2-CHO-1-cyclopropanide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C4H5O- + Hydrogen cation = Cyclopropanecarboxaldehyde

By formula: C4H5O- + H+ = C4H6O

Quantity Value Units Method Reference Comment
Δr1631. ± 21.kJ/molG+TSBaschky, Peterson, et al., 1994gas phase; Between D2O and PhF. Cis and Trans anions do not interconvert and have same expt. acidity.
Quantity Value Units Method Reference Comment
Δr1598. ± 21.kJ/molIMRBBaschky, Peterson, et al., 1994gas phase; Between D2O and PhF. Cis and Trans anions do not interconvert and have same expt. acidity.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baschky, Peterson, et al., 1994
Baschky, M.C.; Peterson, K.C.; Kass, S.R., Stereospecificity in the gas phase. Formation and characterization of configurationally stable cyclopropyl anions, J. Am. Chem. Soc., 1994, 116, 16, 7218, https://doi.org/10.1021/ja00095a026 . [all data]


Notes

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