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Reaction data

HO- + Water = (HO- bullet Water)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

DeltarH° (kJ/mol) Method Reference Comment
112. ± 4.2TDAsPaul and Kebarle, 1990gas phase; B
108.4TherGolub and Steiner, 1968gas phase; For a complete Fragment KE/LPES analysis, see Deyerl, Luong, et al., 2000; B
112. ± 4.2TDEqMeot-Ner and Sieck, 1986gas phase; B
111. ± 4.2N/AMeot-Ner (Mautner) and Speller, 1986gas phase; B
100.4TDAsPayzant, Yamdagni, et al., 1971gas phase; B
149. ± 29.CIDTDe Paz, Giardini, et al., 1970gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Thermodynamics of the Association Reactions OH- - H2O = HOHOH- and CH3O- - CH3OH = CH3OHOCH3- in the Gas Phase, J. Phys. Chem., 1990, 94, 12, 5184, https://doi.org/10.1021/j100375a076 . [all data]

Golub and Steiner, 1968
Golub, S.; Steiner, B., Photodetachment of {OH(H2O)}-, J. Chem. Phys., 1968, 49, 11, 5191, https://doi.org/10.1063/1.1670021 . [all data]

Deyerl, Luong, et al., 2000
Deyerl, H.J.; Luong, A.K.; Clements, T.G.; Continetti, R.E., Transition state dynamics of the OH+H2O hydrogen exchange reaction studied by dissociative photodetachment of H3O2-, Faraday Disc. Chem. Soc., 2000, 115, 147-160, https://doi.org/10.1039/a909619a . [all data]

Meot-Ner and Sieck, 1986
Meot-Ner, M.; Sieck, L.W., The ionic hydrogen bond and ion solvation. 5. OH...O- bonds. Gas phase solvation and clustering of alkoxide and carboxylate anions, J. Am. Chem. Soc., 1986, 108, 7525. [all data]

Meot-Ner (Mautner) and Speller, 1986
Meot-Ner (Mautner), M.; Speller, C.V., The Filling of Solvent Shells in Cluster Ions: Thermochemical Criteria nd the Effects of Isomeric Clusters, J. Phys. Chem., 1986, 90, 25, 6616, https://doi.org/10.1021/j100283a006 . [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

De Paz, Giardini, et al., 1970
De Paz, M.; Giardini, A.G.; Friedman, L., Tandem-Mass Spectrometer Study of Solvated Derivatives of OD-. Total Hydration Energy of the Proton, J. Chem. Phys., 1970, 52, 2, 687, https://doi.org/10.1063/1.1673041 . [all data]


Notes

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