3-Me-thiophenide anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C5H5S- + Hydrogen cation = Thiophene, 3-methyl-

By formula: C5H5S- + H+ = C5H6S

Quantity Value Units Method Reference Comment
Δr1593. ± 13.kJ/molG+TSDePuy, Kass, et al., 1988gas phase; Acid: 3-methylthiophene. Between MeOH, EtOH. 1 D exchange implies ring proton as site.
Quantity Value Units Method Reference Comment
Δr1561. ± 13.kJ/molIMRBDePuy, Kass, et al., 1988gas phase; Acid: 3-methylthiophene. Between MeOH, EtOH. 1 D exchange implies ring proton as site.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Kass, et al., 1988
DePuy, C.H.; Kass, S.R.; Bean, G.P., Formation and Reactions of Heteroaromatic Anions in the Gas Phase, J. Org. Chem., 1988, 53, 19, 4427, https://doi.org/10.1021/jo00254a001 . [all data]


Notes

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