ClFCH anion
- Formula: CHClF-
- Molecular weight: 67.471
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
CHClF- + =
By formula: CHClF- + H+ = CH2ClF
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 385.94 ± 0.95 | kcal/mol | G+TS | Poutsma, Paulino, et al., 1997 | gas phase; Relative to MeOH at ΔGacid=375.1 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 376.70 ± 0.30 | kcal/mol | IMRE | Poutsma, Paulino, et al., 1997 | gas phase; Relative to MeOH at ΔGacid=375.1 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Poutsma, Paulino, et al., 1997
Poutsma, J.C.; Paulino, J.A.; Squires, R.R.,
Absolute Heats of Formation of CHCl, CHF, and CClF. A Gas-Phase Experimental and G2 Theoretical Study.,
J. Phys. Chem. A, 1997, 101, 29, 5327, https://doi.org/10.1021/jp970778f
. [all data]
Notes
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- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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