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(Z)-5-(1-Methoxyethylidenebicyclo[2.2.1]hept-2-ene


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

(Z)-5-(1-Methoxyethylidenebicyclo[2.2.1]hept-2-ene = Bicyclo[2.2.1]hept-2-ene, 5-(1-methoxyethylidene)-, (E)-

By formula: C10H14O = C10H14O

Quantity Value Units Method Reference Comment
Deltar0.6 ± 0.3kJ/molEqkTaskinen, 1985liquid phase; solvent: Cyclohexane; GLC

Exo-5-(1-methoxyethenyl)bicyclo[2.2.1]hept-2-ene = (Z)-5-(1-Methoxyethylidenebicyclo[2.2.1]hept-2-ene

By formula: C10H14O = C10H14O

Quantity Value Units Method Reference Comment
Deltar6.1 ± 0.9kJ/molEqkTaskinen, 1985liquid phase; solvent: Cyclohexane; GLC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taskinen, 1985
Taskinen, E., Thermodynamics of vinyl ethers. XXX. On the ease of introduction of a C=C bond exocyclic to some bi- and tricyclic rings, Acta Chem. Scand., 1985, 39, 779-783. [all data]


Notes

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