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Cyclohexanol

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedCapillaryPackedPackedPacked
Active phase C78, Branched paraffinOV-101C78, Branched paraffinApolaneSE-30
Column length (m) 3.320.3.33.73.
Carrier gas He   Ar
Substrate   Chromosorb G HP Gas Chrom Q (80-100 mesh)
Column diameter (mm)  0.5   
Phase thickness (mum)      
Temperature (C) 130.150.130.130.150.
I 851.1921.1852.9855.885.
ReferenceDallos, Sisak, et al., 2000Cha and Lee, 1994Reddy, Dutoit, et al., 1992Dutoit, 1991Tiess, 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase SE-30Apiezon LApiezon LApiezon LSE-30
Column length (m) 2.   2.
Carrier gas      
Substrate Gaschrom QCelite 545Celite 545  
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 100.120.160.130.120.
I 891.880.900.880.874.
ReferenceWinskowski, 1983Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Pascal, Heintz, et al., 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase SE-30SE-30Apiezon LApiezon LApiezon L
Column length (m) 2.2. 2.32.25
Carrier gas    N2 
Substrate   Chromosorb W AWDCMS-treated Chromosorb WCelite
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 140.160.130.100.130.
I 879.883.878.863.880.
ReferencePascal, Heintz, et al., 1974Pascal, Heintz, et al., 1974Paris and Alexandre, 1972Brown, Chapman, et al., 1968Wehrli and Kováts, 1959
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase Apiezon L
Column length (m) 2.25
Carrier gas  
Substrate Celite
Column diameter (mm)  
Phase thickness (mum)  
Temperature (C) 190.
I 898.
ReferenceWehrli and Kováts, 1959
Comment MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E., Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0 . [all data]

Cha and Lee, 1994
Cha, K.-W.; Lee, D.-J., Prediction of retention indices of various compounds in gas-liquid chromatography, J. Korean Chem. Soc., 1994, 38, 2, 108-120, retrieved from http://journal.kcsnet.or.kr/publi/dh/dh94n2/108.pdf. [all data]

Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz., Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S . [all data]

Dutoit, 1991
Dutoit, J., Gas chromatographic retention behaviour of some solutes on structurally similar polar and non-polar stationary phases, J. Chromatogr., 1991, 555, 1-2, 191-204, https://doi.org/10.1016/S0021-9673(01)87179-X . [all data]

Tiess, 1984
Tiess, D., Gaschromatographische Retentionsindices von 125 leicht- bis mittelflüchtigen organischen Substanzen toxikologisch-analytischer Relevanz auf SE-30, Wiss. Z. Wilhelm-Pieck-Univ. Rostock Math. Naturwiss. Reihe, 1984, 33, 6-9. [all data]

Winskowski, 1983
Winskowski, J., Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren, Chromatographia, 1983, 17, 3, 160-165, https://doi.org/10.1007/BF02271041 . [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Pascal, Heintz, et al., 1974
Pascal, J.C.; Heintz, M.; Druilhe, A.; Lefort, D., Relations entre structure chimique et grandeurs de rétention. III. Stéréoisomères cyclohexaniques, Chromatographia, 1974, 7, 5, 236-245, https://doi.org/10.1007/BF02321774 . [all data]

Paris and Alexandre, 1972
Paris, C.; Alexandre, P., Stereochemical Investigation of Cyclohexane and Terpene Compounds by Gas Chromatography, J. Chromatogr. Sci., 1972, 10, 6, 402-411, https://doi.org/10.1093/chromsci/10.6.402 . [all data]

Brown, Chapman, et al., 1968
Brown, I.; Chapman, I.L.; Nicholson, G.J., Gas chromatography of polar solutes in electron acceptor stationary phases, Aust. J. Chem., 1968, 21, 5, 1125-1141, https://doi.org/10.1071/CH9681125 . [all data]

Wehrli and Kováts, 1959
Wehrli, A.; Kováts, E., Gas-chromatographische Charakterisierung ogranischer Verbindungen. Teil 3: Berechnung der Retentionsindices aliphatischer, alicyclischer und aromatischer Verbindungen, Helv. Chim. Acta, 1959, 7, 7, 2709-2736, https://doi.org/10.1002/hlca.19590420745 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References