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2-Butene, 2-(ethylthio)-, (Z)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: H.Y. Afeefy, J.F. Liebman, and S.E. Stein

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Individual Reactions

2-(Ethylthio)-1-butene = 2-Butene, 2-(ethylthio)-, (Z)-

By formula: C6H12S = C6H12S

Quantity Value Units Method Reference Comment
Deltar-5.4 ± 0.2kJ/molEqkKimmelma and Taskinen, 1987liquid phase; solvent: THF; Isomerization

trans-1-(Ethylthio)-2-butene = 2-Butene, 2-(ethylthio)-, (Z)-

By formula: C6H12S = C6H12S

Quantity Value Units Method Reference Comment
Deltar3.6 ± 0.3kJ/molEqkKimmelma, 1987liquid phase; solvent: DMSO

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kimmelma and Taskinen, 1987
Kimmelma, R.; Taskinen, E., Structure-stability relationships in vinyl sulfides. II. Stabilization energies due to alkyl and alkylthio groups attached to the «beta» carbon of vinyl sulfides and vinyl ethers, Acta Chem. Scand., 1987, 41, 271-277. [all data]

Kimmelma, 1987
Kimmelma, R., The stabilization due to the methyl group in RSCH2CH=CHCH3, Acta Chem. Scand., 1987, 41, 344-347. [all data]


Notes

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