0cal/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(CO3- bullet Carbon dioxide) + Carbon dioxide = (CO3- bullet 2Carbon dioxide)

By formula: (CO3- bullet CO2) + CO2 = (CO3- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar5.7 ± 0.2kcal/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.9cal/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(Hydronium cation bullet 2Carbon dioxide) + Carbon dioxide = (Hydronium cation bullet 3Carbon dioxide)

By formula: (H3O+ bullet 2CO2) + CO2 = (H3O+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar10.5kcal/molPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.9cal/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Peterson, Mark, et al., 1984
Peterson, K.I.; Mark, T.D.; Keesee, R.G.; Castleman, A.W., Thermochemical Properties of Gas - Phase Mixed Clusters: H2O/CO2 with Na+, J. Phys. Chem., 1984, 88, 13, 2880, https://doi.org/10.1021/j150657a042 . [all data]

Keller and Beyer, 1971
Keller, G.E.; Beyer, R.A., CO2 and O2 Clustering to Sodium Ions, J. Geophys. Res., 1971, 74, 1, 289, https://doi.org/10.1029/JA076i001p00289 . [all data]

Larson, Szulejko, et al., 1988
Larson, J.W.; Szulejko, J.E.; McMahon, T.B., Gas Phase Lewis Acid-Base Interactions. An Experimental Determination of Cyanide Binding Energies From Ion Cyclotron Resonance and High-Pressure Mass Spectrometric Equilibrium Measurements., J. Am. Chem. Soc., 1988, 110, 23, 7604, https://doi.org/10.1021/ja00231a004 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Cluster Ions: Gas Phase Stabilities of NO+(O2)n and NO+(CO2)n with n = 1 - 5, J. Chem. Phys., 1991, 95, 9, 6800, https://doi.org/10.1063/1.461518 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Hiraoka, Shoda, et al., 1986
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Notes

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