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CN anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CN- + trifluoroarsine = (CN- bullet trifluoroarsine)

By formula: CN- + AsF3 = (CN- bullet AsF3)

Quantity Value Units Method Reference Comment
Deltar104. ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar69.5 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Carbonic difluoride = (CN- bullet Carbonic difluoride)

By formula: CN- + CF2O = (CN- bullet CF2O)

Quantity Value Units Method Reference Comment
Deltar98.3 ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar150.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar54.8 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Fluorodichloromethane = (CN- bullet Fluorodichloromethane)

By formula: CN- + CHCl2F = (CN- bullet CHCl2F)

Quantity Value Units Method Reference Comment
Deltar74. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar43.5 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Trichloromethane = (CN- bullet Trichloromethane)

By formula: CN- + CHCl3 = (CN- bullet CHCl3)

Quantity Value Units Method Reference Comment
Deltar76. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar45.2 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Fluoroform = (CN- bullet Fluoroform)

By formula: CN- + CHF3 = (CN- bullet CHF3)

Quantity Value Units Method Reference Comment
Deltar71. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar40. ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Hydrogen cyanide = (CN- bullet Hydrogen cyanide)

By formula: CN- + CHN = (CN- bullet CHN)

Quantity Value Units Method Reference Comment
Deltar91. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Deltar83.7 ± 8.4kJ/molEstLarson and McMahon, 1984gas phase; B
Deltar86.6kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar86.6kJ/molPHPMSMeot-ner, 1988gas phase; M,B,B,M
Quantity Value Units Method Reference Comment
Deltar86.2J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar86.2J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Deltar86.2J/mol*KPHPMSMeot-ner, 1988gas phase; M
Deltar113.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(H2O), Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar60.7 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar57.3 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Deltar60.7 ± 6.7kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- bullet Hydrogen cyanide) + Hydrogen cyanide = (CN- bullet 2Hydrogen cyanide)

By formula: (CN- bullet CHN) + CHN = (CN- bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar68.6kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar68.6kJ/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar91.2J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Deltar91.2J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar41.4kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- bullet 2Hydrogen cyanide) + Hydrogen cyanide = (CN- bullet 3Hydrogen cyanide)

By formula: (CN- bullet 2CHN) + CHN = (CN- bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar52.7kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar52.7kJ/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar88.7J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Deltar88.7J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.4kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- bullet 3Hydrogen cyanide) + Hydrogen cyanide = (CN- bullet 4Hydrogen cyanide)

By formula: (CN- bullet 3CHN) + CHN = (CN- bullet 4CHN)

Quantity Value Units Method Reference Comment
Deltar45.6kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar45.6kJ/molPHPMSMeot-ner, 1988gas phase; M,B,M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar104.J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Deltar104.J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar14.6kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- bullet 4Hydrogen cyanide) + Hydrogen cyanide = (CN- bullet 5Hydrogen cyanide)

By formula: (CN- bullet 4CHN) + CHN = (CN- bullet 5CHN)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Deltar41.kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar84.5J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar15.9kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- bullet 5Hydrogen cyanide) + Hydrogen cyanide = (CN- bullet 6Hydrogen cyanide)

By formula: (CN- bullet 5CHN) + CHN = (CN- bullet 6CHN)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.0kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(CN- bullet 6Hydrogen cyanide) + Hydrogen cyanide = (CN- bullet 7Hydrogen cyanide)

By formula: (CN- bullet 6CHN) + CHN = (CN- bullet 7CHN)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar6.69kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.238.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

(CN- bullet Hydrogen cyanide) + Water = (CN- bullet Water bullet Hydrogen cyanide)

By formula: (CN- bullet CHN) + H2O = (CN- bullet H2O bullet CHN)

Quantity Value Units Method Reference Comment
Deltar51.9 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar27. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet 2Hydrogen cyanide) + Water = (CN- bullet Water bullet 2Hydrogen cyanide)

By formula: (CN- bullet 2CHN) + H2O = (CN- bullet H2O bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar52.3J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar17. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet 3Hydrogen cyanide) + Water = (CN- bullet Water bullet 3Hydrogen cyanide)

By formula: (CN- bullet 3CHN) + H2O = (CN- bullet H2O bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar39. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar14. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- bullet Hydrogen cyanide bullet Water) + Hydrogen cyanide = (CN- bullet 2Hydrogen cyanide bullet Water)

By formula: (CN- bullet CHN bullet H2O) + CHN = (CN- bullet 2CHN bullet H2O)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar74.5J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- bullet Hydrogen cyanide bullet 2Water) + Hydrogen cyanide = (CN- bullet 2Hydrogen cyanide bullet 2Water)

By formula: (CN- bullet CHN bullet 2H2O) + CHN = (CN- bullet 2CHN bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar52.7kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- bullet 2Hydrogen cyanide bullet Water) + Hydrogen cyanide = (CN- bullet 3Hydrogen cyanide bullet Water)

By formula: (CN- bullet 2CHN bullet H2O) + CHN = (CN- bullet 3CHN bullet H2O)

Quantity Value Units Method Reference Comment
Deltar51.5kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CN- + Methylene chloride = (CN- bullet Methylene chloride)

By formula: CN- + CH2Cl2 = (CN- bullet CH2Cl2)

Quantity Value Units Method Reference Comment
Deltar68. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar38. ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Chloromethane = (CN- bullet Chloromethane)

By formula: CN- + CH3Cl = (CN- bullet CH3Cl)

Quantity Value Units Method Reference Comment
Deltar42.7 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar20.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

CN- + Silane, trifluoromethyl- = (CN- bullet Silane, trifluoromethyl-)

By formula: CN- + CH3F3Si = (CN- bullet CH3F3Si)

Quantity Value Units Method Reference Comment
Deltar94.6 ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar57.3 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Methyl Alcohol = (CN- bullet Methyl Alcohol)

By formula: CN- + CH4O = (CN- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar65.7 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar69.5 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar69. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar102.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar36.8 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar43.5 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar38. ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Carbon dioxide = (CN- bullet Carbon dioxide)

By formula: CN- + CO2 = (CN- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar72.4 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar132.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar33.1 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B

CN- + C2F4O = (CN- bullet C2F4O)

By formula: CN- + C2F4O = (CN- bullet C2F4O)

Quantity Value Units Method Reference Comment
Deltar150.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Deltar150.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M

CN- + Pentafluorodimethyl ether = (CN- bullet Pentafluorodimethyl ether)

By formula: CN- + C2HF5O = (CN- bullet C2HF5O)

Quantity Value Units Method Reference Comment
Deltar78. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar47.3 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + 1,1,1',1'-Tetrafluorodimethyl ether = (CN- bullet 1,1,1',1'-Tetrafluorodimethyl ether)

By formula: CN- + C2H2F4O = (CN- bullet C2H2F4O)

Quantity Value Units Method Reference Comment
Deltar92. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar63.2 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Ethanol, 2,2,2-trifluoro- = (CN- bullet Ethanol, 2,2,2-trifluoro-)

By formula: CN- + C2H3F3O = (CN- bullet C2H3F3O)

Quantity Value Units Method Reference Comment
Deltar100.4 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar103. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar109.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar63.18 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar68.6 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + 1,1,2-Trifluoroethane = (CN- bullet 1,1,2-Trifluoroethane)

By formula: CN- + C2H3F3 = (CN- bullet C2H3F3)

Quantity Value Units Method Reference Comment
Deltar77.0kJ/molICRLarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar46.0kJ/molICRLarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M

CN- + Acetonitrile = (CN- bullet Acetonitrile)

By formula: CN- + C2H3N = (CN- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar57.7 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Deltar69. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Deltar65.69kJ/molTDAsHiraoka, Mizure, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka, Mizure, et al., 1988gas phase; M
Deltar59.4J/mol*KPHPMSMeot-ner, 1988gas phase; M
Deltar102.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar40. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar38. ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Deltar38.5kJ/molTDAsHiraoka, Mizure, et al., 1988gas phase; B

CN- + 2-Chloroethanol = (CN- bullet 2-Chloroethanol)

By formula: CN- + C2H5ClO = (CN- bullet C2H5ClO)

Quantity Value Units Method Reference Comment
Deltar88. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar56.5 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Ethanol, 2-fluoro- = (CN- bullet Ethanol, 2-fluoro-)

By formula: CN- + C2H5FO = (CN- bullet C2H5FO)

Quantity Value Units Method Reference Comment
Deltar85. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar54.0 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Silane, difluorodimethyl- = (CN- bullet Silane, difluorodimethyl-)

By formula: CN- + C2H6F2Si = (CN- bullet C2H6F2Si)

Quantity Value Units Method Reference Comment
Deltar70.3 ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M

CN- + Ethanol = (CN- bullet Ethanol)

By formula: CN- + C2H6O = (CN- bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar72.8 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Deltar73. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KPHPMSMeot-ner, 1988gas phase; M
Deltar103.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar44.8 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar41.8 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + C3F6O = (CN- bullet C3F6O)

By formula: CN- + C3F6O = (CN- bullet C3F6O)

Quantity Value Units Method Reference Comment
Deltar115. ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar72.0 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B

CN- + 2-Propanone, 1,1,1,3,3-pentafluoro- = (CN- bullet 2-Propanone, 1,1,1,3,3-pentafluoro-)

By formula: CN- + C3HF5O = (CN- bullet C3HF5O)

Quantity Value Units Method Reference Comment
Deltar108. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar74.9 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + 2-Propanol, 1,1,1,3,3,3-hexafluoro- = (CN- bullet 2-Propanol, 1,1,1,3,3,3-hexafluoro-)

By formula: CN- + C3H2F6O = (CN- bullet C3H2F6O)

Quantity Value Units Method Reference Comment
Deltar105. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar70.3 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + 2-Propanone, 1,1,1-trifluoro- = (CN- bullet 2-Propanone, 1,1,1-trifluoro-)

By formula: CN- + C3H3F3O = (CN- bullet C3H3F3O)

Quantity Value Units Method Reference Comment
Deltar85. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar54.0 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + 1,3-Difluoro-2-propanol = (CN- bullet 1,3-Difluoro-2-propanol)

By formula: CN- + C3H6F2O = (CN- bullet C3H6F2O)

Quantity Value Units Method Reference Comment
Deltar98.3kJ/molICRLarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar66.1kJ/molICRLarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M

CN- + Acetone = (CN- bullet Acetone)

By formula: CN- + C3H6O = (CN- bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar62. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar33. ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Isopropyl Alcohol = (CN- bullet Isopropyl Alcohol)

By formula: CN- + C3H8O = (CN- bullet C3H8O)

Quantity Value Units Method Reference Comment
Deltar69.9 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar76. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar104.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar37.7 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar44.8 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Boric acid, trimethyl ester = (CN- bullet Boric acid, trimethyl ester)

By formula: CN- + C3H9BO3 = (CN- bullet C3H9BO3)

Quantity Value Units Method Reference Comment
Deltar82.0 ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar150.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar44.8 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + C4H4F6O = (CN- bullet C4H4F6O)

By formula: CN- + C4H4F6O = (CN- bullet C4H4F6O)

Quantity Value Units Method Reference Comment
Deltar108. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Deltar110.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar74.5 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M,M

CN- + Carbonocyanidic acid, ethyl ester = (CN- bullet Carbonocyanidic acid, ethyl ester)

By formula: CN- + C4H5NO2 = (CN- bullet C4H5NO2)

Quantity Value Units Method Reference Comment
Deltar73. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar41.8 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Pyrrole = (CN- bullet Pyrrole)

By formula: CN- + C4H5N = (CN- bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar97.9 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Deltar82. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSMeot-ner, 1988gas phase; M
Deltar99.6J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar64.0 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar51.5 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Propane, 2-chloro-2-methyl- = (CN- bullet Propane, 2-chloro-2-methyl-)

By formula: CN- + C4H9Cl = (CN- bullet C4H9Cl)

Quantity Value Units Method Reference Comment
Deltar66.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Deltar31.6 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

CN- + 2-Propanol, 2-methyl- = (CN- bullet 2-Propanol, 2-methyl-)

By formula: CN- + C4H10O = (CN- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar76. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar44.8 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + L-Alanine, N-acetyl-, methyl ester = (CN- bullet L-Alanine, N-acetyl-, methyl ester)

By formula: CN- + C6H11NO3 = (CN- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar110.kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSMeot-ner, 1988gas phase; M

CN- + CH3CONHCH(CH3)COOCH3 = (CN- bullet CH3CONHCH(CH3)COOCH3)

By formula: CN- + C6H11NO3 = (CN- bullet C6H11NO3)

Quantity Value Units Method Reference Comment
Deltar110. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar74.5 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

CN- + Borane, triethyl- = (CN- bullet Borane, triethyl-)

By formula: CN- + C6H15B = (CN- bullet C6H15B)

Quantity Value Units Method Reference Comment
Deltar150.2 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar115.5 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B

CN- + Thionyl fluoride = (CN- bullet Thionyl fluoride)

By formula: CN- + F2OS = (CN- bullet F2OS)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar28.9 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Phosphoryl fluoride = (CN- bullet Phosphoryl fluoride)

By formula: CN- + F3OP = (CN- bullet F3OP)

Quantity Value Units Method Reference Comment
Deltar98.3 ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar61.1 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Phosphorus trifluoride = (CN- bullet Phosphorus trifluoride)

By formula: CN- + F3P = (CN- bullet F3P)

Quantity Value Units Method Reference Comment
Deltar64.0 ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar26.8 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Sulfur tetrafluoride = (CN- bullet Sulfur tetrafluoride)

By formula: CN- + F4S = (CN- bullet F4S)

Quantity Value Units Method Reference Comment
Deltar108. ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar70.7 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Silicon tetrafluoride = (CN- bullet Silicon tetrafluoride)

By formula: CN- + F4Si = (CN- bullet F4Si)

Quantity Value Units Method Reference Comment
Deltar114. ± 4.2kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KN/ALarson, Szulejko, et al., 1988gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar76.6 ± 2.1kJ/molIMRELarson, Szulejko, et al., 1988gas phase; B,M

CN- + Water = (CN- bullet Water)

By formula: CN- + H2O = (CN- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar53.1 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar61.1 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,B,M,M
Deltar57.74kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Deltar61.1kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar75.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar82.0J/mol*KPHPMSMeot-ner, 1988gas phase; M
Deltar82.0J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Deltar82.8J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.5 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar36. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar36. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B
Deltar33.1kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

(CN- bullet 3Water) + Hydrogen cyanide = (CN- bullet Hydrogen cyanide bullet 3Water)

By formula: (CN- bullet 3H2O) + CHN = (CN- bullet CHN bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
33.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- bullet Water bullet Hydrogen cyanide) + Water = (CN- bullet 2Water bullet Hydrogen cyanide)

By formula: (CN- bullet H2O bullet CHN) + H2O = (CN- bullet 2H2O bullet CHN)

Quantity Value Units Method Reference Comment
Deltar40. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar73.2J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar18. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet Water bullet 2Hydrogen cyanide) + Water = (CN- bullet 2Water bullet 2Hydrogen cyanide)

By formula: (CN- bullet H2O bullet 2CHN) + H2O = (CN- bullet 2H2O bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar12. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- bullet 2Water bullet Hydrogen cyanide) + Water = (CN- bullet 3Water bullet Hydrogen cyanide)

By formula: (CN- bullet 2H2O bullet CHN) + H2O = (CN- bullet 3H2O bullet CHN)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
Deltar10. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

(CN- bullet Water) + Water = (CN- bullet 2Water)

By formula: (CN- bullet H2O) + H2O = (CN- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar49.0 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Deltar49.0kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar75.7J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar75.7J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar26. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet 2Water) + Water = (CN- bullet 3Water)

By formula: (CN- bullet 2H2O) + H2O = (CN- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar44.8 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B,M
Deltar44.8kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.8J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar82.8J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar33. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B

(CN- bullet 3Water) + Water = (CN- bullet 4Water)

By formula: (CN- bullet 3H2O) + H2O = (CN- bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M

CN- + Hydrogen sulfide = (CN- bullet Hydrogen sulfide)

By formula: CN- + H2S = (CN- bullet H2S)

Quantity Value Units Method Reference Comment
Deltar79.1 ± 4.2kJ/molTDEqMeot-ner, 1988gas phase; B
Deltar83. ± 15.kJ/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
Deltar54.0 ± 4.2kJ/molTDEqMeot-ner, 1988gas phase; B
Deltar51.9 ± 9.6kJ/molIMRELarson and McMahon, 1987gas phase; B,M

CN- + Borane = (CN- bullet Borane)

By formula: CN- + H3B = (CN- bullet H3B)

Quantity Value Units Method Reference Comment
Deltar256. ± 8.8kJ/molEndoWorkman and Squires, 1988gas phase; B

CN- + Sulfur dioxide = (CN- bullet Sulfur dioxide)

By formula: CN- + O2S = (CN- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar90.8 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar56.07 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Larson, Szulejko, et al., 1988
Larson, J.W.; Szulejko, J.E.; McMahon, T.B., Gas Phase Lewis Acid-Base Interactions. An Experimental Determination of Cyanide Binding Energies From Ion Cyclotron Resonance and High-Pressure Mass Spectrometric Equilibrium Measurements., J. Am. Chem. Soc., 1988, 110, 23, 7604, https://doi.org/10.1021/ja00231a004 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. The energetics of interaction between cyanide ion and bronsted acids, J. Am. Chem. Soc., 1987, 109, 6230. [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Gas phase bihalide and pseudohalide ions. An ICR determination of hydrogen bond energies in XHY- species (X,Y = F, Cl, Br, CN), Inorg. Chem., 1984, 23, 2029. [all data]

Meot-Ner (Mautner) and Speller, 1989
Meot-Ner (Mautner), M.; Speller, C.V., Multicomponent Cluster Ions.3. Comparative Stabilities of Cationic and Anionic Hydrogen Bonded Networks. Mixed Clusters of Water and Hydrogen Cyanide, J. Phys. Chem., 1989, 93, 6580. [all data]

Meot-ner, 1988
Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

Meot-ner, Cybulski, et al., 1988
Meot-ner, M.; Cybulski, S.M.; Scheiner, S.; Liebman, J.F., Is CN- Significantly Anisotropic? Comparison of CN- vs. Cl-: Clustering with HCN and Condensed Phase Thermochemistry, J. Phys. Chem., 1988, 92, 10, 2738, https://doi.org/10.1021/j100321a009 . [all data]

Meot-Ner (Mautner) M. and Speller, 1989
Meot-Ner (Mautner) M.; Speller, C.V., Multicomponent Cluster Ions. 2. Comparative Stabilities of Cationic and Anionic Hydrogen Bonded Networks. Mixed Clusters of Water and Hydrogen Cyanide, J. Phys. Chem., 1989, 93, 9, 3663, https://doi.org/10.1021/j100346a058 . [all data]

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o . [all data]

Hiraoka, Mizure, et al., 1988
Hiraoka, K.; Mizure, S.; Yamabe, S.; Nakatsuji, Y., Gas Phase Clustering Reactions of CN- and CH2CN- with MeCN, Chem. Phys. Lett., 1988, 148, 6, 497, https://doi.org/10.1016/0009-2614(88)80320-8 . [all data]

Meot-ner, 1988, 2
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]

Workman and Squires, 1988
Workman, D.B.; Squires, R.R., Hydride Binding Energies of Boranes, Inorg. Chem., 1988, 27, 11, 1846, https://doi.org/10.1021/ic00284a003 . [all data]


Notes

Go To: Top, Ion clustering data, References