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Phentermine


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spec Data Center, S.E. Stein, director

Kovats' RI, non-polar column, isothermal

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Column typeActive phaseTemperature (C)IReferenceComment
CapillaryBP-1130.1155.Japp, Gill, et al., 198725. m/0.22 mm/0.25 «mu»m, N2
CapillaryBP-1130.1174.Japp, Gill, et al., 198725. m/0.53 mm/1. «mu»m, N2
PackedOV-101150.1173.Huber, Kenndler, et al., 1979N2; Column length: 2. m
PackedApiezon L120.1168.Huber, Kenndler, et al., 1979 
PackedApiezon L120.1168.Donike and Stratmann, 1976Chromosorb W

Kovats' RI, non-polar column, custom temperature program

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Column typeActive phaseIReferenceComment
PackedOV-1011140.McLinden and Stenhouse, 1979N2, Chromosorb W; Column length: 2. m; Program: not specified
PackedSE-301130.Moffat, Stead, et al., 1974Column length: 2. m; Program: not specified

Kovats' RI, polar column, isothermal

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Column typeActive phaseTemperature (C)IReferenceComment
PackedPEG-20M120.1573.Huber, Kenndler, et al., 1979N2
PackedPEG-20M120.1573.Donike and Stratmann, 1976Chromosorb W

Kovats' RI, polar column, custom temperature program

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Column typeActive phaseIReferenceComment
PackedCarbowax 20M1566.Moffat, Stead, et al., 1974Column length: 1. m; Program: not specified

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column typeActive phaseIReferenceComment
CapillaryVF-5MS1173.4Tretyakov, 201430. m/0.25 mm/0.25 «mu»m, He; Tstart: 60. C; Tend: 270. C
CapillarySPB-11159.Christ, Noomano, et al., 198830. m/0.75 mm/1.0 «mu»m, He, 10. K/min, 280. C @ 12. min; Tstart: 160. C
CapillarySE-301138.Anderson and Stafford, 198315. m/0.25 mm/0.25 «mu»m, He, 5. K/min; Tstart: 100. C; Tend: 295. C
PackedSE-301130.Perrigo and Peel, 1981N2, Chromosorb W, 130. C @ 2. min, 8. K/min, 290. C @ 8. min; Column length: 1.8 m

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column typeActive phaseIReferenceComment
CapillaryBP-11152.Stowell and Wilson, 198712. m/0.22 mm/0.25 «mu»m, He; Program: 120C => 8C/min => 270C => 25C/min => 300C

Normal alkane RI, non-polar column, isothermal

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Column typeActive phaseTemperature (C)IReferenceComment
CapillaryApieson L / KOH150.1177.Caddy, Fish, et al., 1973 
CapillaryApieson L / KOH150.1183.Caddy, Fish, et al., 1973 
CapillaryApieson L / KOH150.1191.Caddy, Fish, et al., 1973 

Normal alkane RI, non-polar column, temperature ramp

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Column typeActive phaseIReferenceComment
PackedSE-301147.MHA, 9999Nitrogen, Chromosorb G AW DMCS (80-100 mesh); Column length: 2. m; Tstart: 100. C; Tend: 300. C
CapillaryDB-11148.Yashiki, Kojima, et al., 199530. m/0.25 mm/0.25 «mu»m, He, 40. C @ 2. min, 25. K/min, 250. C @ 5. min
CapillaryDB-51138.Phillips, Logan, et al., 199015. m/0.25 mm/0.2 «mu»m, He, 10. K/min; Tstart: 100. C; Tend: 150. C
CapillaryBP-11138.Stowell and Wilson, 198512. m/0.22 mm/0.25 «mu»m, He, 5. K/min; Tstart: 100. C; Tend: 295. C

Normal alkane RI, non-polar column, custom temperature program

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Column typeActive phaseIReferenceComment
CapillaryBP-11152.Stowell and Wilson, 198512. m/0.22 mm/0.25 «mu»m, He; Program: 120 0X 8 0C/min -> 270 0C 25 0C/min -> 300 0C (5 min)
CapillaryBP-11130.Stowell and Wilson, 198512. m/0.22 mm/0.25 «mu»m, He; Program: not specified
OtherMethyl Silicone1147.Ardrey and Moffat, 1981Program: not specified

Normal alkane RI, polar column, isothermal

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Column typeActive phaseTemperature (C)IReferenceComment
CapillaryCarbowax 20M / KOH150.1629.Caddy, Fish, et al., 1973 
CapillaryCarbowax 20M / KOH150.1638.Caddy, Fish, et al., 1973 
CapillaryCarbowax 20M / KOH150.1649.Caddy, Fish, et al., 1973 

Lee's RI, non-polar column, temperature ramp

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Column typeActive phaseIReferenceComment
CapillaryDB-5MS195.74Chen, Keeran, et al., 200230. m/0.25 mm/0.5 «mu»m, 40. C @ 1. min, 10. K/min; Tend: 310. C
CapillaryDB-5MS195.47Chen, Keeran, et al., 200230. m/0.25 mm/0.5 «mu»m, 40. C @ 1. min, 4. K/min; Tend: 310. C

References

Go To: Top, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Japp, Gill, et al., 1987
Japp, M.; Gill, R.; Osselton, M.D., Comparison of drug retention indices determined on packed, wide bore capillary and narrow bore capillary columns, J. Forensic Sci., 1987, 32, 6, 1574-1586. [all data]

Huber, Kenndler, et al., 1979
Huber, J.F.K.; Kenndler, E.; Reich, G., Quantitation of the Information Content of Multi-Dimensional Gas Chromatography and Low- Resolution Mass Spectrometry in the Identification of Doping Drugs, J. Chromatogr., 1979, 172, 1, 15-30. [doi:10.1016/S0021-9673(00)90941-5] [all data]

Donike and Stratmann, 1976
Donike, M.; Stratmann, D., Gas-chromatographische identifizierung von stimulantien der phenyläthylaminreihe mit hilfe der retnetions-indices, Z. Anal. Chem., 1976, 279, 2, 129-131. [doi:10.1007/BF00440798] [all data]

McLinden and Stenhouse, 1979
McLinden, V.J.; Stenhouse, A.M., A chromatography system for drug identification, Forensic Sci. Int., 1979, 13, 71-79. [doi:10.1016/0379-0738(79)90265-2] [all data]

Moffat, Stead, et al., 1974
Moffat, A.C.; Stead, A.H.; Smalldon, K.W., Optimum use of paper, thin-layer and gas-liquid chromatography for the identification of basic drugs. III. Gas-liquid chromatography, J. Chromatogr., 1974, 90, 1, 19-33. [doi:10.1016/S0021-9673(01)94770-3] [all data]

Tretyakov, 2014
Tretyakov, K.V., Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2014. [all data]

Christ, Noomano, et al., 1988
Christ, D.W.; Noomano, P.; Rosas, M.; Rhone, D., Retention indices by wide-bore capillary gas chromatography with nitrogen-phosphorus detection, J. Anal. Toxicol., 1988, 12, 2, 84-88. [doi:10.1093/jat/12.2.84] [all data]

Anderson and Stafford, 1983
Anderson, W.H.; Stafford, D.T., Applications of capillary gas chromatography in routine toxicological analyses, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 5, 247-254. [doi:10.1002/jhrc.1240060506] [all data]

Perrigo and Peel, 1981
Perrigo, B.J.; Peel, H.W., The use of retention indices and temperature-programmed gas chromatography in analytical toxicology, J. Chromatogr. Sci., 1981, 19, 5, 219-226. [doi:10.1093/chromsci/19.5.219] [all data]

Stowell and Wilson, 1987
Stowell, A.; Wilson, L.W., A simple approach to the interlaboratory transfer of drug retention indices determined by temperature programmed capillary gas chromatography, J. Forensic Sci., 1987, 32, 5, 1214-1220. [all data]

Caddy, Fish, et al., 1973
Caddy, B.; Fish, F.; Scott, D., Chromatographic screening for drugs of abuse using capillary columds. II. Peak identification on support coated open tubular columns for a series of central nervous system stimulating drugs, Chromatographia, 1973, 6, 7, 293-300. [doi:10.1007/BF02269329] [all data]

MHA, 9999
MHA, Directorate of ForensicScience., Forensic Toxicology, 9999. [all data]

Yashiki, Kojima, et al., 1995
Yashiki, M.; Kojima, T.; Miyazaki, T.; Nagasawa, N.; Iwasaki, Y.; Hara, K., Detection of amphetamines in urine using head space-solid phase microextraction and chemical ionization selected ion monitoring, Forensic Sci. Int., 1995, 76, 3, 169-177. [doi:10.1016/0379-0738(95)01819-0] [all data]

Phillips, Logan, et al., 1990
Phillips, A.M.; Logan, B.K.; Stafford, D.T., Further applications for capillary gas chromatography in routine quantitative toxicological analyses, J. Hi. Res. Chromatogr., 1990, 13, 11, 754-758. [doi:10.1002/jhrc.1240131106] [all data]

Stowell and Wilson, 1985
Stowell, A.; Wilson, L., Use of retention indices in drug screening by capillary gas chromatography, Rep. # CD 2362, Department of Scientific and Industrial Reseach, Chemistry Division, Lower Hutt, NZ, 1985, 32. [all data]

Ardrey and Moffat, 1981
Ardrey, R.E.; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. Chromatogr., 1981, 220, 3, 195-252. [doi:10.1016/S0021-9673(00)81925-1] [all data]

Chen, Keeran, et al., 2002
Chen, P.H.; Keeran, W.S.; Van Ausdale, W.A.; Schindler, D.R.; Roberts, D.W., Application of Lee retention indices to the confirmation of tentatively identified compounds from GC/MS analysis of environmental samples, Technical paper, Analytical Services Division, Environmental ScienceEngineering, Inc, PO Box 1703, Gainesville, FL 32602, 2002, 11. [all data]


Notes

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