Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Reaction data

Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Heptane (solution) = C14H21MnO2 (solution) + Carbon monoxide (solution)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

DeltarH° (kJ/mol) Method Reference Comment
196.2 ± 7.5PACHester, Sun, et al., 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by HeSiH3. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
202.1 ± 5.0PACHester, Sun, et al., 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by Me2EtSiH. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
195.4 ± 8.8PACHester, Sun, et al., 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by Et3SiH. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
194.6 ± 8.4PACHester, Sun, et al., 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by Pr3SiH. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
191. ± 13.PACHester, Sun, et al., 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by He3SiH. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
194.6 ± 7.5PACHester, Sun, et al., 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by (i-Bu)3SiH. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
197.5 ± 7.1PACHester, Sun, et al., 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by (i-Pr)3SiH. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
195.4 ± 4.6PACYang and Yang, 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by CH2Cl2. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
197.1 ± 3.8PACYang and Yang, 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by CH2Br2. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
196.2 ± 4.2PACYang and Yang, 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by BuCl. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
195.4 ± 4.2PACYang and Yang, 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by BuBr. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
195.0 ± 2.5PACYang and Yang, 1992solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by PeBr. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
200. ± 17.PACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation.; MS
187.0 ± 5.9PACBurkey, 1990solvent: Heptane; The enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
193.3 ± 5.0PACKlassen, Selke, et al., 1990solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by thf. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
200.0 ± 7.1PACKlassen, Selke, et al., 1990solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by Me2CO. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
199.2 ± 5.9PACKlassen, Selke, et al., 1990solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by cis-cy-C8H14. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS
189.5 ± 5.9PACKlassen, Selke, et al., 1990solvent: Heptane; The reaction is the first of two consecutive reactions, the second being the replacement of heptane by Bu2S. The reaction enthalpy relies on 0.65 for the quantum yield of CO dissociation; MS

References

Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hester, Sun, et al., 1992
Hester, D.M.; Sun, J.; Harper, A.W.; Yang, G.K., J. Am. Chem. Soc., 1992, 114, 5234. [all data]

Yang and Yang, 1992
Yang, P.-F.; Yang, K.G., J. Am. Chem. Soc., 1992, 114, 6937. [all data]

Johnson, Popov, et al., 1991
Johnson, F.P.A.; Popov, V.K.; George, M.W.; Bagratashvili, V.N.; Poliakoff, M.; Turner, J.J., Mendeleev Commun., 1991, 145.. [all data]

Burkey, 1990
Burkey, T.J., J. Am. Chem. Soc., 1990, 112, 8329. [all data]

Klassen, Selke, et al., 1990
Klassen, J.K.; Selke, M.; Sorensen, A.A.; Yang, G.K., J. Am. Chem. Soc., 1990, 112, 1267. [all data]


Notes

Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), References