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Silicon tetrachloride

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Silicon tetrachloride = (Chlorine anion bullet Silicon tetrachloride)

By formula: Cl- + Cl4Si = (Cl- bullet Cl4Si)

QuantityValueUnitsMethodReferenceComment
Deltar105. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase
Deltar101. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase
QuantityValueUnitsMethodReferenceComment
Deltar73.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034. [doi:10.1021/jp040743x] [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]


Notes

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