Benzene, 1-chloro-3-methyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil435.2KN/AWeast and Grasselli, 1989BS
Tboil431.2KN/AOgimachi, Andrews, et al., 1955Uncertainty assigned by TRC = 2. K; TRC
Tboil434.89KN/AStuckey and Saylor, 1940Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tfus225.35KN/AMartin, Yalkowsky, et al., 1979Uncertainty assigned by TRC = 0.5 K; TRC
Tfus224.26KN/ABrown and Stock, 1957Uncertainty assigned by TRC = 0.6 K; TRC
Tfus246.9KN/ATimmermans, 1934as reported in Chem. Abstracts; TRC
Tfus225.35KN/AHaase, 1893Uncertainty assigned by TRC = 2. K; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
10.0388.N/ADykyj, Svoboda, et al., 1999Based on data from 373. - 435. K.; AC
10.4292.AStephenson and Malanowski, 1987Based on data from 277. - 436. K. See also Stull, 1947.; AC
11.0288.N/AStuckey and Saylor, 1940, 2Based on data from 273. - 348. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
277.9 - 435.54.475771807.576-32.105Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Ogimachi, Andrews, et al., 1955
Ogimachi, N.N.; Andrews, L.J.; Keefer, R.M., The Free Energies and Heats of Formation of Polyalkoxybenzene-Iodine Monochloride Complexes, J. Am. Chem. Soc., 1955, 77, 4202. [all data]

Stuckey and Saylor, 1940
Stuckey, J.M.; Saylor, J.H., Vapor Pressures of Organic Compounds I., J. Am. Chem. Soc., 1940, 62, 2922. [all data]

Martin, Yalkowsky, et al., 1979
Martin, E.L.; Yalkowsky, S.H.; Wells, J.E., J. Pharm. Sci., 1979, 68, 565. [all data]

Brown and Stock, 1957
Brown, H.C.; Stock, L.M., J. Am. Chem. Soc., 1957, 79, 5175. [all data]

Timmermans, 1934
Timmermans, J., Theory of Concentrated Solutions XII., Bull. Soc. Chim. Belg., 1934, 43, 626. [all data]

Haase, 1893
Haase, E., Chem. Ber., 1893, 26, 1053. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, . [all data]

Stuckey and Saylor, 1940, 2
Stuckey, James M.; Saylor, John H., The Vapor Pressures of Some Organic Compounds. I. 1, J. Am. Chem. Soc., 1940, 62, 11, 2922-2925, . [all data]


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