Li8


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 20800 gas Bonacic-Koutecky, Broyer, et al., 1992

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 14700 gas Bonacic-Koutecky, Broyer, et al., 1992

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 295.3 Ar Ra Kornath, Kaufmann, et al., 2003
2 221.0 Ar Ra Kornath, Kaufmann, et al., 2003
e 3 241.7 Ar Ra Kornath, Kaufmann, et al., 2003
4 83.0 Ar Ra Kornath, Kaufmann, et al., 2003
f2 6 298.5 s Ar Ra Kornath, Kaufmann, et al., 2003
7 201.4 Ar Ra Kornath, Kaufmann, et al., 2003
8 132.8 Ar Ra Kornath, Kaufmann, et al., 2003

Additional references: Jacox, 1994, page 381

Notes

sStrong
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bonacic-Koutecky, Broyer, et al., 1992
Bonacic-Koutecky, V.; Broyer, M.; Chevaleyre, J.; Dugourd, Ph.; Koutecky, J.; Scheuch, C.; Wolf, J.P.; Woste, L., Evolution of the electronic structure of lithium clusters between four and eight atoms, J. Chem. Phys., 1992, 96, 3, 1793, https://doi.org/10.1063/1.462846 . [all data]

Kornath, Kaufmann, et al., 2003
Kornath, A.; Kaufmann, A.; Zoermer, A.; Ludwig, R., Raman spectroscopic investigation of small matrix-isolated lithium clusters, J. Chem. Phys., 2003, 118, 15, 6957, https://doi.org/10.1063/1.1555800 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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