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CO2..CO3 radical anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CO3- + Carbon dioxide = C2O5-

By formula: CO3- + CO2 = C2O5-

Quantity Value Units Method Reference Comment
Deltar24.7 ± 0.84kJ/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar29.7 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Deltar4.2 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1992gas phase
Deltar2.5 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase

C2O5- + 2Carbon dioxide = C3O7-

By formula: C2O5- + 2CO2 = C3O7-

Quantity Value Units Method Reference Comment
Deltar24. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase
Quantity Value Units Method Reference Comment
Deltar2. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]


Notes

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