Biphenylene, positive ion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C12H8+ + Acenaphthene = (C12H8+ • Acenaphthene)

By formula: C12H8+ + C12H10 = (C12H8+ • C12H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr14.2kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.3283.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

C12H8+ + Fluorene = (C12H8+ • Fluorene)

By formula: C12H8+ + C13H10 = (C12H8+ • C13H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr13.3kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.4283.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

C12H8+ + Biphenyl = (C12H8+ • Biphenyl)

By formula: C12H8+ + C12H10 = (C12H8+ • C12H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr13.4kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.5279.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

C12H8+ + Naphthalene = (C12H8+ • Naphthalene)

By formula: C12H8+ + C10H8 = (C12H8+ • C10H8)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr12.6kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr28.cal/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr5.1kcal/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1980
Meot-Ner (Mautner), M., Dimer Cations of Polycyclic Aromatics: Experimental Bonding Energies and Resonance Stabilization, J. Phys. Chem., 1980, 84, 21, 2724, https://doi.org/10.1021/j100458a012 . [all data]


Notes

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