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BCl3+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 49300 ± 120 gas Bassett and Lloyd, 1971
Biehl, Boyle, et al., 1996
Shpinkova, Holland, et al., 1999
Mackie, Shpinkova, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 BCl stretch 380 ± 15 gas PE TPE Bassett and Lloyd, 1971
Biehl, Boyle, et al., 1996
Shpinkova, Holland, et al., 1999
Mackie, Shpinkova, et al., 2003
e' 3 BCl stretch 1065 ± 15 gas TPE Mackie, Shpinkova, et al., 2003

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 29990 ± 120 gas Bassett and Lloyd, 1971
Biehl, Boyle, et al., 1996
Shpinkova, Holland, et al., 1999
Mackie, Shpinkova, et al., 2003
gas D-X 330 420 Lee, Han, et al., 1989
Creasey, Hatherly, et al., 1993
Biehl, Creasey, et al., 1995
gas D-A,B 420 580 Lee, Han, et al., 1989
Creasey, Hatherly, et al., 1993
Biehl, Creasey, et al., 1995
Txd = 31200 Ar D-X Miller and Andrews, 1980


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 BCl stretch 476 ± 15 gas TPE Mackie, Shpinkova, et al., 2003
a2 2 OPLA 218 ± 15 gas TPE Mackie, Shpinkova, et al., 2003
e' 4 Deformation 240 T gas TPE Mackie, Shpinkova, et al., 2003

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 20900 ± 120 gas Bassett and Lloyd, 1971
Biehl, Boyle, et al., 1996
Shpinkova, Holland, et al., 1999
Mackie, Shpinkova, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 BCl stretch 468 gas PE TPE Bassett and Lloyd, 1971
Biehl, Boyle, et al., 1996
Shpinkova, Holland, et al., 1999
Mackie, Shpinkova, et al., 2003

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 9280 ± 120 gas Bassett and Lloyd, 1971
Biehl, Boyle, et al., 1996
Shpinkova, Holland, et al., 1999
Mackie, Shpinkova, et al., 2003

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 5080 ± 120 gas Bassett and Lloyd, 1971
Biehl, Boyle, et al., 1996
Shpinkova, Holland, et al., 1999
Mackie, Shpinkova, et al., 2003


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

e' 4 Deformation 320 T gas PE Shpinkova, Holland, et al., 1999

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

e' 3 BCl stretch 1103.8 Ne IR Jacox, Irikura, et al., 1996
3 BCl stretch 1090 Ar IR Miller and Andrews, 1980
209 gas TPE Yang, Mo, et al., 2005
194 gas TPE Yang, Mo, et al., 2005

Additional references: Jacox, 1994, page 201; Jacox, 1998, page 255; Jacox, 2003, page 234; Boyle, Seccomb, et al., 1999

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R., J. Chem. Soc. A, 1971, 641. [all data]

Biehl, Boyle, et al., 1996
Biehl, H.; Boyle, K.J.; Smith, D.M.; Tuckett, R.P.; Yoxall, K.R.; Codling, K.; Hatherly, P.A.; Stankiewicz, M., J. Chem. Soc., 1996, Faraday Trans. 92, 185. [all data]

Shpinkova, Holland, et al., 1999
Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A., Mol. Phys., 1999, 96, 323. [all data]

Mackie, Shpinkova, et al., 2003
Mackie, R.A.; Shpinkova, L.G.; Holland, D.M.P.; Shaw, D.A., A study of the threshold photoelectron spectra and the photoionisation yield curves of the boron trihalides, Chem. Phys., 2003, 288, 2-3, 211, https://doi.org/10.1016/S0301-0104(03)00025-9 . [all data]

Lee, Han, et al., 1989
Lee, L.C.; Han, J.C.; Suto, M., Fluorescence from photoexcitation of BCl3 at 45--106 nm, J. Chem. Phys., 1989, 91, 4, 2036, https://doi.org/10.1063/1.457063 . [all data]

Creasey, Hatherly, et al., 1993
Creasey, J.C.; Hatherly, P.A.; Lambert, I.R.; Tuckett, R.P., Vacuum UV fluorescence excitation spectroscopy of BCl, Mol. Phys., 1993, 79, 2, 413, https://doi.org/10.1080/00268979300101311 . [all data]

Biehl, Creasey, et al., 1995
Biehl, H.; Creasey, J.C.; Smith, D.M.; Tuckett, R.P.; Yoxall, K.R.; Baumgartel, H.; Jochims, H.W.; Rockland, U., J. Chem. Soc., 1995, Faraday Trans. 91, 3073. [all data]

Miller and Andrews, 1980
Miller, J.H.; Andrews, L., Matrix photoionization and radiolysis of boron trihalides. Infrared and ultraviolet spectra of boron trichloride(1+) and boron tribromide(1+) and infrared spectra of boron dichloride and boron dibromide, J. Am. Chem. Soc., 1980, 102, 15, 4900, https://doi.org/10.1021/ja00535a011 . [all data]

Jacox, Irikura, et al., 1996
Jacox, M.E.; Irikura, K.K.; Thompson, W.E., Matrix isolation study of the interaction of excited neon atoms with BCl3: Infrared spectra of BCl+3, BCl+2, and BCl-3, J. Chem. Phys., 1996, 104, 22, 8871, https://doi.org/10.1063/1.471622 . [all data]

Yang, Mo, et al., 2005
Yang, J.; Mo, Y.; Lau, K.C.; Song, Y.; Qian, X.M.; Ng, C.Y., A combined vacuum ultraviolet laser and synchrotron pulsed field ionization study of BCl3, Phys. Chem. Chem. Phys., 2005, 7, 7, 1518, https://doi.org/10.1039/b417083k . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Boyle, Seccomb, et al., 1999
Boyle, K.J.; Seccomb, D.P.; Tuckett, R.P.; Baumgartel, H.; Jochims, H.W., Vacuum-UV fluorescence spectroscopy of BF, J. Phys. B: At. Mol. Opt. Phys., 1999, 32, 11, 2569, https://doi.org/10.1088/0953-4075/32/11/308 . [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References