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Methanone, (4-nitrophenyl)phenyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to C13H9NO3+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.570 ± 0.087IMREHuh, Kang, et al., 1999«DELTA»G(EA) 343K; anchored to «DELTA»G value. Including anchor «DELTA»S, EA is ca. 0.4 kcal/mol more bound.; B

Ionization energy determinations

IE (eV) Method Reference Comment
10. ± 0.1EIKrenmayr, Heller, et al., 1974LLK
10. ± 0.1EIHeller, Varmuza, et al., 1974LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H5+15.5 ± 0.3?EIKrenmayr, Heller, et al., 1974LLK
C7H4NO3+12.4 ± 0.2?EIKrenmayr, Heller, et al., 1974LLK
C7H4NO3+12.4 ± 0.2?EIHeller, Varmuza, et al., 1974LLK
C7H5O+11.4 ± 0.1?EIKrenmayr, Heller, et al., 1974LLK
C13H8NO2+11.5 ± 0.1?EIKrenmayr, Heller, et al., 1974LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Huh, Kang, et al., 1999
Huh, C.; Kang, C.H.; Lee, H.W.; Nakamura, H.; Mishima, M.; Tsuno, Y.; Yamataka, H., Thermodynamic stabilities and resonance demand of aromatic radical anions in the gas phase, Bull. Chem. Soc. Japan, 1999, 72, 5, 1083-1091, https://doi.org/10.1246/bcsj.72.1083 . [all data]

Krenmayr, Heller, et al., 1974
Krenmayr, P.; Heller, R.; Varmuza, K., Massenspektrometrische untersuchungen an benzophenon und substituierten benzophenonen. I. Ermittlung thermodynamischer grossen, Org. Mass Spectrom., 1974, 9, 998. [all data]

Heller, Varmuza, et al., 1974
Heller, R.; Varmuza, K.; Krenmayr, P., Massenspektrometrische untersuchung des substituenteneffektes bei einfach substituierten benzophenonen, Monatsh. Chem., 1974, 105, 787. [all data]


Notes

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