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HO anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

HO- = CHO2-

By formula: HO- = CHO2-

Quantity Value Units Method Reference Comment
Deltar76.3 ± 2.5kJ/molN/AJohnson, Harding, et al., 2011gas phase; trans isomer. See Wang, Li, et al., 2014 for computational analysis

HO- = HN2O2-

By formula: HO- = HN2O2-

Quantity Value Units Method Reference Comment
Deltar35.6kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.189 eV. Affinity is EA difference with next lower +0.08 eV f

HO- + Carbon dioxide = (HO- bullet Carbon dioxide)

By formula: HO- + CO2 = (HO- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar213. ± 10.kJ/molCIDTSquires, 1992gas phase; Dissociative protonation threshold at nPrSH, 9 kcal> calc. CIDC(HOCO2-..HSH) = 7:1 HOCO2-
Deltar366.5kJ/molEndoHierl and Paulson, 1984gas phase; Implies «DELTA»Hacid = 291.4, anion appears too stable - JEB

HO- + Iron pentacarbonyl = (HO- bullet Iron pentacarbonyl)

By formula: HO- + C5FeO5 = (HO- bullet C5FeO5)

Quantity Value Units Method Reference Comment
Deltar254. ± 14.kJ/molIMRESunderlin and Squires, 1993gas phase; HO- transfer equilibrium to SO2. Structure thought ot be (CO)4Fe-CO2H
Deltar237. ± 17.kJ/molIMRBLane, Sallans, et al., 1985gas phase
Quantity Value Units Method Reference Comment
Deltar196. ± 17.kJ/molIMRBLane, Sallans, et al., 1985gas phase

HO- + Water = (HO- bullet Water)

By formula: HO- + H2O = (HO- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar120. ± 30.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar80.3 ± 4.2kJ/molTDAsPaul and Kebarle, 1990gas phase
Deltar84.1 ± 6.7kJ/molTDEqMeot-Ner and Sieck, 1986gas phase
Deltar83.7 ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase
Deltar77.82kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase

(HO- bullet Water) + Water = (HO- bullet 2Water)

By formula: (HO- bullet H2O) + H2O = (HO- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar73.6 ± 4.2kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase
Deltar74.9 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase
Quantity Value Units Method Reference Comment
Deltar46.9 ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase
Deltar48.53kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase

(HO- bullet 2Water) + Water = (HO- bullet 3Water)

By formula: (HO- bullet 2H2O) + H2O = (HO- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar63.2 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase
Deltar67.8 ± 4.2kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar38. ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase

(HO- bullet 3Water) + Water = (HO- bullet 4Water)

By formula: (HO- bullet 3H2O) + H2O = (HO- bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar50.21kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar24. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase

(HO- bullet 4Water) + Water = (HO- bullet 5Water)

By formula: (HO- bullet 4H2O) + H2O = (HO- bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar48.12kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar18. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase

(HO- bullet 5Water) + Water = (HO- bullet 6Water)

By formula: (HO- bullet 5H2O) + H2O = (HO- bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar46.86kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar18. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase

(HO- bullet 6Water) + Water = (HO- bullet 7Water)

By formula: (HO- bullet 6H2O) + H2O = (HO- bullet 7H2O)

Quantity Value Units Method Reference Comment
Deltar43.51kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase
Quantity Value Units Method Reference Comment
Deltar13. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase

(HO- bullet 7Water) + Water = (HO- bullet 8Water)

By formula: (HO- bullet 7H2O) + H2O = (HO- bullet 8H2O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; Entropy estimated
Quantity Value Units Method Reference Comment
Deltar11. ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; Entropy estimated

HO- + Ammonia = H4NO-

By formula: HO- + H3N = H4NO-

Quantity Value Units Method Reference Comment
Deltar50.21kJ/molN/ASchwartz, Davico, et al., 2000gas phase; Vertical Detachment Energy: 2.54±0.015 eV. Affinity is from difference in EAs

(HO- bullet Nitrous oxide) + Nitrous oxide = (HO- bullet 2Nitrous oxide)

By formula: (HO- bullet N2O) + N2O = (HO- bullet 2N2O)

Quantity Value Units Method Reference Comment
Deltar32.6kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.485 eV. Affinity is EA difference with next lower +0.08 eV f

(HO- bullet 2Nitrous oxide) + Nitrous oxide = (HO- bullet 3Nitrous oxide)

By formula: (HO- bullet 2N2O) + N2O = (HO- bullet 3N2O)

Quantity Value Units Method Reference Comment
Deltar28.9kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.761 eV. Affinity is EA difference with next lower +0.08 eV f

(HO- bullet 3Nitrous oxide) + Nitrous oxide = (HO- bullet 4Nitrous oxide)

By formula: (HO- bullet 3N2O) + N2O = (HO- bullet 4N2O)

Quantity Value Units Method Reference Comment
Deltar>30. ± 140.kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 2.981 eV. Affinity is EA difference with next lower +0.08 eV f

(HO- bullet 4Nitrous oxide) + Nitrous oxide = (HO- bullet 5Nitrous oxide)

By formula: (HO- bullet 4N2O) + N2O = (HO- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar>20. ± 230.kJ/molN/AKim, Wenthold, et al., 1998gas phase; Vertical Detachment Energy: 3.146 eV. Affinity is EA difference with next lower +0.08 eV f

HO- + Sulfur dioxide = (HO- bullet Sulfur dioxide)

By formula: HO- + O2S = (HO- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar259. ± 12.kJ/molCIDTSquires, 1992gas phase; Dissociative protonation between HCl, MeCHClCO2H
Deltar>213. ± 13.kJ/molIMRBHierl and Paulson, 1984gas phase; CO2..HO- + SO2 ->. data revised per 92SQU

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Johnson, Harding, et al., 2011
Johnson, C.J.; Harding, M.E.; Poad, B.L.J.; Stanton, J.F.; Continetti, R.E., Electron Affinities, Well Depths, and Vibrational Spectroscopy of cis- and trans-HOCO, J. Am. Chem. Soc., 2011, 133, 49, 19606-19609, https://doi.org/10.1021/ja207724f . [all data]

Wang, Li, et al., 2014
Wang, J.; Li, J.; Ma, J.Y.; Guo, H., Full-dimensional characterization of photoelectron spectra of HOCO- and DOCO- and tunneling facilitated decay of HOCO prepared by anion photodetachment, Journal Of Chemical Physics, 2014, 140, 18, 184314, https://doi.org/10.1063/1.4874975 . [all data]

Kim, Wenthold, et al., 1998
Kim, J.B.; Wenthold, P.G.; Lineberger, W.C., Photoelectron spectroscopy of OH-(N2O)(n=1-5), J. Chem. Phys., 1998, 108, 3, 830-837, https://doi.org/10.1063/1.475447 . [all data]

Squires, 1992
Squires, R.R., Gas Phase Thermochemical Properties of the Bicarbonate and Bisulfate Ions, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 565, https://doi.org/10.1016/0168-1176(92)80114-G . [all data]

Hierl and Paulson, 1984
Hierl, P.M.; Paulson, J.F., Translational energy dependence of cross sections for reactions of OH- (H2O)n with CO2 and SO2, J. Chem. Phys., 1984, 80, 4890. [all data]

Sunderlin and Squires, 1993
Sunderlin, L.S.; Squires, R.R., Energetics and Mechanism of the Thermal Decarboxylation of (CO)4FeCOOH- in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 1, 337, https://doi.org/10.1021/ja00054a048 . [all data]

Lane, Sallans, et al., 1985
Lane, K.R.; Sallans, L.; Squires, R.R., Anion affinities of transition metal carbonyls. A thermochemical correlation for iron tetracarbonyl acyl negative ions, J. Am. Chem. Soc., 1985, 107, 5369. [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Thermodynamics of the Association Reactions OH- - H2O = HOHOH- and CH3O- - CH3OH = CH3OHOCH3- in the Gas Phase, J. Phys. Chem., 1990, 94, 12, 5184, https://doi.org/10.1021/j100375a076 . [all data]

Meot-Ner and Sieck, 1986
Meot-Ner, M.; Sieck, L.W., The ionic hydrogen bond and ion solvation. 5. OH...O- bonds. Gas phase solvation and clustering of alkoxide and carboxylate anions, J. Am. Chem. Soc., 1986, 108, 7525. [all data]

Meot-Ner (Mautner) and Speller, 1986
Meot-Ner (Mautner), M.; Speller, C.V., The Filling of Solvent Shells in Cluster Ions: Thermochemical Criteria nd the Effects of Isomeric Clusters, J. Phys. Chem., 1986, 90, 25, 6616, https://doi.org/10.1021/j100283a006 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Schwartz, Davico, et al., 2000
Schwartz, R.L.; Davico, G.E.; Kim, J.B.; Lineberger, C.W., Negative Ion Photoelectron Spectroscopy of OH-(NH3), J. Chem. Phys., 2000, 112, 11, 4966, https://doi.org/10.1063/1.481051 . [all data]


Notes

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