PhSiMe2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C8H11Si- + Hydrogen cation = Silane, dimethylphenyl-

By formula: C8H11Si- + H+ = C8H12Si

Quantity Value Units Method Reference Comment
Δr1582. ± 9.2kJ/molG+TSIrie, Kikukawa, et al., 2001gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB
Quantity Value Units Method Reference Comment
Δr1550. ± 8.4kJ/molIMREIrie, Kikukawa, et al., 2001gas phase; The anion may be ArSiH(Me)CH2-, based on LFER size and ab initio calculations - JEB

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Irie, Kikukawa, et al., 2001
Irie, M.; Kikukawa, K.; Shimizu, N.; Mishima, M., Gas-phase acidities of aryldimethylsilanes, J. Chem. Soc. Perkin Trans., 2001, 2, 6, 923-928, https://doi.org/10.1039/b100488n . [all data]


Notes

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