Benzene, 1-methyl-4-propyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 2HP-1HP-1OV-101OV-101
Column length (m) 100.25.25.50.50.
Carrier gas  N2N2 He
Substrate      
Column diameter (mm) 0.250.200.200.250.20
Phase thickness (μm) 0.25    
Temperature (C) 80.60.60.100.100.
I 1046.01032.1032.1046.51046.
ReferenceEstel, Mohnke, et al., 1995Zhang, Li, et al., 1992Zhang, Li, et al., 1992Dimov and Mekenyan, 1989Matisová, Kovacicová, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101OV-101
Column length (m) 278.278.278.278.278.
Carrier gas H2H2H2H2H2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)      
Temperature (C) 100.100.100.100.100.
I 1046.1046.1046.1047.1047.
ReferenceMatisová, Rukríglová, et al., 1988Matisová, Rukríglová, et al., 1988Matisová, Rukríglová, et al., 1988Matisová, Rukríglová, et al., 1988Matisová, Rukríglová, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101SqualaneSE-30OV-101OV-101
Column length (m) 278. 15.50.50.
Carrier gas H2 N2N2N2
Substrate      
Column diameter (mm) 0.25 0.250.300.30
Phase thickness (μm)      
Temperature (C) 100.100.70.100.120.
I 1047.1040.1038.11048.1053.
ReferenceMatisová, Rukríglová, et al., 1988Nabivach and Vasiliev, 1987Tóth, 1983Gerasimenko and Nabivach, 1982Gerasimenko and Nabivach, 1982
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101SqualaneSqualaneOV-101OV-101
Column length (m) 50.50.50.50.50.
Carrier gas N2N2N2N2N2
Substrate      
Column diameter (mm) 0.300.250.250.30.3
Phase thickness (μm)      
Temperature (C) 140.86.96.100.120.
I 1058.1035.91038.81047.51052.6
ReferenceGerasimenko and Nabivach, 1982Macák, Nabivach, et al., 1982Macák, Nabivach, et al., 1982Gerasimenko, Kirilenko, et al., 1981Gerasimenko, Kirilenko, et al., 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101SE-30SqualaneSqualaneSqualane
Column length (m) 50. 45.750.50.
Carrier gas N2    
Substrate      
Column diameter (mm) 0.3 0.250.250.25
Phase thickness (μm)      
Temperature (C) 140.65.80.86.96.
I 1057.71035.41033.01035.91038.8
ReferenceGerasimenko, Kirilenko, et al., 1981Kuchhal, Kumar, et al., 1980Kuchhal, Kumar, et al., 1980Nabivach, Bur'yan, et al., 1978Nabivach, Bur'yan, et al., 1978
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSE-30SqualaneSqualane
Column length (m) 100.100.25.510.545.
Carrier gas N2H2HeHeN2
Substrate      
Column diameter (mm) 0.230.250.50.250.2
Phase thickness (μm)      
Temperature (C) 100.80.65.100.92.
I 1040.1033.021035.41039.31039.
ReferenceEngewald and Wennrich, 1976Soják and Rijks, 1976Svob and Deur-Siftar, 1974Svob and Deur-Siftar, 1974Krupcík, Liska, et al., 1970
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase Squalane
Column length (m) 200.
Carrier gas N2
Substrate  
Column diameter (mm) 0.2
Phase thickness (μm)  
Temperature (C) 115.
I 1044.0
ReferenceKrupcík, Liska, et al., 1970
Comment MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Estel, Mohnke, et al., 1995
Estel, D.; Mohnke; Biermans; Rotzsche, The analysis of C4-C11 hydrocarbons in naphtha and reformate with a new apolar fused silica column, J. Hi. Res. Chromatogr., 1995, 18, 7, 403-412, https://doi.org/10.1002/jhrc.1240180703 . [all data]

Zhang, Li, et al., 1992
Zhang, M.J.; Li, S.D.; Chen, B.J., Compositional studies of high-temperature coal tar by GC/FTIR analysis of light oil fractions, Chromatographia, 1992, 33, 3/4, 138-146, https://doi.org/10.1007/BF02275894 . [all data]

Dimov and Mekenyan, 1989
Dimov, N.; Mekenyan, Ov., Quantitative Relationships Between the Structure of Alkylbenzenes and Their Gas Chromatographic Retention on Stationary Phasses with Different Polarity, J. Chromatogr., 1989, 471, 227-236, https://doi.org/10.1016/S0021-9673(00)94170-0 . [all data]

Matisová, Kovacicová, et al., 1989
Matisová, E.; Kovacicová, E.; Ha, P.T.; Kolek, E.; Engewald, W., Identification of alkylbenzenes up to C12 by capillary gas chromatography-mass spectrometry. II. Retention indices on OV-101 columns and retention-molecular structure correlations, J. Chromatogr., 1989, 475, 2, 113-123, https://doi.org/10.1016/S0021-9673(01)89667-9 . [all data]

Matisová, Rukríglová, et al., 1988
Matisová, E.; Rukríglová, M.; Krupcík, J.; Kovacicová, E.; Holotík, S., Identification of alkylbenzenes up to C12 by capillary gas chromatography and combined gas chromatography-mass spectrometry. I. OV-101 as stationary phase, J. Chromatogr., 1988, 455, 301-309, https://doi.org/10.1016/S0021-9673(01)82129-4 . [all data]

Nabivach and Vasiliev, 1987
Nabivach, V.M.; Vasiliev, E.E.E., Correlation dependencies of GC retention indices from physical chemical properties and structures of aromatic hydrocarbons, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 1987, 30, 72-75. [all data]

Tóth, 1983
Tóth, T., Use of capillary gas chromatography in collecting retention and chemical information for the analysis of complex petrochemical mixtures, J. Chromatogr., 1983, 279, 157-165, https://doi.org/10.1016/S0021-9673(01)93614-3 . [all data]

Gerasimenko and Nabivach, 1982
Gerasimenko, V.A.; Nabivach, V.M., Relationship between molecular structure and gas chromatographic retention of alkylbenzenes C8-C1 2 on polydimethylsiloxane, Zh. Anal. Khim., 1982, 37, 110-116. [all data]

Macák, Nabivach, et al., 1982
Macák, J.; Nabivach, V.; Buryan, P.; Sindler, S., Dependence of retention indices of alkylbenzenes on their molecular structure, J. Chromatogr., 1982, 234, 2, 285-302, https://doi.org/10.1016/S0021-9673(00)81867-1 . [all data]

Gerasimenko, Kirilenko, et al., 1981
Gerasimenko, V.A.; Kirilenko, A.V.; Nabivach, V.M., Capillary gas chromatography of aromatic compounds found in coal tar fractions, J. Chromatogr., 1981, 208, 1, 9-16, https://doi.org/10.1016/S0021-9673(00)87953-4 . [all data]

Kuchhal, Kumar, et al., 1980
Kuchhal, R.K.; Kumar, B.; Kumar, P.; Gupta, P.L., Determination of the isomeric distribution and associated impurities in commercial diethylbenzenes by capillary gas chromatography, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1980, 3, 10, 497-502, https://doi.org/10.1002/jhrc.1240031003 . [all data]

Nabivach, Bur'yan, et al., 1978
Nabivach, V.M.; Bur'yan, P.; Matsak, I., Retention indices of aromatic hydrocarbons on a squalane capillary column, Zh. Anal. Khim., 1978, 33, 7, 1108-1113. [all data]

Engewald and Wennrich, 1976
Engewald, W.; Wennrich, L., Molekülstruktur und Retentionsverhalten. VIII. Zum Retentionsverhalten höherer Alkylbenzole bei der Gas-Verteilungs-Chromatographie, Chromatographia, 1976, 9, 11, 540-547, https://doi.org/10.1007/BF02275960 . [all data]

Soják and Rijks, 1976
Soják, L.; Rijks, J.A., Capillary gas chromatography of alkylbenzenes. I. Some problems encountered with the precision of the retention indcies of alkylbenzenes, J. Chromatogr., 1976, 119, 505-521, https://doi.org/10.1016/S0021-9673(00)86812-0 . [all data]

Svob and Deur-Siftar, 1974
Svob, V.; Deur-Siftar, D., Kovats Retention Indices in the Identification of Alkylbenzene Degradation Products, J. Chromatogr., 1974, 91, 677-689, https://doi.org/10.1016/S0021-9673(01)97947-6 . [all data]

Krupcík, Liska, et al., 1970
Krupcík, J.; Liska, O.; Soják, L., The applicability of the linear free energy relationships for the identification of some alkyl aromatic hydrocarbons by open tubular column gas chromatography, J. Chromatogr., 1970, 51, 119-127, https://doi.org/10.1016/S0021-9673(01)96846-3 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References