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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.12 ± 0.02TRPIGotkis, Oleinikova, et al., 1993LL
8.12 ± 0.01PIPECORuhl, Price, et al., 1989LL
8.138 ± 0.008SAngus, Christ, et al., 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3D3+19.32(C7D5)PIJochims, Rasekh, et al., 1993LL
C5D3+19.90(C5D5)PIJochims, Rasekh, et al., 1993LL
C6D3+20.5 ± 0.5C4D5PIPECORuhl, Price, et al., 1989LL
C6D4+19.75C4D4PIPECORuhl, Price, et al., 1989LL
C6D5+18.87(C4D3)PIJochims, Rasekh, et al., 1993LL
C6D5+19.5C4D3PIPECORuhl, Price, et al., 1989LL
C6D6+15.83C4D2PIJochims, Rasekh, et al., 1993LL
C6D6+16.1 ± 0.1C4D2PIPECORuhl, Price, et al., 1989LL
C6D7+20.5 ± 0.5C4DPIPECORuhl, Price, et al., 1989LL
C7D3+20.5 ± 0.5C3D5PIPECORuhl, Price, et al., 1989LL
C7D4+20.0 ± 0.1C3D4PIPECORuhl, Price, et al., 1989LL
C7D5+16.60C3D3PIJochims, Rasekh, et al., 1993LL
C7D5+18.0 ± 0.1C3D3PIPECORuhl, Price, et al., 1989LL
C8D5+19.3 ± 0.1C2D3PIPECORuhl, Price, et al., 1989LL
C8D6+15.77C2D2PIJochims, Rasekh, et al., 1993LL
C8D6+12.72C2D2EVALGotkis, Oleinikova, et al., 1993T = 0K; LL
C8D6+14.8 ± 0.1C2D2TRPIGotkis, Oleinikova, et al., 1993LL
C8D6+16.0 ± 0.1C2D2PIPECORuhl, Price, et al., 1989LL
C10D6+≤17.7D2PIPECORuhl, Price, et al., 1989LL
C10D7+15.68DPIJochims, Rasekh, et al., 1993LL
C10D7+12.45DEVALGotkis, Oleinikova, et al., 1993T = 0K; LL
C10D7+15.5 ± 0.1DTRPIGotkis, Oleinikova, et al., 1993LL
C10D7+16.1 ± 0.1DPIPECORuhl, Price, et al., 1989LL


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gotkis, Oleinikova, et al., 1993
Gotkis, Y.; Oleinikova, M.; Naor, M.; Lifshitz, C., Time-independent mass spectra and breakdown graphs. 17. Naphthalene and phenanthrene, J. Phys. Chem., 1993, 97, 12282. [all data]

Ruhl, Price, et al., 1989
Ruhl, E.; Price, S.D.; Leach, S., Single and double photoionization processes in naphthalene between 8 and 35 eV, J. Phys. Chem., 1989, 93, 6312. [all data]

Angus, Christ, et al., 1968
Angus, J.G.; Christ, B.J.; Morris, G.C., Absorption spectra in the vacuum ultraviolet and the ionization potentials of naphthalene and naphthalene-d, molecules, Australian J. Chem., 1968, 21, 2153. [all data]

Jochims, Rasekh, et al., 1993
Jochims, H.-W.; Rasekh, H.; Ruhl, E.; Baumgartel, H.; Leach, S., Deuterium isotope effects in the photofragmentation of naphthalene monocations, J. Phys. Chem., 1993, 97, 1312. [all data]


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