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(CF3)2CHO anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C3HF6O- + Hydrogen cation = 2-Propanol, 1,1,1,3,3,3-hexafluoro-

By formula: C3HF6O- + H+ = C3H2F6O

Quantity Value Units Method Reference Comment
Deltar1443. ± 8.8kJ/molG+TSTaft, Koppel, et al., 1990gas phase
Quantity Value Units Method Reference Comment
Deltar1416. ± 8.4kJ/molIMRETaft, Koppel, et al., 1990gas phase
Deltar1424.2kJ/molIMRBKoppel, Pikver, et al., 1981gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft, Koppel, et al., 1990
Taft, R.W.; Koppel, I.J.; Topsom, R.D.; Anvia, F., Acidities of OH Compounds, including Alcohols, Phenols, Carboxylic Acids, and Mineral Acids, J. Am. Chem. Soc., 1990, 112, 6, 2047, https://doi.org/10.1021/ja00162a001 . [all data]

Koppel, Pikver, et al., 1981
Koppel, I.; Pikver, R.; Sugis, A.; Suurmaa, E.; Lippmaa, E., FTICR Study of Structure and Solvent Effects on Basicity of Some Anions in the Gas Phase, Org. Reac., 1981, 18, 3. [all data]


Notes

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