Propene, hexafluoro-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Propene, hexafluoro- = C3ClF6-

By formula: Cl- + C3F6 = C3ClF6-

Quantity Value Units Method Reference Comment
Δr52.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr21.5 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

Iodide + Propene, hexafluoro- = C3F6I-

By formula: I- + C3F6 = C3F6I-

Quantity Value Units Method Reference Comment
Δr36.0 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr6.0 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

Bromine anion + Propene, hexafluoro- = C3BrF6-

By formula: Br- + C3F6 = C3BrF6-

Quantity Value Units Method Reference Comment
Δr41.4 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr17.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

C3ClF6- + 2Propene, hexafluoro- = C6ClF12-

By formula: C3ClF6- + 2C3F6 = C6ClF12-

Quantity Value Units Method Reference Comment
Δr40.2 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr11.5 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

C6ClF12- + 3Propene, hexafluoro- = C9ClF18-

By formula: C6ClF12- + 3C3F6 = C9ClF18-

Quantity Value Units Method Reference Comment
Δr37.2 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr6.1 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

C3BrF6- + 2Propene, hexafluoro- = C6BrF12-

By formula: C3BrF6- + 2C3F6 = C6BrF12-

Quantity Value Units Method Reference Comment
Δr34.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr7.3 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

C3F6I- + 2Propene, hexafluoro- = C6F12I-

By formula: C3F6I- + 2C3F6 = C6F12I-

Quantity Value Units Method Reference Comment
Δr32.2 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr1.0 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

Propene, hexafluoro- + Chlorine = 1,2-Dichlorohexafluoropropane

By formula: C3F6 + Cl2 = C3Cl2F6

Quantity Value Units Method Reference Comment
Δr-197.27 ± 0.48kJ/molCmLacher, McKinley, et al., 1949gas phase; Heat of chlorination at 363 °K; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Takao, et al., 2002
Hiraoka, K.; Takao, K.; Lino, T.; Nakagawa, F.; Suyama, H.; Mizuno, T.; Yamabe, S., Gas-phase ion-molecule reactions in C3F6, J. Phys. Chem. A, 2002, 106, 4, 603-611, https://doi.org/10.1021/jp0116306 . [all data]

Lacher, McKinley, et al., 1949
Lacher, J.R.; McKinley, J.J.; Walden, C.; Lea, K.; Park, J.D., Reaction heats of organic fluorine compounds. II. The vapor phase heats of chlorination of some simple fluoroolefins, J. Am. Chem. Soc., 1949, 71, 1334-1337. [all data]


Notes

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