Silanol, trimethyl-, phosphate (3:1)
- Formula: C9H27O4PSi3
- Molecular weight: 314.5385
- IUPAC Standard InChI: InChI=1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3
- IUPAC Standard InChIKey: QJMMCGKXBZVAEI-UHFFFAOYSA-N
- CAS Registry Number: 10497-05-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Tris(trimethylsilyl) phosphate; Phosphoric acid, tris(trimethylsilyl) ester; Tris-(trimethylsilyl)fosfat; Phosphoric acid, tris-TMS; Phosphoric acid, triTMS; Phosphoric acid, TMS
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Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Packed |
|---|---|---|---|---|
| Active phase | HP-5 MS | HP-5 | HP-5 | SE-30 |
| Column length (m) | 30. | 30. | 30. | |
| Carrier gas | Helium | Helium | ||
| Substrate | ||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 80. | 50. | 50. | 70. |
| Tend (C) | 320. | 300. | 300. | 150. |
| Heat rate (K/min) | 5. | 3. | 3. | 5. |
| Initial hold (min) | ||||
| Final hold (min) | 30. | 30. | ||
| I | 1292. | 1286. | 1286. | 1273. |
| Reference | Erxleben, Gessler, et al., 2012 | Isidorov, Lech, et al., 2008 | Isidorov, Lech, et al., 2008 | Butts and Rainey, 1971 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Erxleben, Gessler, et al., 2012
Erxleben, A.; Gessler, A.; Vervliet-Scheebaum, M.; Reski, R.,
Metabolite profiling of the moss Physcomitrella patens reveals evolutionary conservation of osmoprotective substances,
Plant Cell Rep., 2012, 31, 2, 427-436, https://doi.org/10.1007/s00299-011-1177-9
. [all data]
Isidorov, Lech, et al., 2008
Isidorov, V.A.; Lech, P.; Zolciak, A.; Rusak, N.; Szczepaniak, L.,
Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack,
Trees, 2008, 22, 4, 531-542, https://doi.org/10.1007/s00468-008-0213-z
. [all data]
Butts and Rainey, 1971
Butts, W.C.; Rainey, W.T., Jr.,
Gas Chromatography and Mass Spectrometry of the Trimethylsilyl Derivatives of Inorganic Anions,
Anal. Chem., 1971, 43, 4, 538-542, https://doi.org/10.1021/ac60299a004
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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