Dimanganese decacarbonyl

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.32 ± 0.01EIMichels and Svec, 1981LLK
7.7PEHigginson, Lloyd, et al., 1975LLK
7.69 ± 0.01PEConnor, Zafarani-Moattar, et al., 1972LLK
8.46 ± 0.03EIJunk and Svec, 1970RDSH
8.4 ± 0.1EIBidinosti and McIntyre, 1970RDSH
8.55 ± 0.10EIWinters and Kiser, 1965RDSH
8.02PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.02PEEvans, Green, et al., 1969Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
MnCO+18.21?EISvec and Junk, 1967RDSH
MnCO+17.5 ± 0.2?EIWinters and Kiser, 1965RDSH
MnC2O2+14.80?EISvec and Junk, 1967RDSH
Mn2C2O2+16.438COEISvec and Junk, 1967RDSH
Mn2C3O3+15.347COEISvec and Junk, 1967RDSH
Mn2C4O4+13.986COEISvec and Junk, 1967RDSH
Mn2C4O4+14.0 ± 0.26COEIWinters and Kiser, 1965RDSH
MnC5O5+9.40?EISvec and Junk, 1967RDSH
MnC5O5+9.3 ± 0.1?EIBidinosti and McIntyre, 1966RDSH
Mn2C5O5+11.915COEISvec and Junk, 1967RDSH
Mn2C5O5+12.6 ± 0.25COEIWinters and Kiser, 1965RDSH
Mn+22.13?EISvec and Junk, 1967RDSH
Mn+20.8 ± 0.4?EIWinters and Kiser, 1965RDSH
Mn2+18.7310COEISvec and Junk, 1967RDSH
Mn2+18.8 ± 0.310COEIWinters and Kiser, 1965RDSH


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)10 and TcRe(CO)10, Inorg. Chem., 1981, 20, 3445. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Connor, Zafarani-Moattar, et al., 1972
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; ElSaied, N.I.; Suradi, S.; Carson, R.; AlTakhin, G.; Skinner, H.A., [Title unavailable], Organometallics, 1972, 1, 1166. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Bidinosti and McIntyre, 1970
Bidinosti, D.R.; McIntyre, N.S., Mass spectrometric study of the thermal decomposition of dimanganese decacarbonyl and dicobalt octacarbonyl, Can. J. Chem., 1970, 48, 593. [all data]

Winters and Kiser, 1965
Winters, R.E.; Kiser, R.W., Ions produced by electron impact with the dimetallic carbonyls of cobalt and manganese, J. Phys. Chem., 1965, 69, 1618. [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W., Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10, J. Am. Chem. Soc., 1967, 89, 2836. [all data]

Bidinosti and McIntyre, 1966
Bidinosti, D.R.; McIntyre, N.S., The metal-metal bond dissociation energy in manganese carbonyl, Chem. Commun., 1966, 555. [all data]


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