Ge(Me)3


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C3H10Ge (g) = C3H9Ge (g) + Hydrogen atom (g)

By formula: C3H10Ge (g) = C3H9Ge (g) + H (g)

Quantity Value Units Method Reference Comment
Δr334. ± 12.kJ/molICRBrinkman, Salomon, et al., 1995The reaction enthalpy was derived from the acidity of Ge(Me)3(H)(g), 1513. ± 12. kJ/mol, the electron affinity of Ge(Me)3(g), 133.5 ± 2.9 kJ/mol Brinkman, Salomon, et al., 1995, and the ionization energy of H(g), 1312.0 kJ/mol Lias, Bartmess, et al., 1988.

Germane, tetramethyl- (g) = C3H9Ge (g) + Methane (g)

By formula: C4H12Ge (g) = C3H9Ge (g) + CH4 (g)

Quantity Value Units Method Reference Comment
Δr339. ± 13.kJ/molVLPPSmith and Patrick, 1983 
Δr347. ± 17.kJ/molN/AMcMillen and Golden, 1982 

Iodine atom (g) + C3H10Ge (g) = C3H9Ge (g) + Hydrogen iodide (g)

By formula: I (g) + C3H10Ge (g) = C3H9Ge (g) + HI (g)

Quantity Value Units Method Reference Comment
Δr42.0 ± 1.8kJ/molKinGDoncaster and Walsh, 1979 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Salomon, et al., 1995
Brinkman, E.A.; Salomon, K.; Tumas, W.; Brauman, J.I., Electron affinities and gas-phase acidities of organogermanium and organotin compounds, J. Am. Chem. Soc., 1995, 117, 17, 4905, https://doi.org/10.1021/ja00122a022 . [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-Phase Ion and Neutral Thermochemistry, J. Phys. Chem. Ref. Data, 1988, 17, Suppl. 1. [all data]

Smith and Patrick, 1983
Smith, G.P.; Patrick, R., Int. J. Chem. Kinet., 1983, 15, 167. [all data]

McMillen and Golden, 1982
McMillen, D.F.; Golden, D.M., Hydrocarbon bond dissociation energies, Ann. Rev. Phys. Chem., 1982, 33, 493. [all data]

Doncaster and Walsh, 1979
Doncaster, A.M.; Walsh, R., J. Phys. Chem., 1979, 83, 578. [all data]


Notes

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