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Mo(Cp)(CO)3(I)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C15H12MoO3 (solution) + Iodine (solution) = C8H5IMoO3 (solution) + Benzene, (iodomethyl)- (solution)

By formula: C15H12MoO3 (solution) + I2 (solution) = C8H5IMoO3 (solution) + C7H7I (solution)

Quantity Value Units Method Reference Comment
Deltar-120.5 ± 4.2kJ/molRSCNolan, de la Vega, et al., 1988solvent: Tetrahydrofuran

C8H6MoO3 (cr) + Iodine (solution) = C8H5IMoO3 (solution) + Hydrogen iodide (solution)

By formula: C8H6MoO3 (cr) + I2 (solution) = C8H5IMoO3 (solution) + HI (solution)

Quantity Value Units Method Reference Comment
Deltar-75.3 ± 2.5kJ/molRSCLandrum and Hoff, 1985solvent: Dichloromethane

C8H5MoNaO3 (solution) + Iodine (cr) = C8H5IMoO3 (solution) + Sodium iodide (cr)

By formula: C8H5MoNaO3 (solution) + I2 (cr) = C8H5IMoO3 (solution) + INa (cr)

Quantity Value Units Method Reference Comment
Deltar-133.1 ± 5.4kJ/molRSCNolan, López de la Vega, et al., 1986solvent: Tetrahydrofuran

C16H10Mo2O6 (cr) + Iodine (solution) = 2C8H5IMoO3 (solution)

By formula: C16H10Mo2O6 (cr) + I2 (solution) = 2C8H5IMoO3 (solution)

Quantity Value Units Method Reference Comment
Deltar-133.1 ± 4.2kJ/molRSCLandrum and Hoff, 1985solvent: Dichloromethane

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nolan, de la Vega, et al., 1988
Nolan, S.P.; de la Vega, R.L.; Mukerjee, S.L.; Gonzalez, A.A.; Zhang, K.; Hoff, C., Polyhedron, 1988, 7, 1491. [all data]

Landrum and Hoff, 1985
Landrum, J.T.; Hoff, C.D., J. Organometal. Chem., 1985, 282, 215. [all data]

Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., J. Organometal. Chem., 1986, 315, 187. [all data]


Notes

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