H3SiCH2 anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH5Si- + Hydrogen cation = Silane, methyl-

By formula: CH5Si- + H+ = CH6Si

Quantity Value Units Method Reference Comment
Δr1625. ± 17.kJ/molG+TSDamrauer, Kass, et al., 1988gas phase; Slightly less acidic then fluorobenzene
Quantity Value Units Method Reference Comment
Δr1590. ± 17.kJ/molIMRBDamrauer, Kass, et al., 1988gas phase; Slightly less acidic then fluorobenzene

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Damrauer, Kass, et al., 1988
Damrauer, R.; Kass, S.R.; DePuy, C.H., Gas-Phase Acidities of Methylsilanes: C-H versus Si-H, Organomet., 1988, 7, 3, 637, https://doi.org/10.1021/om00093a011 . [all data]


Notes

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