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W(CO)3(PCy3)2(H2)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C39H68O3P2W (solution) + Water (solution) = C39H68O4P2W (solution) + Hydrogen (g)

By formula: C39H68O3P2W (solution) + H2O (solution) = C39H68O4P2W (solution) + H2 (g)

Quantity Value Units Method Reference Comment
Deltar-11.7 ± 0.4kJ/molEqSKubas, Burns, et al., 1992solvent: Tetrahydrofuran; Temperature range: 203-298 K

C39H66N2O3P2W (solution) + Hydrogen (g) = C39H68O3P2W (solution) + Nitrogen (g)

By formula: C39H66N2O3P2W (solution) + H2 (g) = C39H68O3P2W (solution) + N2 (g)

Quantity Value Units Method Reference Comment
Deltar18.4 ± 1.7kJ/molEqSGonzalez and Hoff, 1989solvent: Tetrahydrofuran; Temperature range: 288-308 K

C39H68O3P2W (solution) + 1,3-Diazine (solution) = C44H71NO3P2W (solution) + Hydrogen (g)

By formula: C39H68O3P2W (solution) + C4H4N2 (solution) = C44H71NO3P2W (solution) + H2 (g)

Quantity Value Units Method Reference Comment
Deltar-39.7 ± 2.1kJ/molRSCGonzalez, Zhang, et al., 1988solvent: Toluene
Deltar-41.8 ± 2.1kJ/molRSCGonzalez, Zhang, et al., 1988solvent: Tetrahydrofuran

C39H68O3P2W (solution) + Carbon monoxide (solution) = C40H66O4P2W (solution) + Hydrogen (g)

By formula: C39H68O3P2W (solution) + CO (solution) = C40H66O4P2W (solution) + H2 (g)

Quantity Value Units Method Reference Comment
Deltar-85.8 ± 2.9kJ/molRSCGonzalez, Zhang, et al., 1988solvent: Toluene
Deltar-95.4 ± 4.2kJ/molRSCGonzalez, Zhang, et al., 1988solvent: Tetrahydrofuran

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kubas, Burns, et al., 1992
Kubas, G.J.; Burns, C.J.; Khalsa, G.R.K.; van der Sluys, L.S.; Kiss, G.; Hoff, C.D., Organometallics, 1992, 11, 3390. [all data]

Gonzalez and Hoff, 1989
Gonzalez, A.A.; Hoff, C.D., Inorg. Chem., 1989, 28, 4295. [all data]

Gonzalez, Zhang, et al., 1988
Gonzalez, A.A.; Zhang, K.; Nolan, S.P.; Lopez de la Vega, R.; Mukerjee, S.L.; Hoff, C.D., Organometallics, 1988, 7, 2429. [all data]


Notes

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