Trisilver trichloride
- Formula: Ag3Cl3
- Molecular weight: 429.964
- CAS Registry Number: 12444-96-1
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.4 ± 0.3 | EI | Bernauer, Busse, et al., 1979 | LLK |
| 10.0 ± 0.5 | EI | Wagner and Grimley, 1972 | LLK |
| 10.4 ± 0.3 | EI | Graber and Weil, 1972 | LLK |
| 10.3 ± 0.4 | EI | Visnapuu and Jensen, 1970 | RDSH |
| 10.7 ± 0.2 | EI | Visnapuu and Jensen, 1970 | RDSH |
| 10.2 | PE | MacNaughton, Bloor, et al., 1981 | Vertical value; LLK |
| 10.14 ± 0.02 | PE | Potts and Lyus, 1978 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Ag+ | 14.5 | ? | EI | Graber and Weil, 1972 | LLK |
| AgCl+ | 14.2 | ? | EI | Graber and Weil, 1972 | LLK |
| Ag2+ | 18.0 ± 0.5 | ? | EI | Graber and Weil, 1972 | LLK |
| Ag2+ | 15.7 ± 1.3 | ? | EI | Visnapuu and Jensen, 1970 | RDSH |
| Ag2Cl+ | 12.9 | ? | EI | Graber and Weil, 1972 | LLK |
| Ag2Cl+ | 11.6 ± 0.6 | ? | EI | Visnapuu and Jensen, 1970 | RDSH |
| Ag3+ | 18.4 ± 0.5 | ? | EI | Wagner and Grimley, 1972 | LLK |
| Ag3Cl+ | 14.9 ± 0.5 | ? | EI | Wagner and Grimley, 1972 | LLK |
| Ag3Cl2+ | 11.1 ± 0.5 | Cl | EI | Wagner and Grimley, 1972 | LLK |
| Ag3Cl2+ | 11.1 ± 0.3 | Cl | EI | Graber and Weil, 1972 | LLK |
| Cl+ | ~15.5 | ? | EI | Wagner and Grimley, 1972 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bernauer, Busse, et al., 1979
Bernauer, O.; Busse, B.; Weil, K.G.,
Massenspektrometrische Untersuchungen an Kupfer- und Silber- Halogeniden IV: Die Systeme AgxCu(1-x) (0=<X=<1) und AgClxBr(1-x) (0=<X=<1),
Ber. Bunsen-Ges. Phys. Chem., 1979, 83, 603. [all data]
Wagner and Grimley, 1972
Wagner, L.C.; Grimley, R.T.,
A study of ionization processes by the angular distribution technique. The AgCl system,
J. Phys. Chem., 1972, 76, 2819. [all data]
Graber and Weil, 1972
Graber, P.; Weil, K.G.,
Mass spectrometric investigations of silver halides I: mass spectrum, appearance potentials, fragmentation scheme of silver chloride,
Ber. Bunsen-Ges. Phys. Chem., 1972, 76, 410. [all data]
Visnapuu and Jensen, 1970
Visnapuu, A.; Jensen, J.W.,
Composition and properties of vapors over molten silver chloride,
J.Less-Common Metals, 1970, 20, 141. [all data]
MacNaughton, Bloor, et al., 1981
MacNaughton, R.M.; Bloor, J.E.; Sherrod, R.E.; Schweitzer, G.K.,
The He(I) photoelectron psectra of some gaseous 3d-transition metal dihalides,
J. Electron Spectrosc. Relat. Phenom., 1981, 22, 1. [all data]
Potts and Lyus, 1978
Potts, A.; Lyus, M.L.,
The photoelectron spectrum and valence shell structure of (CuX)3 and (AgCl)3,
J. Electron Spectrosc. Relat. Phenom., 1978, 13, 305. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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