Biphenylene, protonated


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C12H9+ + Naphthalene = (C12H9+ • Naphthalene)

By formula: C12H9+ + C10H8 = (C12H9+ • C10H8)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr58.2kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr27.kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

C12H9+ + Biphenylene = (C12H9+ • Biphenylene)

By formula: C12H9+ + C12H8 = (C12H9+ • C12H8)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Δr120.J/mol*KPHPMSMeot-Ner (Mautner), 1980gas phase

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.277.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1980
Meot-Ner (Mautner), M., Dimer Cations of Polycyclic Aromatics: Experimental Bonding Energies and Resonance Stabilization, J. Phys. Chem., 1980, 84, 21, 2724, https://doi.org/10.1021/j100458a012 . [all data]


Notes

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