Citronellol

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Van Den Dool and Kratz RI, polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20BP-20BP-20ZB-WaxDB-Wax
Column length (m) 50.50.50.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.220.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.50.40.
Tend (C) 220.220.220.220.240.
Heat rate (K/min) 2.2.2.4.6.
Initial hold (min)    1.10.
Final hold (min) 20.20.20.10.25.
I 1762.1765.1761.1769.1750.
ReferenceBoti, Koukoua, et al., 2007Duquesnoy, Castola, et al., 2007Gonny, Cavaleiro, et al., 2006Ugliano, Bartowsky, et al., 2006Varming, Andersen, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxStabilwaxDB-WaxInnowax
Column length (m) 60.30.30.30.30.
Carrier gas N2HeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.251.0.250.25
Tstart (C) 70.40.40.40.40.
Tend (C) 230.250.230.250.200.
Heat rate (K/min) 2.3.4.3.5.
Initial hold (min) 2. 2. 5.
Final hold (min) 20.20.10.20.2.
I 1771.1755.1760.1757.1717.
ReferenceChoi, 2005Fanciullino, Gancel, et al., 2005Fang and Qian, 2005Gancel, Ollitrault, et al., 2005Pena, Barciela, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-WaxDB-WaxRTX-WaxZB-Wax
Column length (m) 30.30.60.30.30.
Carrier gas HeliumN2HeHeHe
Substrate      
Column diameter (mm) 0.320.250.320.250.25
Phase thickness (μm) 0.500.250.250.250.15
Tstart (C) 40.60.32.45.35.
Tend (C) 240.220.220.240.220.
Heat rate (K/min) 7.5.3.3.1.8
Initial hold (min)  10. 6.10.
Final hold (min) 5.  10.10.
I 1773.1722.1774.1752.1768.
ReferenceBell, 2004Bertoli, Pistelli, et al., 2004Brophy, Goldsack, et al., 2004Dugo, Mondello, et al., 2004Ledauphin, Saint-Clair, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase InnowaxSupelcowaxSupelcowaxDB-WaxDB-Wax
Column length (m) 15.25.25.60.60.
Carrier gas He  N2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 35.35.35.70.40.
Tend (C) 225.225.225.230.210.
Heat rate (K/min) 4.4.4.2.2.
Initial hold (min) 5.5.5.2. 
Final hold (min) 20.10.10.20.40.
I 1779.1775.1775.1771.1754.
ReferenceChisholm, Jell, et al., 2003Chisholm, Wilson, et al., 2003Chisholm, Wilson, et al., 2003Choi, 2003Chyau, Ko, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxDB-WaxDB-WaxBP-20
Column length (m) 60.30.60.60.50.
Carrier gas H2 N2HeHe
Substrate      
Column diameter (mm) 0.320.320.250.320.22
Phase thickness (μm) 0.250.50.250.50.25
Tstart (C) 40.40.70.67.60.
Tend (C) 245.240.230.235.220.
Heat rate (K/min) 1.57.2.2.72.
Initial hold (min)      
Final hold (min) 20.5.20.30.20.
I 1757.1773.1767.1786.1756.
ReferenceGancel, Ollitrault, et al., 2003Högnadóttir and Rouseff, 2003Choi, Kim. M.-S.L., et al., 2002Claudela, Dirningera, et al., 2002Lota, de Rocca Serra, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20DB-WaxBP-20DB-WaxDB-Wax
Column length (m) 50.30.50.30.30.
Carrier gas  HeHeH2He
Substrate      
Column diameter (mm) 0.220.320.220.320.32
Phase thickness (μm) 0.250.500.250.250.5
Tstart (C) 60.40.60.35.60.
Tend (C) 220.240.220.220.245.
Heat rate (K/min) 2.7.2.4.3.
Initial hold (min)    0.53.
Final hold (min) 20.5.  20.
I 1755.1774.1756.1773.61760.
ReferencePintore, Usai, et al., 2002Lin and Rouseff, 2001Lota, Serra, et al., 2001Pet'ka, Mocák, et al., 2001Wirth, Guo, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxDB-WaxDB-WaxBP-20
Column length (m) 60.60.30.60.50.
Carrier gas HeHe N2He
Substrate      
Column diameter (mm) 0.50.530.320.250.22
Phase thickness (μm) 0.321.00.50.250.25
Tstart (C) 40.50.60.70.60.
Tend (C) 290.220.245.230.230.
Heat rate (K/min) 4.3.3.2.2.
Initial hold (min) 2. 3.2. 
Final hold (min) 5. 20.20.35.
I 1730.1770.1765.1772.1756.
ReferenceBartley and Jacobs, 2000Brophy, Goldsack, et al., 2000Bureau, Razungles, et al., 2000Choi and Sawamura, 2000Lota, de Rocca Serra, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20DB-WaxDB-WaxBP-20SP-1000
Column length (m) 50.60.30.50.85.
Carrier gas HeHeH2HeHe
Substrate      
Column diameter (mm) 0.220.530.250.220.5
Phase thickness (μm) 0.25 0.250.25 
Tstart (C) 60.50.60.60.60.
Tend (C) 230.220.220.230.225.
Heat rate (K/min) 2.3.2.2.3.
Initial hold (min)   3.  
Final hold (min) 35.  35. 
I 1756.1770.1760.1756.1770.
ReferenceLota, de Rocca Serra, et al., 2000Brophy, Goldsack, et al., 1999Chassagne, Boulanger, et al., 1999Lota, Serra, et al., 1999Brophy, Forster, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxCarbowax 20MCarbowax 20MHP-20M
Column length (m) 60.25.60.50.50.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.320.20.25
Phase thickness (μm) 0.250.250.4250.2 
Tstart (C) 40.50.45.30.60.
Tend (C) 200.240.300.170.190.
Heat rate (K/min) 3.4.3.4.3.
Initial hold (min) 5.3.3.2. 
Final hold (min) 60. 20.20. 
I 1763.1759.1747.1719.1737.
ReferenceCha, Kim, et al., 1998Möllenbeck, König, et al., 1997Mondello, Dugo, et al., 1995Píry, Príbela, et al., 1995Chung, Eiserich, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-FFAPDB-WaxDB-WaxDB-WaxDB-Wax
Column length (m) 50.30.30.30.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.320.320.25
Phase thickness (μm)  0.250.250.5 
Tstart (C) 60.50.40.40.50.
Tend (C) 210.220.220.220.240.
Heat rate (K/min) 3.4.5.3.2.
Initial hold (min)  3.3.  
Final hold (min)  20.   
I 1781.1748.1777.1771.1760.7
ReferenceChung, Eiserich, et al., 1993Humpf and Schreier, 1991Frohlich and Schreier, 1990Le Quere and Latrasse, 1990Chang, Sheng, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxDB-WaxCarbowax 20M
Column length (m) 30.30.30.60.
Carrier gas  HeHeHe
Substrate     
Column diameter (mm) 0.250.250.250.32
Phase thickness (μm)  0.250.25 
Tstart (C) 50.50.50.50.
Tend (C) 240.250.250.225.
Heat rate (K/min) 2.4.4.1.5
Initial hold (min)  3.3. 
Final hold (min)    80.
I 1762.61777.1778.1769.
ReferenceChang, Sheng, et al., 1989Fröhlich, Duque, et al., 1989Fröhlich, Duque, et al., 1989Chen and Ho, 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Boti, Koukoua, et al., 2007
Boti, J.B.; Koukoua, G.; N'Guessan, T.Y.; Casanova, J., Chemical variability of Conyza sumatrensis and Microglossa pyrifolia from Côte d'Ivoire, Flavour Fragr. J., 2007, 22, 1, 27-31, https://doi.org/10.1002/ffj.1743 . [all data]

Duquesnoy, Castola, et al., 2007
Duquesnoy, E.; Castola, V.; Casanova, J., Composition and chemical variability of the twig oil of Abies alba Miller from Corsica, Flavour Fragr. J., 2007, 22, 4, 293-299, https://doi.org/10.1002/ffj.1796 . [all data]

Gonny, Cavaleiro, et al., 2006
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Ugliano, Bartowsky, et al., 2006
Ugliano, M.; Bartowsky, E.J.; McCarthy, J.; Moio, L.; Henschke, P.A., Hydrolysis and Transformation of Grape Glycosidically Bound Volatile Compounds during Fermentation with Three Saccharomyces Yeast Strains, J. Agric. Food Chem., 2006, 54, 17, 6322-6331, https://doi.org/10.1021/jf0607718 . [all data]

Varming, Andersen, et al., 2006
Varming, C.; Andersen, M.L.; Poll, L., Volatile Monoterpenes in Black Currant (Ribes nigrum L.) Juice: Effects of Heating and Enzymatic Treatment by β-Glucosidase, J. Agric. Food Chem., 2006, 54, 6, 2298-2302, https://doi.org/10.1021/jf051938k . [all data]

Choi, 2005
Choi, H.-S., Characteristic odor components of kumquat (Fortunella japonica Swingle) peel oil, J. Agric. Food Chem., 2005, 53, 5, 1642-1647, https://doi.org/10.1021/jf040324x . [all data]

Fanciullino, Gancel, et al., 2005
Fanciullino, A.-L.; Gancel, A.-L.; Froelicher, Y.; Luro, F.; Ollitrault, P.; Brillouet, J.-M., Effects of Nucleo-cytoplasmic Interactions on Leaf Volatile Compounds from Citrus Somatic Diploid Hybrids, J. Agric. Food Chem., 2005, 53, 11, 4517-4523, https://doi.org/10.1021/jf0502855 . [all data]

Fang and Qian, 2005
Fang, Y.; Qian, M., Aroma compounds in Oregon Pinot Noir wine determined by aroma extract dilution analysis (AEDA), Flavour Fragr. J., 2005, 20, 1, 22-29, https://doi.org/10.1002/ffj.1551 . [all data]

Gancel, Ollitrault, et al., 2005
Gancel, A.-L.; Ollitrault, P.; Froelicher, Y.; Tomi, F.; Jacquemond, C.; Luro, F.; Brillouet, J.-M., Leaf volatile compounds of six citrus somatic allotetraploid hybrids originating from various combinations of lime, lemon, citron, sweet orange, and grapefruit, J. Agric. Food Chem., 2005, 53, 6, 2224-2230, https://doi.org/10.1021/jf048315b . [all data]

Pena, Barciela, et al., 2005
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Bell, 2004
Bell, W.A.-M., Examination of Aroma Volatiles Formed from Thermal Processing of Florida Reconstituted Grapefruit Juice. A Thesis presented to the graduate school of the university of Florida in partial fulfillment of the requirements for the degree of master of science, 2004. [all data]

Bertoli, Pistelli, et al., 2004
Bertoli, A.; Pistelli, L.; Morelli, I.; Fraternale, D.; Giamperi, L.; Ricci, D., Volatile constituents of different parts (roots, stems and leaves) of Smyrnium olusatrum L., Flavour Fragr. J., 2004, 19, 6, 522-525, https://doi.org/10.1002/ffj.1382 . [all data]

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Ledauphin, Saint-Clair, et al., 2004
Ledauphin, J.; Saint-Clair, J.-F.; Lablanquie, O.; Guichard, H.; Founier, N.; Guichard, E.; Barillier, D., Identification of trace volatile compounds in freshly distilled calvados and cognac using preparative separations coupled with gas chromatography-mass spectrometry, J. Agric. Food Chem., 2004, 52, 16, 5124-5134, https://doi.org/10.1021/jf040052y . [all data]

Chisholm, Jell, et al., 2003
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Chisholm, Wilson, et al., 2003
Chisholm, M.G.; Wilson, M.A.; Gaskey, G.M., Characterization of aroma volatiles in key lime essential oils (Cirtrus aurantifolia Swingle), Flavour Fragr. J., 2003, 18, 2, 106-115, https://doi.org/10.1002/ffj.1172 . [all data]

Choi, 2003
Choi, H.-S., Character impact odorants of Citrus Hallabong [(C. unshiu Marcov × C. sinensis Osbeck) × C. reticulata Blanco] cold-pressed peel oil, J. Agric. Food Chem., 2003, 51, 9, 2687-2692, https://doi.org/10.1021/jf021069o . [all data]

Chyau, Ko, et al., 2003
Chyau, C.-C.; Ko, P.-T.; Chang, C.-H.; Mau, J.-L., Free and glycosidically bound aroma compounds in lychee (Litchi chinensis Sonn.), Food Chem., 2003, 80, 3, 387-392, https://doi.org/10.1016/S0308-8146(02)00278-9 . [all data]

Gancel, Ollitrault, et al., 2003
Gancel, A.-L.; Ollitrault, P.; Froelicher, Y.; Tomi, F.; Jacquemond, C.; Luro, F.; Brillouet, J.-M., Leaf volatile compounds of seven citrus somatic tetraploid hybrids sharing willow leaf mandarin (Citrus deliciosa Ten.) as their common parent, J. Agric. Food Chem., 2003, 51, 20, 6006-6013, https://doi.org/10.1021/jf0345090 . [all data]

Högnadóttir and Rouseff, 2003
Högnadóttir, Á.; Rouseff, R.L., Identification of aroma active compounds in organce essence oil using gas chromatography-olfactometry and gas chromatography-mass spectrometry, J. Chromatogr. A, 2003, 998, 1-2, 201-211, https://doi.org/10.1016/S0021-9673(03)00524-7 . [all data]

Choi, Kim. M.-S.L., et al., 2002
Choi, H.-S.; Kim. M.-S.L.; Sawamura, M., Constituents of the essential oil of cnidium officinale Makino, a Korean medicinal plant, Flavour Fragr. J., 2002, 17, 1, 49-53, https://doi.org/10.1002/ffj.1038 . [all data]

Claudela, Dirningera, et al., 2002
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Lota, de Rocca Serra, et al., 2002
Lota, M.-L.; de Rocca Serra, D.; Tomi, F.; Jacquemond, C.; Casanova, J., Volatile components of peel and leaf oils of lemon and lime species, J. Agric. Food Chem., 2002, 50, 4, 796-805, https://doi.org/10.1021/jf010924l . [all data]

Pintore, Usai, et al., 2002
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Lin and Rouseff, 2001
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Lota, Serra, et al., 2001
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Pet'ka, Mocák, et al., 2001
Pet'ka, J.; Mocák, J.; Farkas, P.; Balla, B.; Kovác, M., Classification of Slovak varietal white wines by volatile compounds, J. Sci. Food Agric., 2001, 81, 15, 1533-1539, https://doi.org/10.1002/jsfa.979 . [all data]

Wirth, Guo, et al., 2001
Wirth, J.; Guo, W.; Baumes, R.; Günata, Z., Volatile compounds released by enzymatic hydrolysis of glycoconjugates of leaves and grape berries from Vitis vinifera muscat of Alexandria and Shiraz cultivars, J. Agric. Food Chem., 2001, 49, 6, 2917-2923, https://doi.org/10.1021/jf001398l . [all data]

Bartley and Jacobs, 2000
Bartley, J.P.; Jacobs, A.L., Effects of drying on flavour compounds in Australian-grown ginger (Zingiber officinale), J. Sci. Food Agric., 2000, 80, 2, 209-215, https://doi.org/10.1002/(SICI)1097-0010(20000115)80:2<209::AID-JSFA516>3.0.CO;2-8 . [all data]

Brophy, Goldsack, et al., 2000
Brophy, J.J.; Goldsack, R.J.; Punruckvong, A.; Bean, A.R.; Forster, P.I.; Lepschi, B.J.; Doran, J.C.; Rozefelds, A.C., Leaf essential oils of the genus Leptospermum (Myrtaceae) in eastern Australia. Part 7. Leptospermum petersonii, L. liversidgei and allies, Flavour Fragr. J., 2000, 15, 5, 342-351, https://doi.org/10.1002/1099-1026(200009/10)15:5<342::AID-FFJ924>3.0.CO;2-V . [all data]

Bureau, Razungles, et al., 2000
Bureau, S.M.; Razungles, A.R.; Baumes, R.L., The aroma of Muscat of Frontignan grapes: effect of the light environment of vine or bunch on volatiles and glycoconjugates, J. Sci. Food Agric., 2000, 80, 14, 2012-2020, https://doi.org/10.1002/1097-0010(200011)80:14<2012::AID-JSFA738>3.0.CO;2-X . [all data]

Choi and Sawamura, 2000
Choi, H.-S.; Sawamura, M., Composition of the essential oil of Citrus tamurana Hort. ex Tanaka (Hyuganatsu), J. Agric. Food Chem., 2000, 48, 10, 4868-4873, https://doi.org/10.1021/jf000651e . [all data]

Lota, de Rocca Serra, et al., 2000
Lota, M.-L.; de Rocca Serra, D.; Tomi, F.; Casanova, J., Chemical variability of peel and leaf essential oils of mandarins from Citrus reticulata Blanco, Biochem. Syst. Ecol., 2000, 28, 1, 61-78, https://doi.org/10.1016/S0305-1978(99)00036-8 . [all data]

Brophy, Goldsack, et al., 1999
Brophy, J.J.; Goldsack, R.J.; Bean, A.R.; Forster, P.I.; Lepschi, B.J., Leaf essential oils of the genus Leptospermum (Myrtaceae) in eastern Australia. Part 5. Leptospermum continentale and allies, Flavour Fragr. J., 1999, 14, 2, 98-104, https://doi.org/10.1002/(SICI)1099-1026(199903/04)14:2<98::AID-FFJ797>3.0.CO;2-V . [all data]

Chassagne, Boulanger, et al., 1999
Chassagne, D.; Boulanger, R.; Crouzet, J., Enzymatic hydrolysis of edible Passiflora fruit glycosides, Food Chem., 1999, 66, 3, 281-288, https://doi.org/10.1016/S0308-8146(99)00044-8 . [all data]

Lota, Serra, et al., 1999
Lota, M.-L.; Serra, D.R.; Tomi, F.; Bessiere, J.-M.; Casanova, J., Chemical composition of peel and leaf essential oils of Citrus medica L. and C. limonimedica Lush., Flavour Fragr. J., 1999, 14, 3, 161-166, https://doi.org/10.1002/(SICI)1099-1026(199905/06)14:3<161::AID-FFJ801>3.0.CO;2-8 . [all data]

Brophy, Forster, et al., 1998
Brophy, J.J.; Forster, P.I.; Goldsack, R.J., The essential oils of three unusual Eucalypts: Eucalyptus curtisii, E. rubiginosa and E. tenuipes (Myrtaceae), Flavour Fragr. J., 1998, 13, 2, 87-89, https://doi.org/10.1002/(SICI)1099-1026(199803/04)13:2<87::AID-FFJ699>3.0.CO;2-Y . [all data]

Cha, Kim, et al., 1998
Cha, Y.J.; Kim, H.; Cadwallader, K.R., Aroma-active compounds in Kimchi during fermentation, J. Agric. Food Chem., 1998, 46, 5, 1944-1953, https://doi.org/10.1021/jf9706991 . [all data]

Möllenbeck, König, et al., 1997
Möllenbeck, S.; König, T.; Schreier, P.; Schwab, W.; Rajaonarivony, J.; Ranarivelo, L., Chemical composition and analyses of enantiomers of essential oils from Madagascar, Flavour Fragr. J., 1997, 12, 2, 63-69, https://doi.org/10.1002/(SICI)1099-1026(199703)12:2<63::AID-FFJ614>3.0.CO;2-Z . [all data]

Mondello, Dugo, et al., 1995
Mondello, L.; Dugo, P.; Basile, A.; Dugo, G., Interactive use of linear retention indices, on polar and apolar columns, with a MS-library for reliable identification of complex mixtures, J. Microcolumn Sep., 1995, 7, 6, 581-591, https://doi.org/10.1002/mcs.1220070605 . [all data]

Píry, Príbela, et al., 1995
Píry, J.; Príbela, A.; Durcanská, J.; Farkas, P., Fractionation of volatiles from blackcurrant (Ribes nigrum L.) by different extractive methods, Food Chem., 1995, 54, 1, 73-77, https://doi.org/10.1016/0308-8146(95)92665-7 . [all data]

Chung, Eiserich, et al., 1993
Chung, T.Y.; Eiserich, J.P.; Shibamoto, T., Volatile compounds isolated from edible Korean chamchwi (Aster scaber Thunb), J. Agric. Food Chem., 1993, 41, 10, 1693-1697, https://doi.org/10.1021/jf00034a033 . [all data]

Humpf and Schreier, 1991
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Notes

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