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Cyclohexane

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-5Petrocol DHSPB-1SPB-1DB-5
Column length (m) 60.50.30.30.30.
Carrier gas  He  He
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (mum) 1.0.50.250.250.25
Tstart (C) 40.35.40.40.40.
Tend (C) 230.200.250.250.310.
Heat rate (K/min) 3.3.10.10.4.
Initial hold (min) 2.10.2.2. 
Final hold (min) 10.10.2.2. 
I 663.655.8647.56648.22656.2
ReferenceEngel and Ratel, 2007Censullo, Jones, et al., 2003LECO Corporation, 2003LECO Corporation, 2003Song, Lai, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5DB-5OV-101
Column length (m) 30.30.30.30.80.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.22
Phase thickness (mum) 0.250.250.250.25 
Tstart (C) 40.40.40.40.30.
Tend (C) 310.310.310.310.130.
Heat rate (K/min) 4.2.4.6.1.
Initial hold (min) 5.    
Final hold (min)      
I 654.9655.4656.2657.6654.6
ReferenceSong, Lai, et al., 2003Song, Lai, et al., 2003Song, Lai, et al., 2003Song, Lai, et al., 2003Yin, Liu, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5DB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (mum) 0.250.250.250.250.25
Tstart (C) 40.40.40.40.40.
Tend (C) 310.310.310.310.310.
Heat rate (K/min) 2.4.6.4.4.
Initial hold (min)     5.
Final hold (min)      
I 655.4656.2657.6656.2654.9
ReferenceLai and Song, 1995Lai and Song, 1995Lai and Song, 1995Lai and Song, 1995Lai and Song, 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Petrocol DHPetrocol DHUltra-1Petrocol DHPetrocol DH
Column length (m) 100.100. 100.100.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.250.25 0.250.25
Phase thickness (mum) 0.50.5 0.50.5
Tstart (C) 30.30.-40.30.30.
Tend (C) 220.220.230.220.220.
Heat rate (K/min) 1.1.4.1.1.
Initial hold (min)      
Final hold (min)      
I 651.20651.24651.651.09651.14
ReferenceSubramaniam, Bochniak, et al., 1994Subramaniam, Bochniak, et al., 1994Olson, Sinkevitch, et al., 1992White, Douglas, et al., 1992White, Douglas, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Petrocol DHPetrocol DHHP-1HP-1HP-1
Column length (m) 100.100.25.25.25.
Carrier gas HeHeN2N2N2
Substrate      
Column diameter (mm) 0.250.250.20.20.2
Phase thickness (mum) 0.50.5   
Tstart (C) 30.30.30.30.30.
Tend (C) 220.220.   
Heat rate (K/min) 1.1.10.2.5.
Initial hold (min)     5.
Final hold (min)      
I 651.668.660.8657.3656.4
ReferenceWhite, Hackett, et al., 1992White, Hackett, et al., 1992Bangjie, Xijian, et al., 1987Bangjie, Xijian, et al., 1987Bangjie, Xijian, et al., 1987
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Ultra-1Ultra-1Ultra-1Ultra-2Ultra-2
Column length (m) 50.50.50.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.220.220.220.22
Phase thickness (mum) 0.330.330.330.330.33
Tstart (C) -30.-30.-30.-30.-30.
Tend (C) 240.240.240.240.240.
Heat rate (K/min) 1.2.3.1.2.
Initial hold (min)      
Final hold (min)      
I 647.36650.41652.19653.15656.24
ReferenceHaynes and Pitzer, 1985Haynes and Pitzer, 1985Haynes and Pitzer, 1985Haynes and Pitzer, 1985Haynes and Pitzer, 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedCapillary
Active phase Ultra-2SE-30OV-101
Column length (m) 50.3.05108.
Carrier gas HeHe 
Substrate  Chromosorb AW 
Column diameter (mm) 0.22 0.25
Phase thickness (mum) 0.33 0.2
Tstart (C) -30.40.35.
Tend (C) 240.210.200.
Heat rate (K/min) 3.10.1.
Initial hold (min)  10. 
Final hold (min)  30. 
I 658.10662.650.
ReferenceHaynes and Pitzer, 1985Buchman, Cao, et al., 1984Hayes and Pitzer, 1981
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Engel and Ratel, 2007
Engel, E.; Ratel, J., Correction of the data generated by mass spectrometry analyses of biological tissues: Application to food authentication, J. Chromatogr. A, 2007, 1154, 1-2, 331-341, https://doi.org/10.1016/j.chroma.2007.02.012 . [all data]

Censullo, Jones, et al., 2003
Censullo, A.C.; Jones, D.R.; Wills, M.T., Speciation of the volatile organic compounds (VOCs) in solventborne aerosol coatings by solid phase microextraction-gas chromatography, J. Coat. Technol., 2003, 75, 936, 47-53, https://doi.org/10.1007/BF02697922 . [all data]

LECO Corporation, 2003
LECO Corporation, Determination of hydrocarbon components in petroleum naphthas, 2003, retrieved from http://www.leco.org/customersupport/apps/separationscience/-190.pdf. [all data]

Song, Lai, et al., 2003
Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s)., Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. [all data]

Yin, Liu, et al., 2001
Yin, C.; Liu, W.; Li, Z.; Pan, Z.; Lin, T.; Zhang, M., Chemometrics to chemical modeling: structural coding in hydrocarbons and retention indices of gas chromatography, J. Sep. Sci., 2001, 24, 3, 213-220, https://doi.org/10.1002/1615-9314(20010301)24:3<213::AID-JSSC213>3.0.CO;2-4 . [all data]

Lai and Song, 1995
Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. and g.c.-m.s. analysis of coal- and petroleum-derived liquid fuels, Fuel, 1995, 74, 10, 1436-1451, https://doi.org/10.1016/0016-2361(95)00108-H . [all data]

Subramaniam, Bochniak, et al., 1994
Subramaniam, B.; Bochniak, D.; Snavely, K., Fischer-Tropsch synthesis in supercritical reaction media, Lawrence Department of Chemical and Petroleum Engineering (DOE/PC/92532--T7), United States Department of Energy, Pittsburgh, PA, 1994, 8, retrieved from http://www.NTIS.gov. [all data]

Olson, Sinkevitch, et al., 1992
Olson, K.L.; Sinkevitch, R.M.; Sloane, T.M., Speciation and Quantitation of Hydrocarbons in Gasoline Engine Exhaust, J. Chromatogr. Sci., 1992, 30, 12, 500-508, https://doi.org/10.1093/chromsci/30.12.500 . [all data]

White, Douglas, et al., 1992
White, C.M.; Douglas, L.J.; Hackett, J.P.; Anderson, R.R., Characterization of synthetic gasoline from the chloromethane-zeolite reaction, Energy Fuels, 1992, 6, 1, 76-82, https://doi.org/10.1021/ef00031a012 . [all data]

White, Hackett, et al., 1992
White, C.M.; Hackett, J.; Anderson, R.R.; Kail, S.; Spock, P.S., Linear temperature programmed retention indices of gasoline range hydrocarbons and chlorinated hydrocarbons on cross-linked polydimethylsiloxane, J. Hi. Res. Chromatogr., 1992, 15, 2, 105-120, https://doi.org/10.1002/jhrc.1240150211 . [all data]

Bangjie, Xijian, et al., 1987
Bangjie, C.; Xijian, G.; Shaoyi, P., Calculation of retention indices in temperature-programmed gas chromatography, Chromatographia, 1987, 23, 12, 888-892, https://doi.org/10.1007/BF02261466 . [all data]

Haynes and Pitzer, 1985
Haynes, P.C., Jr.; Pitzer, E.W., Disengaging solutes in shale- and petroleum-derived jet fuels by altering GC programmed temperature rates, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1985, 8, 5, 230-242, https://doi.org/10.1002/jhrc.1240080504 . [all data]

Buchman, Cao, et al., 1984
Buchman, O.; Cao, G.-Y.; Peng, C.T., Structure assignment by retention index in gas-liquid radiochromatography of substituted cyclohexenes, J. Chromatogr., 1984, 312, 75-90, https://doi.org/10.1016/S0021-9673(01)92765-7 . [all data]

Hayes and Pitzer, 1981
Hayes, P.C., Jr.; Pitzer, E.W., Kovats indices as a tool in characterizing hydrocarbon fuels in temperature programmed glass capillary gas chromatography. Part 1. Qualitative identification, Inhouse rpt. for Air Force Wright Aeronautical Labs., Air Force Wright Aeronautical Labs., Wright-Patterson AFB, Ohio, 1981, 75. [all data]


Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References